• 한국표면공학회지
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• 제53권4호
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• pp.131-137
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• 2020

A series of Dy³⁺, Sm³⁺, and Dy³⁺/Sm³⁺ doped Gd₂WO₆ phosphors were synthesized by the conventional solid-state reaction. The X-ray diffraction patterns revealed that all of the diffraction peaks could be attributed to the monoclinic Gd₂WO₆ crystal structure, irrespective of the type and the concentration of activator ions. The photoluminescence (PL) excitation spectra of Dy³⁺-doped Gd₂WO₆ phosphors contained an intense charge transfer band centered at 302 nm in the range of 240-340 nm and two weak peaks at 351 and 386 nm. Under an excitation wavelength of 302 nm, the PL emission spectra consisted of two strong blue and yellow bands centered at 482 nm and 577 nm. The PL emission spectra of the Sm³⁺-doped Gd₂WO₆ phosphors had a series of three peaks centered at 568 nm, 613 nm, and 649 nm, corresponding to the ⁶G_5/2 → ⁶H_5/2, ⁶G_5/2 → ⁶H_9/2, and ⁶G_5/2 → ⁶H_11/2 transitions of Sm³⁺, respectively. The PL emission spectra of the Dy³⁺- and Sm³⁺-codoped Gd₂WO₆ phosphors showed the blue and yellow emission lines originating from the ⁴F_9/2 → ⁶H_15/2 and ⁴F_9/2 → ⁴H_13/2 transitions of Dy³⁺ and reddish-orange and red emission bands due to the ⁴G_5/2 → ⁶H_7/2 and ⁴G_5/2 → ⁶H_9/2 transitions of Sm³⁺. As the concentration of Sm³⁺ increased from 1 to 15 mol%, the intensities of two PL spectra emitted by the Dy³⁺ ions gradually decreased, while those of the three emission bands due to the Sm³⁺ ions slowly increased, thus producing the color change from white to orange. The CIE color coordinates of Gd₂WO₆:5 mol% Dy³⁺, 1 mol% Sm³⁺ phosphors were (0.406, 0.407), which was located in the warm white light region.

• 한국전기전자재료학회논문지
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• 제30권11호
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• pp.710-716
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• 2017

New white-light-emitting $SrSnO_3:Dy^{3+}$ phosphors were prepared using different concentrations of $Dy^{3+}$ ions via a solid-state reaction. The phase structure, luminescence, and morphological properties of the synthesized phosphors were investigated using X-ray diffraction analysis, fluorescence spectrophotometry, and scanning electron microscopy, respectively. All the synthesized phosphors crystallized in an orthorhombic phase with a major (020) diffraction peak, irrespective of the concentration of $Dy^{3+}$ ions. The excitation spectra were composed of a broad band centered at 298 nm, ascribed to the $O^2-Dy^{3+}$ charge transfer band and five weak bands in the range of 350~500 nm. The emission spectra of $SrSnO_3:Dy^{3+}$ phosphors consisted of three bands centered at 485, 577, and 665 nm, corresponding to the $^4F_{9/2}{\rightarrow}^6H_{15/2}$, $^4F_{9/2}{\rightarrow}^6H_{13/2}$, and $^4F_{9/2}{\rightarrow}^6H_{11/2}$ transitions of $Dy^{3+}$, respectively. As the $Dy^{3+}$ concentration increased from 1 to 15 mol%, the intensities of all the emission bands gradually increased, reached maxima at 15 mol% of $Dy^{3+}$ ions, and then decreased rapidly at 20 mol% due to concentration quenching. The critical distance between neighboring $Dy^{3+}$ ions for concentration quenching was calculated to be $9.4{\AA}$. The optimal white light emission by the $SrSnO_3:Dy^{3+}$ phosphors was obtained when the $Dy^{3+}$ concentration was 15 mol%.

• 천문학논총
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• 제15권spc1호
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• pp.103-112
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• 2000

Symbiotic stars are known as binary systems of a giant with heavy mass loss and a white dwarf accompanied by an emission nebula. They often show bipolar nebulae, and are believed to form an accretion disk around the white dwarf component by attracting the slow but heavy stellar wind around the giant companion. However, the existence and physical properties of the accretion disk in these systems still remain controversial. Unique to the spectra of symbiotic stars is the existence of the symbiotic bands around $6830{\AA}$ and $7088{\AA}$, which have been identified by Schmid (1989) as the Raman scattered features of the O VI $1032{\AA}$ and $1038{\AA}$ doublet by atomic hydrogen. Due to the incoherency of the Raman scattering, these features have very broad profiles and they are also strongly polarized. In the accretion disk emission model, it is expected that the Raman features are polarized perpendicular to the binary axis and show multiple peak structures in the profile, because the neutral scatterers located near the giant component views the accretion disk in the edge-on direction. Assuming the presence of scattering regions outflowing in the polar directions, we may explain the additional red wing or red peak structure, which is polarized parallel to the binary axis. We argue that in the accretion disk emission model it is predicted that the profile of the Raman feature around $6830{\AA}$ is different from the profile of the $7088{\AA}$ because the O VI line optical depth varies locally around the white dwarf component. We conclude that the Raman scattered features are an important tool to investigate the physical conditions and geometrical configuration of the accretion disk in a symbiotic star.

• 한국표면공학회지
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• 제47권4호
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• pp.192-197
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• 2014

Red-emitting nitride phosphors recently attracted considerable attention because of their high thermal stability and high color rendering index properties. For excellent phosphor of white light-emitting-diode, ternary nitride phosphor of $Sr/SmSi_5N_8:Eu^{2+}$ with different $Eu^{2+}$ ion concentration were synthesized by solid state reaction method. In this work, red-emitting nitride $Sr/SmSi_5N_8:Eu^{2+}$ phosphor was successfully synthesized by using multi-step high frequency induction heat treatment. The effects of molar ratio of component and experimental conditions on luminescence property of prepared phosphors have been investigated. The structure and luminescence properties of prepared $Sr/SmSi_5N_8:Eu^{2+}$ phosphors were investigated by XRD and photoluminescence spectroscopy. The excitation spectra of $Sr/SmSi_5N_8:Eu^{2+}$ phosphors indicated broad excitation wavelength range of 300 - 550 nm, namely from UV to visible area with distinct enhanced emission peaks. With an increase of $Eu^{2+}$ ion concentration, the peak position of emission in spectra was red-shifted from 613 to 671 nm. After via multi-step heat treatment, prepared phosphor showed excellent luminescence properties, such as high emission intensity and low thermal quenching, better than commercial phosphor of $Y_3Al_5O_{12}:Ce^{3+}$. Using $Eu_2O_3$ as a raw material for $Eu^{2+}$ dopant with nitrogen gas flowing instead of using commercial EuN chemical for $Sr/SmSi_5N_8:Eu^{2+}$ synthesis is one of characteristic of this work.

• 터널과지하공간
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• 제21권5호
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• pp.349-358
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• 2011

본 연구에서는 방사성폐기물처분장에서 발생하는 탄성파와 같이 낮은 신호 대 잡음비로 인하여 P파의 식별이 어려운 신호에 적합한 P파 도달시간 결정 알고리즘에 대한 연구를 수행하였다. 사용된 알고리즘은 임계 전압법, Akaike Information Criterion(AIC), Two step AIC, Hinkley criterion이며 샤프심 압절법에 의하여 생성된 탄성파 신호에 white noise를 적용하여 신호 대 잡음비를 낮추었다. 실험결과 임계전압, AIC, Hinkley criterion 알고리즘의 경우 배경잡음 수준이 증가함에 따라 P파 도달시간의 정확성은 감소하였으나 Two step AIC 알고리즘의 경우 1차적으로 결정된 P파의 도달시간 주변의 신호를 중심으로 특성함수와 AIC 알고리즘을 반복적으로 적용함에 따라 배경잡음 수준에 관계없이 정확한 결과를 나타냈다.

• 한국표면공학회지
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• 제54권3호
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• pp.112-118
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• 2021

Dy³⁺- and Eu³⁺-codoped BaWO₄ phosphors for white light-emitting diode were synthesized with different activator ions via a solid-state reaction process. The structural, morphological, and optical properties of the BaWO₄:Dy³⁺,Eu³⁺ phosphors were investigated as a function of Eu³⁺ concentration at a fixed concentration of Dy³⁺ ions. XRD patterns exhibited that all the synthesized phosphors had a tetragonal system, irrespective of the concentrations of Dy³⁺ and Eu³⁺ ions. The excitation spectra of the synthesized phosphors were composed of three intense bands centered at 251, 355, and 393 nm and several weak peaks. For the BaWO₄:Dy³⁺,Eu³⁺ phosphors synthesized with 1 mol% of Eu³⁺, the emission spectra under ultraviolet excitation at 393 nm showed two strong blue and yellow bands at 485 and 577 nm corresponding to the ⁴F_9/2⁶H_15/2 and ⁴F_9/2⁶H_13/2 transitions of Dy³⁺ ions, respectively and several weak bands in the range of 600-700 nm resulting from the 4f transitions of Eu³⁺ ions. As the concentration of Eu³⁺ ions increased, intensities of the blue and yellow emission bands gradually decreased while those of the red emissions increased rapidly and the energy transfer efficiency from Dy³⁺ to Eu³⁺ ions was 95.3% at 20 mol% of Eu³⁺. The optimum white light emission with x=0.363, y=0.357 CIE 1931 chromaticity coordinates was obtained for the sample doped with 5 mol% Dy³⁺ and 1 mol% of Eu³⁺.

• 한국재료학회지
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• 제16권3호
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• pp.145-150
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• 2006

Various colors of light emitting diodes(LED) and four-band white light sources are obtained using a violet LED and various phosphor films. $BaMg_2Al_{16}O_{27}:Eu\;(blue),\;SrGa_2S_4:Eu\;(green),\;and\;Eu(TTA)_3(PTA)$ (red) phosphors are dispersed in poly-vinyl-alcohol aqueous solutions, and phosphor films are prepared by coating the suspensions to PET film. The narrow band emission of $Eu(TTA)_3(PTA)$ phosphor has excellent red luminescent property for four-band white light excited by the violet LED.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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• pp.1403-1406
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• 2007

An effective WOLED structure was demonstrated which improved a luminous efficiency and white color chromaticity independent on applied bias by employing effective carrier transporting layer, without any alteration of emissive materials. The modified WOLEDs exhibited 2 times higher luminous efficiency than the control device and showed balanced white emission during an operation.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.343-346
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• 2001

To implementation of white electroluminescnet device in this paper, two methods were tried without synthesis of new white EL phosphor. At first, ZnS:Mn,Cl was mixed with ZnS:Cu from 20 to 50 weight percents. Second, ZnS:Mn,Cl was mixed with blue dye from 0 to 1.2 weight percents. The devices for experiments were measured as following; current-voltage, emission spectrum, brightness-voltage and CIE coordinate system and frequency properties.

• Applied Science and Convergence Technology
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• 제23권5호
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• pp.296-300
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• 2014

The synthesis of pure and rare-earth doped gallium oxide (${\beta}-Ga_2O_3$) nanoparticles is reported. The synthesized nanoparticles are characterized with XRD, TEM, and PL analyses. Strong blue emission is observed from un-doped gallium oxide nanoparticles, while nanoparticles doped with $Eu^{3+}$ and $Tb^{3+}$ give strong red and green emissions, respectively. When doped with $Eu^{3+}$ and $Tb^{3+}$ together, gallium oxide nanoparticles emit white light. The CIE coordinate of the emitted light was found to be (0.33, 0.33), which is well within the white light region.