Chemical Mechanical Polishing (CMP) Characteristics of BST Ferroelectric Film by Sol-Gel Method

졸겔법에 의해 제작된 강유전체 BST막의 기계.화학적인 연마 특성

  • 서용진 (대불대학교 전기공학과) ;
  • 박성우 (대불대학교 전기공학과)
  • Published : 2004.03.01

Abstract

The perovskite ferroelectric materials of the PZT, SBT and BST series will attract much attention for application to ULSI devices. Among these materials, the BST ($Ba_0.6$$Sr_0.4$/$TiO_3$) is widely considered the most promising for use as an insulator in the capacitors of DRAMS beyond 1 Gbit and high density FRAMS. Especially, BST thin films have a good thermal-chemical stability, insulating effect and variety of Phases. However, BST thin films have problems of the aging effect and mismatch between the BST thin film and electrode. Also, due to the high defect density and surface roughness at grain boundarys and in the grains, which degrades the device performances. In order to overcome these weakness, we first applied the chemical mechanical polishing (CMP) process to the polishing of ferroelectric film in order to obtain a good planarity of electrode/ferroelectric film interface. BST ferroelectric film was fabricated by the sol-gel method. And then, we compared the surface characteristics before and after CMP process of BST films. We expect that our results will be useful promise of global planarization for FRAM application in the near future.

Keywords

References

  1. L. P. Cook et al, 'Microstructural Changes during Processing of Laser Deposited BaTiO3 and PZT Thin Films', MRS Symposium Proceeding, Vol. 202, pp. 241-245, 1991
  2. D. S. Shin et al, 'Effects of Morphological Changes of Pt/SrBi2Ta209 Interface on the Electrical Properties of Ferroelectric Capacitor', Jpn. J. Appl. Phys. Vol. 37. pp. 5189-5192, 1998 https://doi.org/10.1143/JJAP.37.5189
  3. S. Y. Kim and Y. J. Seo, 'Correlation analysis between pattern and non-pattern wafer for characterization of shallow trench isolation-chemical mechanical polishing(STI-CMP) process', Microelectronic Engineering, Elsevier Science, Vol. 60, Issue 3-4, pp. 357-364, 2002 https://doi.org/10.1016/S0167-9317(01)00694-3
  4. W. S. Lee, S. Y. Kim, Y. J. Seo and J. K. Lee, 'An Optimization of Tungsten Plug Chemical Mechanical Polishing (CMP) using Different Consumables', Journal of Materials Science : Materials in Electronics, Vol. 12, No. 1, pp. 63-68, 2001 https://doi.org/10.1023/A:1011276830620
  5. F. B. Kaufman, D. B. Thompson, R. E. Broadie, M. A. Jaso, W. L. Guthrie, D. J. Pearson and M. B. Small, 'Chemical-Mechanical Polishing for Fabricating Patterned W Metal Features as Chip Interconnects', Electrochem Soc., Vol. 138, p. 3460, 1991 https://doi.org/10.1149/1.2085434
  6. S. Y. Kim, S. Y. Jeong, and Y. J. Seo, 'Effects of deionized water pressure and purified nitrogen gas on the chemical mechanical polishing process', J. of Materials Science : Materials in Electronics, Kluwer Academic Publishers, Vol. 13, No. 5, pp. 299-302, 2002 https://doi.org/10.1023/A:1015524009343
  7. Takeharn, 'Dielectric Properties of (BaxSr1-x)TiO3 Thin Film Prepared by RF Sputtering for Dynamic Random Access Memory Application', Jpn. J. Appl. phys. Vol. 33, p. 5190, 1994
  8. T. Atsuki et al, 'Preparation of Bi-Based Ferroelectric Thin Films by Sol-Gel Method,' Japanese Journal of Applied Physics', Vol. 34, No. 9B, pp. 5096-5099, 1995 https://doi.org/10.1143/JJAP.34.5096
  9. F. wang, et al, 'Ba0.7Sr0.3TiO3 Ferroelectric Film Prepared with the Sol-Gel Process and its Dielectric Performance in Planar Capacitor Structure', J. Mater. Res. Vol. 13, No. 5, p. 1243, 1998 https://doi.org/10.1557/JMR.1998.0177