• Title/Summary/Keyword: wood discoloration

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A Color Difference of White Polyurethane Coating Containing Antioxidant (산화방지제가 첨가된 백색 폴리우레탄 도막의 색차)

  • Lee, Phil-Woo;Yun, Young-Ki
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.3
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    • pp.45-50
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    • 1994
  • This experiment was to investigate the effects of UV radiation and chemical treatments on the color difference in antioxidant (Tris(2,4-di-t-butyl phenoxy) phosphite)-containing polyurethane coats. The results obtained were summerized as follows: 1. The color difference increased as the exposure time of UV radiation increases, but decreased as addition level of antioxidant increaes. 2. After 400 hours exposure to UV radiation, the color difference respectively showed 6.13 and 5.94 at 0.7 % and 1.0 % addition level but appeared more severe below 0.7 % addition level. Thus, antioxidant prevented discoloration effectively. 3. The color difference of films by chemical treatments increased after 8 hours. Color difference of films treated with 5 % acetic acid($CH_3COOH$), 30 % ethyl alchol ($CH_3CH_2OH$) showed 7.31 and 7.30 respectively. 1 % sodium hydroxide treatment showed 1.86 color difference after 8 hours.

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Antifungal Metabolisms of Streptomyces rimosus against Sapstain and Mold Fungi(I) -Antifungal Efficacy of Secondary Metabolites- (목재변색균(木材變色菌) 및 표면오염균류(表面汚染菌類)에 대(對)한 Streptomyces rimosus의 항균대사(抗菌代謝) (I) -2차(次) 대사물질(代謝物質)의 항균효능(抗菌效能)-)

  • Kang, Kyu-Young;Lee, Dong-Heub;Oh, Jung-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.1
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    • pp.42-48
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    • 1995
  • The purpose of this study is to evaluate the efficacy of metabolites produced form Streptomyces rimosus in controlling the growth of sapwood - inhabiting fungi. In order to carry out this task, the following specific fungi were tested : sapstain fungi - Ceratocystis pilifera, Ceratocystis piceae, and Aureobasidium pullulans ; mold fungi - Trichoderma hazianum, Trichoderma viride, Penicillium cirtrinum, and Aspergillus niger. Based on the tests, the following observations can be drawn. 1. The conidial germination of sapstain and mold fungi was completely inhibited leaving a clear zone around the paper disc treated with metabolites. The best inhibition was observed in A. pullulans plate and the least in T. viride. 2. Concentration of SB medium for the production of metabolites from St, rimosus affected antifungal activity of metabolites against sapwood - inhabiting fungi. Metabolites prepared from 1/3${\times}$SB medium showed the best activity and the least activity was observed in metabolites form 1/4${\times}$medium. 3. in vivo and in vitro test using wood blocks, treatment of pine sapwood blocks with metabolites also inhibited conidial germination and thus prevented discoloration. 4. Treatment with metabolites did not change the macroscopic structure of wood and did not cause the discoloration of the surface of wood by pigments produced form St. rimosus. In conclusion the results of this study indicate that antifungal metabloites of St, rimosus could be used for the biological control of sapstain and mold fungi.

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Chemical and Morphological Change and Discoloration of Cedar Wood Stored Indoor (실내 보관 삼나무 목재의 재색 및 화학적·현미경적 변화 특성)

  • Lee, Kwang Ho;Cha, Mi Young;Chung, Woo Yang;Bae, Hyeun-Jong;Kim, Yoon Soo
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.6
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    • pp.566-577
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    • 2009
  • The modification of wood color occurs rapidly during the service period at indoor. It is crucial to investigate the characteristics of color change, chemical and microscopical modification of wood at indoor. Wood products made of Japanese cedar at different years were used for this work. The tests were performed in order to evaluate the degree of color change of wood surface, breakpoint of brightness from surface to inside of wood, chemical analysis with FT-IR, and microscopical characteristics using the LM and TEM. Surface color of cedar wood stored indoor were rapidly changed at early stage, particularly ${\Delta}a$ (yellow), and ${\Delta}b$ (red) values were steeply decreased for one year old indoor wood, ${\Delta}L$ (white) value was dropped until 5 years old indoor wood compared with control sample. Decrease of peaks related to polysaccharide and lignin was noticed, especially, lignin was severely degraded. Although degradation of cell wall limited only to surface layers of indoor wood, degradation pattern of indoor wood showed similar degradation pattern to natural weathering of wood during outdoor weathering or wood behavior under artificial UV irradiation.

Control of Discoloration of Cedar Wood (Cryptomeria japonica) by Heat and UV Treatment (열처리와 자외선처리를 이용한 삼나무 재색제어)

  • Yoon, Kyung-Jin;Eom, Chang-Deuk;Park, Jun-Ho;Lee, Yang-Woo;Choi, In-Gyu;Lee, Jun-Jae;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.6
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    • pp.33-40
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    • 2008
  • Normally, cedar heartwood has a red color. However, it frequently changes black color (blackening phenomenon). It is reported that blackening phenomenon of cedar has been caused by oxidation of phenolics and norlignan extractives under weak alkaline conditions. In this study, heat treatment and UV irradiation were carried out to reduce the difference of color value between blackened wood and bright sap wood. Effects of temperature, moisture content, treatment time and light on decrease of color difference between blackened heartwood and sapwood were evaluated in each treatment. A decrement of different color value between blackened heartwood and bright sapwood by hot-water treatment was bigger than others. An effect of the vacuum drying was similar to that of the kiln drying. UV irradiation decreases the color difference between dried blackened heartwood and bright sapwood. It is suggested that UV irradiation could be used as final treatment to reduce the color difference on wood during drying process. Determination of optimum conditions and development of hybrid process for control of discoloration will be needed in a further study.

Study on the Discoloration Identified from the Column of Wooden house, Hyunchungsa(Shrine) - Focused on Influence of Microorganisms and Correlation with Strength - (현충사 옛집의 기둥 하부 변색에 관한 연구 - 미생물에 의한 영향 및 강도와의 상관관계를 중심으로 -)

  • Jeong, So-young;Seo, Min-seok;Hong, Jin-young;Kim, Soo-ji;Jeong, Ah-ruem;Kim, Ji-seo
    • Korean Journal of Heritage: History & Science
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    • v.47 no.4
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    • pp.58-73
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    • 2014
  • In general, it is thought discoloration on wood is frequently found in decorative wood products. So this study was conducted focusing on white rot found lower parts of columns and baseboards of a wooden house, Hyunchungsa (shrine) to know whether microorganisms have any influence on discoloration or there is correlation with strength by investigating resistograph, occurrence of microorganisms and microscopy for analysis(SEM, tissue analysis etc.). The results obtained were as follows: (1) The result of measurement of resistograph showed there are little correlation between discoloration and strength though there was a spot indicating low resistance. (2) The moisture content of discolored part was relatively higher than that of normal parts, but occurrence of microorganisms was less in discolored parts while more kinds of microorganisms were identified in normal parts with high CFU(Colony Forming Unit). (3) The result of SEM (with a magnification of 500 times) on the surface of discolored parts, it was found out there are many kinds of particles in different sizes on the surface and those were composed of elements such as C, O, Si, Ca, and a small amount of Na and Cl (weight %) were detected in part. (4) The result of tissue analysis showed discoloration occurs limitedly to the outer surface of column. As these results, it is concluded that discoloration has nothing to do with strength, damage by microorganisms and salt.

The Cause of Whitening by Flame Retardants Treatment on Korean Wooden Cultural Heritage

  • Kim, Jin Qyu;Chung, Yong Jae;Lee, Hwa Soo;Seo, Hyun Jeong;Son, Dong Won;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.4
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    • pp.589-599
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    • 2016
  • Korean wooden cultural heritages are treated by flame retardants to protect fire hazards. Two types of flame retardants are used to treat wooden cultural heritage. These flame retardants cause some problems such as surface whitening, discoloration, and cracks due to the chemical reaction caused by Korean traditional wood painting (Dancheong), flame retardant and wood humidity. The Korean government is trying to cut down on the amount of flame retardants for the wooden cultural heritage because of these problems. This study was carried out to find the cause of whitening by flame retardants treatment. The reaction between pigment and flame retardant chemicals was analyzed by infrared spectroscopy.

Hygroscopicity and Surface Hardness of Domestic Wood Heat-Treated at $220^{\circ}C$

  • Kang, Ho-Yang
    • Journal of the Korea Furniture Society
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    • v.19 no.4
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    • pp.229-234
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    • 2008
  • In a previous study, it was revealed that three major softwoods, Japanese pine, Korean pine and Japanese larch, heat-treated at $220^{\circ}C$, could produce high quality dark-colored boards. It is known that heat treatment decreases the hygroscopicity of wood. The hygroscopicity of major domestic softwoods and hardwoods heat-treated at $220^{\circ}C$ was investigated by a saturated salt solution method and compared with that of black and white charcoals. Equilibrium moisture contents of wood decreased with the increase of heat treatment time. Isotherm shapes of wood species were different from those of charcoals. Heat treatment decreases the equilibrium moisture contents of black locust more than those of Korean pine and Japanese larch. It was found that surface hardness of wood is improved by heat treatment to a certain extent, but a longer heat treatment causes thermal degradation, resulting in the decrease of the surface hardness.

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Manufacture of Rainbow-colored Veneer by Natural Dyeing

  • Suh, Jin Suk;Park, Ryeong Jae;Cho, Yeong Hee;Song, Eon Ja;Kim, Jong In;Park, Sang Bum
    • Journal of the Korea Furniture Society
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    • v.26 no.3
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    • pp.286-290
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    • 2015
  • The wood veneers were clearly rainbow-colored with natural dyes. As shown through Korean-style jacket with stripes of multi-colors beyond traditional obang colors (red, blue, yellow, black and white colors), eco-friendly coloring methods representing Korean colors familiar from old times could be used nobly by coloring natural wood veneer being raw material of wood products. In terms of industrialization, the study to manifest korean color, substituting chemical stains such as dye and pigment, would be necessary. In order to realize this purpose, the study about economical dyeing materials and characteristics, that is, mordant, dyeing and drying techniques showing environment-friendly coloring and high coloration level ought to be followed. In addition to this, investigating discoloration transition by fading test for interior and exterior uses would have to be carried out.

Shrinkages of Prefrozen or Presteamed Wood (전처리(前處理) 목재(木材)의 수축율(收縮率) 변화(變化))

  • Kang, Ho-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.1
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    • pp.66-71
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    • 1994
  • To increase drying rate and reduce drying degradation, pretreatments such as prefreezing and presteaming have been widely used in wood industries. Presteaming lumbers prior to kiln drying is known positively to improve its permeability, to increase diffusion coefficient and to reduce discoloration, but negatively to increase collapse. Prefreezing lumbers prior to kiln drying is also known to reduce significantly its drying defects and its shrinkages. Thus it is no doubt that the pretreated lumbers shrink diversely from the untreated. In this study the shrinkage behaviors of the pretreated specimens are investigated by drying two tropical hardwoods (Apitong and Taun) in three different dying conditions: high temperature and slow drying rate (drying in a closed cylinder), high temperature and rapid drying rate (drying in an oven) and low temperature and slow drying rate(drying at room temperature). The prefrozen specimens show the least volumetric shrinkages in most drying conditions. The specimens dried in cylinders shrink most among all drying conditions. In general the pretreated specimens reached the 30 % moisture content faster than the untreated by about 30 %.

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Discoloration Effects of LEDs on Painting Binder Materials (LED광원에 의한 회화 전색제의 변색 영향 연구)

  • Kim, Ji Won;Lee, Yu Jung;Kim, Kyu Lin;Lee, Hwa Soo;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.34 no.2
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    • pp.77-85
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    • 2018
  • In order to understand the influence of light artifact discoloration, priority must be given to the reaction characteristics of the light the materials constituting the product. In this study, we focus on two representative medium, animal glue and linseed oil which constitute the colored layer of the painting relics. This study is based on an accelerated degradation test using two types of light emitting diods (LEDs) with different wavelength characteristics. In the experiments, discoloration appeared markedly in the animal glue and linseed oil under accelerated aging test conditions using Blue LED. Among the two types of LEDs, the degree of discoloration of the material was much higher with the Blue LED having the total radiation flux (mW). This indicates that the discoloration of painting artifacts such as animal glue and linseed oil is more significantly influenced by the total radiation flux (mW) of the light source than the total luminous flux (lm).