• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.606-612
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• 2022

The purpose of this study is to convert hydrophobic dyestuff to hydrophilic dyestuff by reacting cationic collector with anionic dyestuff and reaction anionic collector with cationic dyestuff. The removal of colors from aqueous solutions and/or dispersions has been studied by dispersed-air flotation in a batch column. In this studies used generated micro bubble by ceramic gas diffuser having micro pore size for air flotation process. In this study, a ceramic gas diffuser with micro pore size was used to generate micro bubbles for the air flotation process. Two colours were used for the experiments: Basic Yellow 1 (cationic dyestuff) and Direct Orange 10 (anionic dyestuff). All two were effectively removed by flotation within 8 mins. Sodium dodecyl sulfate, sodium oleate (an anionic collector), and amines (a cationic collector) were found to be effective as collectors in the removal of color, which was found to be related to the pH of the solution and the amount of collector added to it, with high collector dosages causing the process to become pH-independent.

• Journal of the Korean Society of Clothing and Textiles
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• v.29 no.12 s.148
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• pp.1608-1618
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• 2005

The purpose of this investigation was to investigate the degradation products of the dye component extracted from madder dyed fabrics using the GC-MS analysis and to evaluate the change of color due to degradation treatment. Four different degradation protocols were used in this study,; refrigeration at $7^{\circ}C$ (LT), room temperature (RT), oven treatment at $100^{\circ}C$ (OV), and $H_2O_2/UV(PER)$ method. Degradation times for each thermal system were 6 hour, 24 hour, 48 hour, 1 week, 2 week, 4 week. Alizarin was detected from the control and degraded samples of both alizarin dyed and madder dyed fabrics. Benzoic acid, 2, 4-di-tert-butylphenol, phthalic anhydride were detected as the degradation products for both alizarin dyed and madder dyed fabrics. The result suggest that these products can be used as the fingerprints of GC-MS analysis for the identification of madder dye in archaeological textiles. Both alizarin dyed and madder dyed samples became less red and less yellow after degradation. In the PER degradation system madder dyed sample showed the greatest color difference even after 1 week of degradation treatment. Further research is necessary for investigating the color change in the exhumed textiles, which is caused by the dual action of dye fading and the staining of organic matters in the soil.

• Journal of Conservation Science
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• v.32 no.3
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• pp.345-352
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• 2016

The purpose of this study is to analyze on the textile used for book covers of "Gukgiboksiksoseon" and "Boepboksajeolboksaek", and slipcase of these books kept in the Oryundae Korean Martyrs Museum in Busan. These records are estimated to be written by Gyeongbin Kim(1831-1907), who was a royal concubine of 24th King Heonjong (reign 1834~1849) of the Joseon Dynasty. The cover textile of slipcase and two books are investigated to be silks by the FT-IR. The cover textile of slipcase is flower patterned satin with silver thread and the cover textile of two books are green and red with Su characters and bat patterned satin. The blackish part of pattern of slipcase is investigated by silver thread by FE-SEM-EDAX. Moreover, by the dye analysis, berberine, brazilin, and carthamin are detected from the cover textile of "Boepboksajeolboksaek". It is indicated that it was dyed with an amur cork-tree, a sappanwood, and a safflower. And rutin which is the main dyestuff of the sophora flower of the pagoda tree was detected from the yellow thread of the cover textile of slipcase.

• Horticultural Science & Technology
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• v.32 no.3
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• pp.390-399
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• 2014

The objective of this study was to establish a processing technology for preserved leaves based on the results from the examination of the optimal period and condition for dye-absorbing treatment for Eucalyptus cinerea F. Mull. ex Benth. (silver dollar eucalyptus) being used frequently as plant material for flower design. Cut foliages of E. cinerea with uniformly matured leaves were cut into 20 cm lengths and their lower stem parts were placed in dye solution in growth chambers with different temperatures (10, 20, 30, and $40^{\circ}C$), vapor pressure deficits (VPD; 0.23, 0.70, 1.17, and 1.61 kPa), and photoperiods (0, 6, 12, 24 hours) for 3, 6, 9, and 12 days, and then dried in a room of $20^{\circ}C$ for three days. Lower temperature during preserving dye treatment reduced the changes in leaf color compared with fresh leaves and decreased ${\Delta}E$ value. Especially, high temperature increased red degree (a) and decreased yellow degree (b) due to browning. Lower VPD reduced the change in leaf color compared with fresh leaves and decreased ${\Delta}E$ value. Shorter photoperiod reduced the change in leaf color compared with fresh leaves and decreased ${\Delta}E$ value. The ${\Delta}E$ value increased with increasing absorbing duration under three environmental conditions. The flexibility of stem and leaves after dipped into preserving dye solution and dried for 3 days increased with decreasing temperature, VPD and dipping duration. Therefore, the optimal environment condition for dye treatment was 0.23-0.70 kPa VPD at $10-20^{\circ}C$ in the darkness, and the optimal and economical duration was 3 days. These conditions reduced the speed of water loss by decreasing transpiration, so yellowing or browning by rapid water loss deteriorated the quality of preserved leaves out of these ranges.

• Journal of the Korean Society of Clothing and Textiles
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• v.21 no.6
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• pp.1051-1059
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• 1997

The objectives of this study were to investigate the effects of mordants and dyeing: on the dyeability and color fastness of the fabrics dyed with the extract from Turmeric. The following results were drawn from the data obtained. 1. The wavelengths of the strongest absorption band of Turmeric extract were 400 nm respectively and the wavelengths were 440 nm after the mordants were added in the color extract. The bands of Turmeric extract shifted to long wave length side as pH increased. In all cases, the abosorbancies were increased as pH increased. 2. The main color substance in extract from Turmeric were expected to be curcumin respectively by spectrophotometric and HPLC studies. 3. As to the concentration of color extract for dyeing, about 20 g/L was the optimum concentration to dye silk and cotton fabrics with extract. 4. The K/S values of dyed fabrics were increased gradually as the concentration of mordants increased, and the highest K/S values were obtained at 5∼10%. When using the mordanting methods, silk fabric by premordanting and cotton fabric by premordanting and synmordanting had influenced upon K/S valse. 5. The color fastness of fabrics dyed with Turmeric extract against dry cleaning, washing, rubbing and perspiration was improved 1 level or so but light fastness was remained.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.41 no.2
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• pp.34-39
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• 2009

The traditional Korean hand-made papers (Hanji) were dyed with colorant extracted from flowers of Sophora japonica L.(pagoda tree), and the effect of various dyeing factors (mordant, mordanting method, pH of dyeing solution, etc.) on colors and K/S values of the dyed Hanji was investigated. Changing mordant affected the color of dyed Hanji. Mordanting with alum, copper acetate made the color of dyed Hanji more yellow, but dyed Hanji mordanted with $FeCl_2$ had dark olive color. The K/S value of the dyed Hanji mainly depended on the pH of the dyeing solution and mordanting method. It was found that sim-mordanting with alum was timesaving and effective dyeing method. The dyed Hanji sim-mordanted with alum had the highest K/S value at low pH (about 4).

• Journal of the Korean Society of Costume
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• v.56 no.1 s.100
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• pp.143-149
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• 2006

For the purpose of standardization and practicability of natural dyeing, the mordanting and dyeing properties of Acorn Shell was studied. Appropriate extraction, dyeing and mordanting condition of Acorn Shell were determined, and the effect of mordanting method on dye uptake and color fastness of dyed fabric was investigated. The maximum absorbance of Acorn Shell solution was at 287.5nm and 294nm. The pH effect was stable in the color difference changes. The optimum temperature to extract Acorn Shell was during 1 hour in $60^{\circ}C$. The effective dyeing temperature and time of silk were $80{\sim}100^{\circ}C$, 1hour. The silk fabrics dyed with Acorn Shell appeared yellow-brown. K/S value of dyeing fabrics was increased by mordant treatment. K/S value of post-mordanting was higher than pre-mordanting. Mordanting treatment attected color change of the dyed silk. In the case of Acorn Shell light fastness of appeared more than 3-5grades by post-mordanting. Abrasion fastness of appeared more than 3-5grades. Perspiration fastness of appered more than $3{\sim}5grades$ by mordant treatment but Cu mordant treatment was $2-5{\sim}4grades$. Dry-cleaning Fastness appered more than 4 grades except Cu mordant treatment. These fastness improvement were generally effective for mordant treatment, specially Al, Sn, Cr.

• Textile Coloration and Finishing
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• v.20 no.3
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• pp.8-17
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• 2008

For the purpose of standardization and practicability of natural dyeing, the mordanting and dyeing properties of turmeric was studied. In this study, the colorants of turmeric were extracted with boiling water. Chitosan-crosslinked cotton fabrics was dyed with aqueous extract of turmeric and their dyeabilities on the fabrics were studied. Additionally the fastness to washing and light were also investigated. Cotton fabrics were treated with a crosslinking agent epichlorohydrin in the presence of chitosan to provide the cotton fabrics the dyeing properties of natural dye(turmeric) by the chemical linking of chitosan to the cellulose structure. The chitosan finishing and durable press finishing of the cotton fabrics occurred simultaneously in the mercerization bath. The dyeability(K/S), which was obtained by CCM observation, remarkably became increased when the crosslinked chitosan concentration was higher. Dyeability of turmeric was improved on chitosan-crosslinked cotton fabric rather than only cotton fabric, while the saturated dyeing time was 20minutes at $60^{\circ}C$. The hue value indicated greenish yellow with increasing the crosslinked chitosan concentration. And the color fastness to washing and light was almost the same.

• Journal of the Korean Society of Costume
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• v.55 no.8 s.99
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• pp.154-160
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• 2005

For the purpose of standardization and practicability of natural dyeing, the mordanting and dyeing properties of Puerariae Radix was studied. Appropriate extraction, dyeing and mordanting condition of Puerariae Radix were determined, and the effect of mordanting method on dye uptake and color fastness of dyed fabric was investigated. The maximum absorbance of Puerariae Radix solution was at 290nm and 301nm. The pH effect was stable in the color difference changes. The optimum temperature to extract Puerariae Radix was during 1 hour in loot. The effective dyeing temperature and time of silk were 80$\~$ 100$^{circ}C$, 1hour. The silk fabrics dyed with Puerariae Radix appeared yellow-brown. US value of dyeing fabrics was increased by Fe, and Cu mordant treatment. Mordanting treatment method affected color change of the dyed silk. In the case of Puerariae Radix light fastness of appeared more than 2-5 grades by mordant treatment. Perspiration fastness of appered more than 4 grades by Al, Sn, Cr mordant treatment. Fastness of abrasion and dry-cleaning appered more than 4-5 grades. These fastness improvement were generally effective for mordant treatment, specially Al, Sn, Cr.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.2
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• pp.82-87
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• 2010

The Hanji dyed with persimmon juice were useful goods in the past, but they are not widely used nowadays despite of their many strong points such as antibacterial and water-resistant properties. The object of this study is to provide useful data for developing new products by using them. We dyed traditional Korean hand-made papers (Hanji) with colorants extracted from fruits of Diospyros kaki and investigated the effect of various dyeing factors (mordant, mordanting method, pH of dyeing solution, light exposure time etc.) on optical and mechanical properties of the dyed Hanji. Changing mordant affected the color of dyed Hanji. The dyed Hanji after-mordanted with Cu mordant had the highest K/S value and showed the deepest yellow and red shade. The best mordanting method was an after-mordanting. The K/S value of dyed Hanji increased with decreasing pH of dyeing solution. The tensile index and size degree values of the Hanji were increased after dyeing.