• Title/Summary/Keyword: wet chemical reduction

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Development of Active Matrix Cathodes Composed of a-Si:H TFTs and Gated Molybdenum Field Emitter Arrays

  • Chung, Choong-Heui;Song, Yoon-Ho;Hwang, Chi-Sun;Ahn, Seong-Deok;Kim, Bong-Chul;Cho, Young-Rae;Lee, Jin-Ho;Cho, Kyoung-Ik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.1020-1023
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    • 2002
  • We successfully developed a-Si TFT controlled active matrix cathode (AMC) with gated Mo emitters. Also, we could remove emitter failures of the AMC through a novel surface treatment of Mo-tips, which indicates reduction of $MoO_3$ or chemical wet etching of $MoO_3$ by surface treatment. Transient behaviors of the AMC are strongly dependent on not only DC characteristics of device but also the device structure. Brightness and gray scale were well realized by low-voltage scan and data signals addressed to a-Si TFTs.

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The Electrochemical properties of Lithium ion Secondary Battery using Ag-deposited graphite anode (은 담지한 혹연을 부극 활물질로 이용한 Li ion 2차전지의 전기화학적 특성 연구)

  • 김상필;조정수;박정후;윤문수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.387-390
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    • 1998
  • New Ag-deposited graphite anodes were developed using wet chemical reduction methods for depositing Ag metal onto graphite particles. In this paper, we investigated X-ray diffraction pattern and charge-discharge behavior for Ag-deposited graphite anode. The Lithium ion cello using Ag-deposited graphite anode showed a high average discharge voltage of 3.6∼3.W and a excellent cycle ability than that of conventional graphite. Little capacity loss in this battery may be due to the highly durable Ag-deposited graphite anodes.

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Electron Beam Modification of Dual Phase Filler: Surface Characteristics and its Influence on the Properties of Styrene-Butadiene Rubber Vulcanizates

  • Shanmugharaj A. M.
    • Rubber Technology
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    • v.5 no.2
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    • pp.94-103
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    • 2004
  • The present work describes modification of dual phase filler by electron beam irradiation in presence of multifunctional acrylates like trimethylol propane triacrylate (TMPTA) or silane coupling agent like bis (3-triethoxysilylpropyltetrasulphide) and in-fluence of the modified fillers on the physical properties of styrene-butadiene rubber (SBR) vulcanizates. Modulus at 300 % elongation increases whereas the tensile strength decreases with increase in radiation dose for the dual phase filler loaded styrene-butadiene rubber vulcanizates (SBR). However, modulus and tensile strength significantly increase, which is more, pronounced at higher filler loadings for TMPTA modified dual phase filler loaded SBR. These changes in properties are explained by the equilibrium swelling data and Kraus plot interpreting the polymer-filler interaction. Electron beam modification of the filler results in a reduction of tan ${\delta}$ at $70^{\circ}C$, a parameter for rolling resistance and increase in tan ${\delta}$ at $0^{\circ}C$, a parameter for wet skid resistance of the SBR vulcanizates. Finally, the influence of modified fillers on the properties like abrasion resistance, tear strength and fatigue failure and the improvement in the properties have been explained in terms of polymer-filler interaction.

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Multi-scale agglomerates and photocatalytic properties of ZnS nanostructures

  • Man, Min-Tan;Lee, Hong-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.267.2-267.2
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    • 2016
  • Semiconductor photo-catalysis offers the potential for complete removal of toxic chemicals through its effective and broad potential applications. Various new compounds and materials for chemical catalysts were synthesized in the past few decades. As one of the most important II-VI group semiconductors, zinc sulfide (ZnS) with a wide direct band gap of 3.8 eV has been extensively investigated and used as a catalyst in photochemistry, environmental protection and in optoelectronic devices. In this work, the ZnS films and nanostructures have been successfully prepared by wet chemical method. We show that the agglomerates with four successive scales are always observed in the case of the homogeneous precipitation of zinc sulfide. Hydrodynamics plays a crucial role to determine the size of the largest agglomerates; however, other factors should be invoked to interpret the complete structure. In addition, studies of the photocatalytic properties by exposure to UV light irradiation demonstrated that ZnS nanocrystals (NCs) are good photo-catalysts as a result of the rapid generation of electron-hole pairs by photo-excitation and the highly negative reduction potentials of excited electrons. A combination of their unique features of high surface-to volume ratios, carrier dynamics and rich photo-catalytic suggests that these ZnS NCs will find many interesting applications in semiconductor photo-catalysis, solar cells, environmental remediation, and nano-devices.

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Synthesis of Titanium Carbide Nano Particles by the Mechano Chemical Process

  • Ahn, In-Shup;Park, Dong-Kyu;Lee, Yong-Hee
    • Journal of Powder Materials
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    • v.16 no.1
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    • pp.43-49
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    • 2009
  • Titanium carbides are widely used for cutting tools and grinding wheels, because of their superior physical properties such as high melting temperature, high hardness, high wear resistance, good thermal conductivity and excellent thermal shock resistance. The common synthesizing method for the titanium carbide powders is carbo-thermal reduction from the mixtures of titanium oxide($TiO_2$) and carbon black. The purpose of the present research is to fabricate nano TiC powders using titanium salt and titanium hydride by the mechanochemical process(MCP). The initial elements used in this experiment are liquid $TiCl_4$(99.9%), $TiH_2$(99.9%) and active carbon(<$32{\mu}m$, 99.9%). Mg powders were added to the $TiCl_4$ solution in order to induce the reaction with Cl-. The weight ratios of the carbon and Mg powders were theoretically calculated. The TiC and $MgCl_2$ powders were milled in the planetary milling jar for 10 hours. The 40 nm TiC powders were fabricated by wet milling for 4 hours from the $TiCl_4$+C+Mg solution, and 300 nm TiC particles were obtained by using titanium hydride.

Catalytic Reduction of Oxidized Mercury to Elemental Form by Transition Metals for Hg CEMS (수은 연속측정시스템에서 전이금속에 의한 산화수은의 원소수은으로의 촉매환원)

  • Ham, Sung-Won
    • Clean Technology
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    • v.20 no.3
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    • pp.269-276
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    • 2014
  • This study was aimed to develop catalytic system for the dry-based reduction of oxidized mercury ($Hg^{2+}$) to elemental mercury ($Hg^0$) which is one of the most important components comprising mercury continuous emission monitoring system (Hg-CEMS). Based on the standard potential in oxidation-reduction reaction, transition metals including Fe, Cu, Ni and Co were selected as possible candidates for catalyst proceeding spontaneous reduction of $Hg^{2+}$ into $Hg^0$. These transition metal catalysts revealed high activity for reduction of $Hg^{2+}$ into $Hg^0$ in the absence of oxygen in reactant gases. However, their activities were greatly decreased in the presence of oxygen, which was attributed to the transformation of transition metals by oxygen to the corresponding transition metal oxides with less catalytic activity for the reduction of oxidized mercury. Hydrogen supplied to the reactant gases significantly enhanced $Hg^{2+}$ reduction activity even in the presence of oxygen. It might be due to occurrence of combustion reaction between $H_2$ and $O_2$ causing the consumption of $O_2$ at such high reaction temperature at which oxidized mercury reduction reaction took place. Because the system showed high activity for $Hg^{2+}$ reduction to $Hg^0$, which was compatible to that of wet-chemistry technology using $SnCl_2$ solution, the catalytic reduction system of Fe catalyst with the supply of $H_2$ could be employed as a commercial system for the reduction of oxidized mercury to elemental mercury.

Mulberry Growth Promotion by Nitrogen Application under Abnormally Wet and Cool Weather Conditions (하추기 이상 저온하에서 뽕나무 발육부진요인과 추비에 의한 생육증진)

  • 이원주;윤명근
    • Journal of Sericultural and Entomological Science
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    • v.36 no.2
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    • pp.110-114
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    • 1994
  • Abnormally cool and wet weather conditions during the summer of 1993 offered an opportunity to evaluate the effects of abnormal weather conditions on mulberry growth and to develop cultivation practicies to reduce leaf yield loss under the similar abnormal weather conditions. Different methods of nutrient supplementation were evaluated in Suwon and Kongju. Nitrogen was supplemented by foliar spray of urea(1.7%) or composite chemical fertilizer Jamsibiryo #8, or by the application of ammonium sulfate(60kg/ha) to the soil. During the period between the late June and the early September which corresponds to the mulberry growing season after summer pruning, mean temperature was 1.4$^{\circ}C$ lower and precipitation 83mm higher than normal year. This weather condition in 1993 caused reduction in leaf yield by 16.4% than common year. Soil nitrogen content decreased due to higher precipitation. Leaf yield loss was reduced by the supplementation of nitrogen to the soil. Leaf nitrogen content increased with the foliar urea spray and nitrogen supplementation to the soil.

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Tin-Based Nanoparticles Prepared by a Wet Chemical Synthesis using Green Reducing and Capping Agents (화학적 습식 합성법에서 친환경 슈거 환원제 및 젤라틴 캡핑제에 의한 주석계 나노입자의 제조)

  • Chee, Sang-Soo;Yun, Young-En;You, Eun-Sun;Park, Sang-Hyun;Park, Sung-Young;Lee, Seok-Hee;Park, In-Seon;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.19 no.4
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    • pp.25-31
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    • 2012
  • In the synthesis of nanoparticles (NPs) via wet chemical reduction using tin(II) acetate precursor, the effects of green reducing agents (sugar) and a capping agent (gelatin) on the formation of NPs were analyzed as functions of synthesis conditions and time. When glucose was used as the reducing agent, it was observed that irregular chainlike shapes, aggregates of NPs, were formed during the synthesis at $70-110^{\circ}C$. The NPs were determined as $SnO_2$ from the fast Fourier transform (FFT) pattern. In the synthesis at $110^{\circ}C$ by using sucrose, fine spherical NPs of ~10 nm in diameter were formed after the synthesis time of 3 h. As the time increased to 9 h, the chainlike NP aggregates besides irregularly aggregated spherical NPs were also formed locally. However, the chainlike NP aggregates were only observed when the synthesis was conducted at $130^{\circ}C$. The spherical NPs and chainlike NP aggregates were analyzed to be pure Sn and $SnO_2$, respectively.

Preparation and Thermal Degradation Behavior of WO3-TiO2 Catalyst for Selective Catalytic Reduction of NOx (NOx 제거용 WO3-TiO2 계 SCR 촉매 제조 및 열적열화거동연구)

  • Shin, Byeongkil;Kim, Janghoon;Yoon, Sanghyeon;Lee, Heesoo;Shin, Dongwoo;Min, Whasik
    • Korean Journal of Metals and Materials
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    • v.49 no.8
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    • pp.596-600
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    • 2011
  • Thermal degradation behavior of a $WO_3-TiO_2$ monolithic catalyst was investigated in terms of structural, morphological, and physico-chemical analyses. The catalyst with 4 wt.% $WO_3$ contents were prepared by a wet-impregnation method, and a durability test of the catalysts were performed in a temperature range between $400^{\circ}C$ and $800^{\circ}C$ for 3 h. An increase of thermal stress decreased the specific surface area, which was caused by grain growth and agglomeration of the catalyst particles. The phase transition from anatase to rutile occurred at around $800^{\circ}C$ and a decrease in the Brønsted acid sites was confirmed by structural analysis and physico-chemical analysis. A change in Brønsted acidity can affect to the catalytic efficiency; therefore, the thermal degradation behavior of the $WO_3-TiO_2$ catalyst could be explained by the transition to a stable rutile phase of $TiO_2$ and the decrease of specific surface area in the SCR catalyst.

A Study on Technology Transfer of Bokto Seeding Method for Crop Production - Based on Theory of Asian and Pacific Center for Transfer of Technology(APCTT) - (복토직파재배기술의 수용과 기술 확산에 관한 연구 - 아시아태평양기술이전센터(APCTT) 이론을 중심으로 -)

  • Ahn, D.H.;Park, K.H.;Kang, Y.K.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.10 no.1
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    • pp.29-41
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    • 2008
  • This research was conducted to develop a technology transfer and farmer's extension of newly released technology of Bokto seeding method for crop and vegetable production based on the theory of Asian and Pacific Center for Transfer of Technology(APCTT). This technology has recently transferred to not only Korea but also other countries like North Korea, China, Japan, Taiwan, Russia and Africa(Cameroon, Sudan and South Africa) since 2005. It has known as a highly reduction of production cost in terms of labors, chemical fertilizer and pesticides as well as environmental friendly due to a deep and side banded placement of chemical fertilizer at basal application. In addition this technology was proven to a precision farming on sowing depth and mechanism of chemical application method and also highly resistant against disasters like typhoon, flooding, low temperature, drought and lodging due to silicate application. It has improved a constraints such as a poor seedling establishment, weed occurrence, lodging, low yield and poor grain and eating quality in the previous direct seeding methods but still have a problem in occurrence of weedy rice and ununiformed operation of wet or flooded soil condition. Also this technology has a limit in marketing and A/S system. Based on a theory of APCTT evaluation and analysis this technology may be more concentrated on establishment of a special cooperation team among researcher and scientists, extension workers, industry sections and governmental sectors in order to rapidly transfer this technology to farmer's field. Also there will be needed to operate a web site for this newly released technology to inform and exchange an idea, experiences and newly improved information. A feed back system might be operated in this technology as well to improve a technology under way on users' operation. Also user's manual will be internationally released and provided for farmer's instruction and training at field site.