• Title/Summary/Keyword: water-dispersion

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Multi-Walled Carbon Nanotube (MWCNT) Dispersion and Aerosolization with Hot Water Atomization without Addition of Any Surfactant

  • Ahn, Kang-Ho;Kim, Sun-Man;Yu, Il-Je
    • Safety and Health at Work
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    • v.2 no.1
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    • pp.65-69
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    • 2011
  • Objectives: Carbon nanotubes are an important new class of technological materials that have numerous novel and useful properties. Multi-walled carbon nanotubes (MWCNTs), which is a nanomaterial, is now in mass production because of its excellent mechanical and electrical properties. Although MWCNTs appear to have great industrial and medical potential, there is little information regarding their toxicological effects on researchers and workers who could be exposed to them by inhalation during the handling of MWCNTs. Methods: The generation of an untangled MWCNT aerosol with a consistent concentration without using surfactants that was designed to be tested in in vivo inhalation toxicity testing was attempted. To do this, MWCNTs were dispersed in deionized water without the addition of any surfactant. To facilitate the dispersion of MWCNTs in deionized water, the water was heated to $40^{\circ}C$, $60^{\circ}C$, and $80^{\circ}C$ depending on the sample with ultrasonic sonication. Then the dispersed MWCNTs were atomized to generate the MWCNT aerosol. After aerosolization of the MWCNTs, the shapes of the NTs were examined by transmission electron microscopy. Results: The aerosolized MWCNTs exhibited an untangled shape and the MWCNT generation rate was about 50 $mg/m^3$. Conclusion: Our method provided sufficient concentration and dispersion of MWNCTs to be used for inhalation toxicity testing.

Effect of Types and Mixing Ratios of Water-Soluble Polymers on In Vitro Release Profile of Sold Dispersion for Acyclovir (아시클로비어 고체분산체의 용해도에 대한 수용성 고분자의 종류 및 배합 비율에 따른 효과)

  • Ahn, Yong-San;Lee, Ha-Young;Hong, Keum-Duck;Jung, Sung-Beum;Cho, Sun-Hang;Rhee, John M.;Lee, Hai-Bang;Khang, Gil-Son
    • Journal of Pharmaceutical Investigation
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    • v.34 no.4
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    • pp.289-297
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    • 2004
  • Acyclovir (ACV) is one of the most effective and selective agents against viruses of the herpes group. Because of low solubility, bioavailability of ACV has shown below 30% with oral dosage form. In our previous study, we reported that the fabrication of solid dispersion of ACV was possible and the solid dispersion of ACV and PVP was the most useful in all samples. In this study, we examined the effect of mixture ratio of polymers (PEG and PVP) to ACV. Solubility of ACV was dramatically increased up to 25 mg/ml in $80^{\circ}C$ distilled water. So water was used as a solvent to eliminate problem of residual solvent. Spray drying method was used for the solid dispersion of ACV as solvent extraction. Different scanning calorimeter was used to check degradation of drug. Polymer carriers were PEG 6,000 and PVP. In summary, ACV-PVP (1:3) showed the best solubility in distilled water.

A numerical study on the dispersion of the Yangtze River water in the Yellow and East China Seas

  • Park, Tea-Wook;Oh, Im-Sang
    • Journal of the korean society of oceanography
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    • v.39 no.2
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    • pp.119-135
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    • 2004
  • A three-dimensional numerical model using POM (the Princeton Ocean Model) is established in order to understand the dispersion processes of the Yangtze River water in the Yellow and East China Seas. The circulation experiments for the seas are conducted first, and then on the bases of the results the dispersion experiments for the river water are executed. For the experiments, we focus on the tide effects and wind effects on the processes. Four cases of systematic experiments are conducted. They comprise the followings: a reference case with no tide and no wind, of tide only, of wind only, and of both tide and wind. Throughout this study, monthly mean values are used for the Kuroshio Current input in the southern boundary of the model domain, for the transport through the Korea Strait, for the river discharge, for the sea surface wind, and for the heat exchange rate across the air-sea interface. From the experiments, we obtained the following results. The circulation of the seas in winter is dependent on the very strong monsoon wind as several previous studies reported. The wintertime dispersion of the Yangtze River water follows the circulation pattern flowing southward along the east coast of China due to the strong monsoon wind. Some observed salinity distributions support these calculation results. In summertime, generally, low-salinity water from the river tends to spread southward and eastward as a result of energetic vertical mixing processes due to the strong tidal current, and to spread more eastward due to the southerly wind. The tide effect for the circulation and dispersion of the river water near the river mouth is a dominant factor, but the southerly wind is still also a considerable factor. Due to both effects, two major flow directions appear near the river mouth. One of them is a northern branch flow in the northeast area of the river mouth moving eastward mainly due to the weakened southerly wind. The other is a southern branch flow directed toward the southeastern area off the river mouth mostly caused by tide and wind effects. In this case, however, the tide effect is more dominant than the wind effect. The distribution of the low salinity water follows the circulation pattern fairly well.

Relationship Between Soil Water-Stable Aggregates and Physico-chemical Soil Properties (토양 내수성 입단과 토양특성과의 관계)

  • Hyun, Byung-Keun;Jung, Sug-Jae;Song, Kwan-Cheol;Sonn, Yeon-Kyo;Jung, Won-Kyo
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.1
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    • pp.57-63
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    • 2007
  • Soil aggregation has been considered as an important factor not only for increasing soil productivity and soil quality but also improving nutrient use availability and water use efficiency. However, the relationship between soil aggregation and soil properties hasn't well reported for Korean soils. Objective of this research was to identify the relationship among soil water-stable aggregate (WSA), soil properties and soil dispersion ratio. Soil samples were analyzed for water-stable aggregate, Middleton's dispersion ratio, and soil physical and chemical properties. Water-stable aggregate was significantly correlated to soil textural properties, soil organic matter, and exchangeable cations. Middleton's dispersion ratio was significantly correlated with water-stable aggregate ($r=-0.76^{***}$). Regression equation for water-stable aggregate was estimated by Middleton's dispersion ratio (Y=-0.79X + 96.49; $r^2=0.58^{**}$). In this research, we conclude that water-stable aggregate was significantly correlated with some soil properties and was able to be estimated by rapid and easily measurable Middleton's dispersion ratio.

Dispersion Polymerization of Acrylamide in Ethanol/water Media (에틸 알코올/물 혼합 용매에서 아크릴아미드의 분산 중합)

  • 이기창;이성은;송봉근
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.358-363
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    • 2003
  • Dispersion polymerization of acrylamide was carried out in the media of ethyl alcohol/water mixtures using hydroxypropyl cellulose and ammonium persulfate as steric stabilizer and initiator, respectively. The effects of concentrations of initiator and steric stabilizer, amount of monomer, polymerization temperature, ethyl alcohol/water ratio, and purification of monomer and nitrogen purge on the particle size of the latices and molecular weight of the polymers were investigated. The average particle diameter increased with increasing concentration of initiator, water content in ethyl alcohol/water media, and polymerization temperature, but decreased with monomer and stabilizer concentrations. The viscosity average molecular weight increased with increasing concentrations of monomer, steric stabilizer, and water content in dispersion media, but decreased with initiator concentration and polymerization temperature. The PAM polymers prepared with the purified monomer and the nitrogen purging before the reaction showed the highest molecular weight. In this study, PAM latices of 0.5∼2.4 $\mu\textrm{m}$ with 20000∼335000 in M$\_$v/ were prepared and the resulting PAM latices were all dissolved in water instantly.

Dispersion Characteristics Water-Based Magnetic Fluids Using Oleic Acid - Preparation and Re-Dispersion Characteristics of Water-Based Magnetic Fluid with Synthesized Magnetite(2) (오레인산에 의한 수상자성유체의 분산특성 - 합성마그네타이트에 의한 수상자성유체의 제고 및 재분산특성에 관한 연구(2))

  • Oh, Jae-Hyun;Kim, Sam-Ill;Kim, Mahn;Lee, Hong-lim
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.298-304
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    • 1994
  • Water-based magnetic fluids were made of the synthesized ultrafine magnetite with surfactants such as sodium oleate and loeic acid. The water-based magnetic fluid was prepared under the condition that added amounts of sodium oleate and oleic acid dissolved with NH4OH were 2.64$\times$10-2 mol, 1.5~2.0$\times$10-2 mol respectively. The water-based magnetic fluid was stable and should be dispersed well dispersion in the range of pH 9.0 to pH 11.0. As the solid content increased from 0.05 g/cc to 0.4 g/cc, the viscosity of water-based magnetic fluids increased from 2.5 cP to 152 cP and their magnetization at 5 KOe linearly increased from 3.1 emu/g to 26 emu/g. The aggregated powder after drying the water-based magnetic fluid was also successfully re-dispersed in dilute NH4OH solution and in kerosene.

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Development of Longitudinal Dispersion Coefficient Based on Theoretical Equation for Transverse Distribution of Stream-Wise Velocity in Open Channel : Part II. Longitudinal Dispersion Coefficient (개수로에서 흐름방향 유속의 횡분포 이론식에 기반한 종분산계수 개발 : II. 종분산계수)

  • Baek, Kyong Oh
    • Journal of Korea Water Resources Association
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    • v.48 no.4
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    • pp.299-308
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    • 2015
  • The aim of this study is that a theoretical formula for estimating the one-dimensional longitudinal dispersion coefficient is derived based on a transverse distribution equation for the depth averaged stream-wise velocity in open channel. In "Part I. Theoretical equation for stream-wise velocity" which is the former volume of this article, the velocity distribution equation is derived analytically based on the Shiono-Knight Method (SKM). And then incorporating the velocity distribution equation into a triple integral formula which was proposed by Fischer (1968), the one-dimensional longitudinal dispersion coefficient can be derived theoretically in "Part II. Longitudinal dispersion coefficient" which is the latter volume of this article. The proposed equations for the velocity distribution and the longitudinal dispersion coefficient are verified by using observed data set. As a result, the non-dimensional longitudinal dispersion coefficient is inversely proportional to square of the Manning's roughness coefficient and the non-dimensional transverse dispersion coefficient, and is directly proportional to square of the aspect ratio (channel width to depth).

The Effect of Coagulation for Dispersion Modelling of Spilled Oil (해상유출유의 분산모델링에 대한 응집효과)

  • 설동관
    • Journal of Ocean Engineering and Technology
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    • v.14 no.2
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    • pp.44-52
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    • 2000
  • The dispersion of surface oil is generally described as a break-up of oil slick into small oil droplets. These small droplets are subjected to turbulence and vertical circulation so that it can be entrained into subsurface. Sometimes they tend to be submerged into sea bottom permanently. The diameter of oil droplets is a critical parameter to determine their behavioral characteristics under water surface. At the same time the variations of droplet stability depends on the weathering of it. That is why the weathered oil has different mechanism from the unweathered one. The variability of physical properties of oil including viscosity and density contribute to interfere with effective separation of oil and emulsion droplets in water. Also in the presence of interactions among the droplets there are coalescing or coagulating effects on the dispersion process of droplets.

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