유기물자원화 (Journal of the Korea Organic Resources Recycling Association)

  • 제30권2호
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  • Pages.5-15
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  • 2022
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  • 1225-6498(pISSN)
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  • 2508-3015(eISSN)
유기성자원학회 (Korea Organic Resources Recycling Association)
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궐련형 담배 바이오매스 기반의 슈퍼커패시터용 탄소의 제조 및 응용

Preparation of Heated Tobacco Biomass-derived Carbon Material for Supercapacitor Application

  • 김지원 (한밭대학교 화학생명공학과) ;
  • 제갈석 (한밭대학교 화학생명공학과) ;
  • 김동현 (한밭대학교 화학생명공학과) ;
  • 윤창민 (한밭대학교 화학생명공학과)
  • Kim, Jiwon (Department of Chemical and Biological Engineering, Hanbat National University) ;
  • Jekal, Suk (Department of Chemical and Biological Engineering, Hanbat National University) ;
  • Kim, Dong Hyun (Department of Chemical and Biological Engineering, Hanbat National University) ;
  • Yoon, Chang-Min (Department of Chemical and Biological Engineering, Hanbat National University)
  • 투고 : 2022.04.07
  • 심사 : 2022.04.22
  • 발행 : 2022.06.30
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초록

본 연구에서는 궐련형 담배의 담뱃잎 바이오매스 폐기물을 수거하여 슈퍼커패시터용 활물질로 제조 및 응용하였다. 수거한 담뱃잎 폐기물을 질소 환경에서 다양한 온도(800/850/950℃)로 탄화하였으며, 탄소/산소 성분비(C/O ratio) 분석을 통해 850℃에서 가장 우수한 품질의 탄소 물질이 제조되었음을 확인하였다. 추가적으로 담뱃잎 기반의 탄소 물질에 폴리피롤(Polypyrrole)을 저온중합법을 통해 코팅하여 전기화학적 성능을 향상시켰다. 탄소 물질(CTL-850)과 폴리피롤을 코팅한 탄소 물질(CTL-850/PPy)을 기반으로 한 전극의 전기화학적 성능을 측정한 결과, -1.0-0.0V와 0.0-1.0V의 전위창에서 각각 100.2F g-1@1 A g-1과 155.3F g-1@1 A g-1의 우수한 비정전용량(Specific capacitance)를 나타내었다. 두 개의 전극을 활용하여 비대칭형 슈퍼커패시터 소자(Asymmetric supercapacitor device)를 제작하였으며, 제조한 비대칭형 CTL-850//CTL-850/PPy 소자는 2.0V의 구동전압 범위와 비정전용량(31.1F g-1@1 A g-1)을 가지고 있음을 확인하였다. 또한, 제조한 슈퍼커패시터 소자의 방전을 통해 1.8V의 Red Led를 점등할 수 있음을 확인하였다. 본 연구 결과를 통해 바이오매스를 우수한 성능의 친환경 에너지 저장매체로 활용하는 후속 연구에 대한 방향성을 제시할 수 있을 것으로 판단된다.

In this study, heated tobacco biomass was prepared as an active material for supercapacitor device. Retrieved tobacco leaf from the heated tobacco was carbonized at various temperature(800/850/950℃). Carbonized tobacco leaf material synthesized at 850℃ exhibited the highest C/O ratio, indicating the finest carbon quality. In addition, polypyrrole was coated onto the carbonized leaf material for increasing the electrochemical performance via low-temperature polymerization method. As-synthesized carbonized leaf material at 850℃(CTL-850)-based electrode and polypyrrole-coated carbonized leaf material(CTL-850/PPy)-based electrode displayed outstanding specific capacitances of 100.2 and 155.3F g-1 at 1 A g-1 with opertaing window of -1.0V and 1.0V. Asymmetric supercapacitor device, assembled with CTL-850 as the negative electrode and CTL-850/PPy as the positive electrode, manifested specific capacitance of 31.1F g-1(@1 A g-1) with widened operating voltage window of 2.0V. Moreover, as-prepared asymmetric supercapacitor device was able to lighten up the RED Led (1.8V), suggesting the high capacitance and extension of operating voltage window. The result of this research may help to pave the new possibility toward preparing the effective energy storage device material recycling the biomass.

키워드

과제정보

본 과제(결과물)는 2021년도 교육부의 재원으로 한국연구재단의 지원을 받아 수행된 지자체-대학 협력기반 지역혁신 사업의 결과입니다.(과제번호: 2021RIS-004)

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