The Samhwa iron ore deposit, which is of typical magnetite skarn type, is located in the Samhwadong area of Donghae city, Kangwon-do, Korea. Skarn minerals are mainly composed of garnet, clinopyroxene, vesuvianite, wollastonite and small amounts of epidote and quartz. The garnets are isotropic $(Ad_{92.82{\sim}98.37})$ or anisotropic andradite $(Ad_{45.30{\sim}75.85})$ and grossular $(Gr_{86.26{\sim}24.47})$, the clinopyroxenes are ferrosalite and salite, Homogenization temperature of gas rich two phase inclusions in garnet are $368{\sim}593^{\circ}C$, and salnities of polyphase inclusions in garnet have 33.9~68.4 equ. NaCl wt. %. Garnet grain often shows composional variation from its core to rim. In other words, Fe and Al contents in garnet vary inversely, which suggest that the variation depends upon $f_{o2}$ during skarn formation.

The tourmalines distributed in the Sangdong area belong to the dravite-schorl series in terms of the cell dimensions and the chemical compositions. Geochemical characteristics of tourmalines indicate that Naedeogni granite and pegmatite appear to be derived from Li-poor and Fe-riched aplite rocks, but Nonggeori granite is derived from Ca-poor or Si-riched pelitic rocks. The Mg+Fe contents of tourmaline in Naedeogni granitoids are decreased from the granites to the pegmatites with the Fe contents increased while Mg contents decreased. It indicates the differentiation during the crystallization of tourmalines. These phenomena are coincided with the chemical variations from cores toward rims of the zonal tourmalines. Such a compositional variations in Nonggeori granite can not be observed.

Geochemical studies on gold-bearing quartz veins and granitic wallrocks from the Mugeug mine were carried out in order to investigate primary dispersion patterns of elements and to quantify primary dispersion widths of elements with distance from the gold-bearing quartz veins. The best fitting model of dispersion pattern in altered wallrock around the gold-bearing quartz veins is an exponential function for Au, As, Sb, $Na_2O$ and Sr, and a quadratic function for CaO, $K_2O$, MnO, Ba, Rb and Cs. The primary dispersion widths are 15~343 cm in the hanging wall, and 33~173 cm in the footwall. The width of primary dispersion in the hanging wall is twice as thick as that in the footwall mainly due to the thermal effect and volatile components. The primary dispersion width is increased as the increase of gold-bearing quartz vein width and contents of As and Sb in gold-bearing quartz veins, but is not related to Au content in gold-bearing quartz veins.

울산지역에 분포하는 가대리 화강암체는 울산 철 텅그스텐 광화작용의 관계화성암으로서 전형적인 미문상조직을 보여주며, 칼크-알칼리 계열과 I-type화강암류의 지화학적 특성을 나타내고 있다. 가대리화강암은 물이 포화된 상태에서 0.5~2.0 kbar의 압력조건하에서 생성된 것으로 이는 천부에서의 분별결정에 기인된 것으로 화학성분의 분화는 대부분 알칼리 장석의 분별결정작용으로 이루어졌다. 경상분지 최남단에 분포하며 철광화작용과 관련된 미문상화강암체인 마산-김해 화강암체와 가대리화강암제는 미량성분의 화학조성을 비교해볼때 전혀다른 모마그마에서 분화되었음올 시사해준다.

Many researchers have investigated most representative sequential extraction method using various reagents for determining the chemical forms of metals in soils and sediments. In this paper, a newly modified method for sequential extraction scheme based on Tessier's method by Environmental Geochemistry Research, Centre for Environmental Technology, Imperial College, was introduced and examined. In comparison with Tessier's method, originally designed for sediment analysis by Atomic Absorption Spectrophotometry (AAS), the sequential extraction scheme has been developed for the multi-element analysis by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES). The partitioning of particulate trace elements was classified into five fractions: (i) exchangeable, (ii) bound to carbonates or specially adsorbed, (iii) bound to Fe and Mn oxides, (iv) bound to organic matter and sulphides and (v) residuals. The experimental results of the pilot study for in-house reference material (HRM2) and certified international standard reference material (SRM2711) using the modified method showed not only reasonable precision and accuracy but also acceptable overall recovery rates. In addition, mine dump soils sampled in the Dalsung Cu-W mine, Korea were prepared and sequentially extracted using the method. Most of Cu was bound to organic matter/sulphides and residual fractions. The dominant fraction of soil Pb and Zn in the study area was found in the residuals. The fraction of Cd showed a wide variation between samples and could be found bound to the carbonates or specially adsorbed, oxides, organic fraction and residuals. The recovery rates of Cd, however, were poor due to relatively low Cd concentrations in soils. The heavy metals in these mine dumps appear to be in the more inert forms and should not be readily bioavailable. The soils, however, had very low pH values (average 4.1) and had sandy textures; consequently, rapid infiltration of rainfall may increase leaching of Zn and Cd which were found to be around 5 to 10% of the exchangeable fraction. As a result of the investigation of this study, it has been strongly recommended that these mine waste materials should still be considered a significant contaminant source and will need environmental remediation to prevent pollutants from being released into the environment.

In this paper, the iterative least-squares inversion method is used to determine shapes and density contrasts of 2-D structures from the gravity data. The 2-D structures are represented by their cross-sections of N-sided polygons with density contrasts which are constant or varying with depth. Gravity data are calculated by theoretical formulas for the above structure models. The data are considered as observed ones and used for inversions. The inversions are performed by the following processes: I) polygon's vertices and density contrast are initially assumed, 2) gravity are calculated for the assumed model and error between the true (observed) and calculated gravity are determined, 3) new vertices and density contrast are determined from the error by using the damped least-squares inversion method, and 4) final model is determined when the error is very small. Results of this study show that the shape and density contrast of each model are accurately determined when the density contrast is constant or vertical density gradient is known. In case where the density gradient is unknown, the inversion gives incorrect results. But the shape and density gradient of the model are determined when the surface density contrast is known.

2층구조 대지속에 존재하는 유한 크기의 불균질체로 인한 지자기 지전류 (MT) 응답을 적분방정식법으로 계산하였다. 적분방정식은 입사전자장과 3차원물체 내부의 산란전류를 층상대지에 적합한 전기적 텐서 그린함수를 통하여 연결시킨다. 본 논문에서는 3차원체의 MT응답에 미치는 표층과 기반층의 영향에 대하여 검토하였다. 표층은 탐사대상물의 검출을 방해하는 효과를 가지며 그 효과는 표층의 전기비저항이 높을 때보다 낮을 때가 더 뚜렷하다. 한편 기반은 상층의 3차원체에 인한 MT이상을 높이는 효과를 가져올 수도 있다. 전기비저항이 높은 기반이 존재하면 물체에 의한 전류의 미소변동은 보다 전기비저항이 낮은 상층에 한정되는 경향이 있다.

기존 미소결함에서의 국소적 응력집중은 새로운 미시적 손상의 원인이 되고, 이러한 미시적 손상은 또한 거시적 손상으로 발달하게 된다. 이들 미시적 손상에서 거시적 손상으로의 바달은 그 암석 및 암반의 변형특성으로 나타난다. 지금까지 응력하에서의 미소크랙의 거동에 대한 연구는 많이 되어왔으나, 실제암석의 파괴전 상태에서 미소크랙거동에 대한 역학적 해석은 아직 미비한 실정이다. 본 연구에서는 새로이 개발한 시험장치에 의한 정밀한 관찰로 손상 발달에 대한 이해를 더하였으며, 수학적 균질화 이론에 의해 수치해석 함으로서 그 역학성을 검토하였다.