• Tunnel and Underground Space
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• v.16 no.3 s.62
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• pp.259-276
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• 2006

In rock mass subject to high in-situ stresses, the failure process of rock is dominated by the stress-induced fractures growing parallel to the excavation boundary. When the ratio of in situ stresses compared to rock strength is greater than a certain value, progressive brittle failure which is characterized by popping and spatting of rock debris occurs due to stress concentration. Traditional constitutive model like Mohr-Coulomb usually assume that the normal stress dependent frictional strength component and the cohesion strength component are constant, therefore modelling progressive brittle failure will be very difficult. In this study, a series of numerical analyses were conducted for surrounding rock mass near crude oil storage cavern using CW-FS model which was known to be efficient for modelling brittle failure and the results were compared with those of linear Mohr-Coulomb model. Further analyses were performed by varying plastic shear strain limits on cohesion and internal friction angle to find the proper values which yield the matching result with the observed failure in the oil storage caverns. The obtained results showed that CW-FS model could be a proper method to characterize essential behavior of progressive brittle failure in competent rock mass.

• Journal of Sericultural and Entomological Science
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• v.35 no.1
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• pp.60-68
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• 1993

It has been known that the silk degumming treated by hot alkali solution is easy to handle but is liable to yield poor-quality silk due to the degree of degumming loss, incomplete-degumming or over-degumming. Therefore, many studies have been carried out on the silk degumming by enzyme in order to improve the quality of silk. However, no attention has been paid to the physicochemical analysis of enzymatic degummed silk. In this paper, two different degumming methods, soap and enzymatic, are compared in aqueous solution state of silk fibroin. The results can be summarized as follows: There was no significant difference between two solutions on the bases of polarizing microscopy, TEM observation and SDS-PAGE. Spherulite of silk fibroin was not observed in polarizing microscopy, however the leaf-shape fibril structure was developed upon solidification. The size of spherulites of silk fibroin in TEM observation were 30~120nm with a wide range of size distribution. The intrinsic viscosity of enzymatic degummed fibroin solution was lower than that of soap degummed solution. This can be explained that the silk fibroin was more degraded by enzymatic degumming method compared with the soap degumming method. SDS-polyacrylamide gel electrophoresis showed that the fibroin molecule was composed of large component of molecule weight above 50 kd and small component of molecule weight about 20 kd. There was no difference in crystallinity between two degumming methods on the bases of results of DSC thermograms and IR spectra.

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.529-533
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• 2012

In this study, we compare various physicochemical properties of solvent extracted coals obtained at both mild and high temperature conditions. In order to characterize the extraction behavior, experiments were performed using a sub-bituminous coal (Kideco) and a polar solvent (N-methyl-2-pyrrolidinone, NMP), where the extraction temperature and the effect of solvent recycling were evaluated. As the extraction temperature increased up to $350^{\circ}C$, an extraction yield and a calorific value of the extracted coal increased, while an ash content of the extracted coal decreased. FT-IR results revealed that the surface of the coal extracted at $350^{\circ}C$ was found to contain more amide, aromatic ester, and aliphatic ether groups than that at the lower temperatures. The result of MALDI-TOF/MS analysis confirmed that the smaller molecules with 300~500 m/z were extracted at a mild condition, while the bigger molecules in the range of 500~1500 m/z were extracted at the high temperature.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.11
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• pp.4635-4642
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• 2010

Latex modification of concrete provides the material with higher flexural strength, as well as high bond strength and reduced water permeability. One of the most advantages of the very early-strength latex-modified concrete (VES-LMC) could be the similar contraction and expansion behaviour to normal concrete substrate, which enable to ensure long-term performance. The purpose of this study was to parametric nonlinear flexural nonlinear analysis of RC beam rehabilitated by VES-LMC. The results were as follows; The flexural nonlinear analysis model of RC beam overlaid by VES-LMC in ABAQUS was proposed to predict the load-deflection response, interfacial stress, and ultimate strength. The proposed FE analysis model was verified by comparison of an experimental data and the FE analysis results. The FE analysis results showed that yield point as well as flexural stiffness increased as the depth increased; the stiffness of beam overall increased as the bond stiffness became larger; the bond strength between two different materials is a key factor in composite beam. A parametric study showed that an overlay thickness was a main influencing factor to the behavior of RC beam overlaid by VES-LMC.

• Journal of Radiation Industry
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• v.10 no.4
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• pp.189-192
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• 2016

$^{68}Ga$ has emerged as a promising candidate for non-invasive diagnostic imaging within Positron Emission Tomography (PET) because of its advantageous radiochemical characteristics ($t_{1/2}=68min$, ${\beta}^+$ yield ~89%). $^{68}Ga$ forms a stable chelation with various ligands and it is possible to be quickly and easily study using a $^{68}Ge/^{68}Ga$ generator. Commercial $^{68}Ge/^{68}Ga$ generators are chromatographic system using the inorganic materials such as alumina and tin dioxide which are employed as column matrixes for $^{68}Ge$. In this study, we tried out to make $^{68}Ge/^{68}Ga$ generator system with the $^{68}GeO_2$ microstructures for column matrix. $^{68}Ge$ tends to have stable bond with oxide as $^{68}GeO_2$ microstructures. The $^{68}GeO_2$ has been synthesized by hydrolysis of $GeCl_4$ (sol-gel method) and characterized by X-ray diffraction and scanning electron microscope for geometrical analysis. The stability of $GeO_2$ was tested using eluents with diverse solvents(water, ethanol and 0.1 N HCl). The radioactivity of $^{68}Ga^{3+}$ in eluate through $GeO_2$ was measured to prove a function as column material for a generator.

• Korean Journal of Materials Research
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• v.28 no.11
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• pp.663-670
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• 2018

H13 tool steels are widely used as metallic mold materials due to their high hardness and thermal stability. Recently, many studies are undertaken to satisfy the demands for manufacturing the complex shape of the mold using a 3D printing technique. It is reported that the mechanical properties of 3D printed materials are lower than those of commercial forged alloys owing to micropores. In this study, we investigate the effect of microstructures and defects on mechanical properties in the 3D printed H13 tool steels. H13 tool steel is fabricated using a selective laser melting(SLM) process with a scan speed of 200 mm/s and a layer thickness of $25{\mu}m$. Microstructures are observed and porosities are measured by optical and scanning electron microscopy in the X-, Y-, and Z-directions with various the build heights. Tiny keyhole type pores are observed with a porosity of 0.4 %, which shows the lowest porosity in the center region. The measured Vickers hardness is around 550 HV and the yield and tensile strength are 1400 and 1700 MPa, respectively. The tensile properties are predicted using two empirical equations through the measured values of the Vickers hardness. The prediction of tensile strength has high accuracy with the experimental data of the 3D printed H13 tool steel. The effects of porosities and unmelted powders on mechanical properties are also elucidated by the metallic fractography analysis to understand tensile and fracture behavior.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.33 no.6
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• pp.419-426
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• 2020

The structural design of the steel eccentrically braced frame (EBF) was developed and analyzed in this study through multiobjective optimization (MOO). For the optimal design, NSGA-II which is one of the genetic algorithms was utilized. The amount of structure and interfloor displacement were selected as the objective functions of the MOO. The constraints include strength ratio and rotation angle of the link, which are required by structural standards and have forms of the penalty function such that the values of the objective functions increase drastically when a condition is violated. The regulations in the code provision for the EBF system are based on the concept of capacity design, that is, only the link members are allowed to yield, whereas the remaining members are intended to withstand the member forces within their elastic ranges. However, although the pareto front obtained from MOO satisfies the regulations in the code provision, the actual nonlinear behavior shows that the plastic deformation is concentrated in the link member of a certain story, resulting in the formation of a soft story, which violates the capacity design concept in the design code. To address this problem, another constraint based on the Eurocode was added to ensure that the maximum values of the shear overstrength factors of all links did not exceed 1.25 times the minimum values. When this constraint was added, it was observed that the resulting pareto front complied with both the design regulations and capacity design concept. Ratios of the link length to beam span ranged from 10% to 14%, which was within the category of shear links. The overall design is dominated by the constraint on the link's overstrength factor ratio. Design characteristics required by the design code, such as interstory drift and member strength ratios, were conservatively compared to the allowable values.

• Journal of Mushroom
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• v.19 no.2
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• pp.103-108
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• 2021

This experiment investigates the characteristics of microorganisms isolated from a medium during cultivation process and reveals the relationship between these microorganisms and the growth of Agaricus bisporus. The domestically grown strains of Agaricus bisporus displayed a higher inhibition growth rate against microorganisms isolated from straw, chicken manure, and medium than imported strains. As for inhibition of mycelial growth among mushroom cultivars of the microorganisms separated by each fermentation step from the mushroom medium, the domestic cultivar, 'Saedo,' grew more vigorously among other cultivars. As the fermentation progressed, it was confirmed that inhibitation of microorganisms against Agaricus bisporus was weakened. A total of 21 strains of microorganisms that promote mushroom growth were isolated in the 4th turning process, and the microorganisms isolated from the mushroom medium affect the growth and as yield of the mushroom through secretory substances.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.467-474
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• 2020

Carbon nanotube has excellent mechanical strength and functionality, so it has been utilized in various applications. In recent years, utilization of carbon nanotube in construction material has started to get interests from researchers in the area of construction materials. However, there is limited amount of work with respect to the rheological properties of cement paste using carbon nanotube. In this work, solution made of multi-walled carbon nanotube with dispersing agent of polyvinyl pyrrolidone was used to prepare cement paste specimens, and rheological properties and 28 day compressive strengths of cement paste using multi-walled carbon nanotube were measured. According to the experimental results, as the amounnt of multi-walled carbon nanotube increased, plastic viscosity and yield stress of cement paste specimens also increased. It was also found that such effect was higher with lower w/c cement paste specimens. With respect to the compressive strength, it was maximized at carbon nanotube content of 0.1wt.% for w/c 0.30 cement paste, whereas the maximum strength of w/c 0.40 cement paste was observed with carbon nanotube content of 0.2wt%.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.1
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• pp.1-6
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• 2021

Concrete structures gradually age due to deterioration of materials or excess loads and environmental factors, and their performance decreases, affecting the usability and safety of structures. Although external tension construction methods are widely used among the reinforcement methods of old bridges, it is insufficient to identify the effects and effects of reinforcement depending on the level of aging. Therefore, in this study, a four-point loading experiment was conducted on the subject with the non-reinforced and external tensioning method to confirm the reinforcement effect of the external tensioning method, assuming the aging of the structure as a reduction in the compressive strength and tensile reinforcement of concrete, to analyze the behavior of the reinforcement and confirm the reinforcement effect. As a result of the experiment, it was difficult to identify the amount of reinforcement in the extreme condition due to early elimination of the anchorage. Therefore, compliance with the regulations on anchor bolts is required when applying the external tension reinforcement method. Crack load and yield load increased depending on whether external tension was reinforced, but before the crack, the stiffness before and after reinforcement was similar, making it difficult to confirm the reinforcement effect.