• Title/Summary/Keyword: water-absorption

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Evaluation of Anticorrosive Performance of Organic Coatings Subjected to Cyclic Wet-dry Exposure (흡 .탈수 반복 환경하에서의 유기도막의 방식성 평가)

  • 박진환;이근대;전호환
    • Journal of Ocean Engineering and Technology
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    • v.18 no.1
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    • pp.75-79
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    • 2004
  • Organic coatings are widely used to control of the corrosion of a steel structure. The water in coatings may cause the coatings to swell, leading to the degradation of the coatings. In addition, water affects the permeation of oxygen and other corrosive agents, and consequently, the presence of such substances at coating-metal interface promotes corrosion of the metal substrate. In this study, the anticorrosive properties of 4 types of coating, such as epoxy-epoxy, epoxy-urethane, urethane-epoxy, urethane-urethane, were evaluated. The evaluation tests were conducted under cyclic water-absorption/desorption conditions, consisting of alternative exposure to diluted 0.001M-LiCl(a$H_2O$≒1) and concentrated 10M-LiCl(a$H_2O$≒0.15). The anticorrosive performance of coatings was found to decrease in the order of urethane-urethane > urethane-epoxy > epoxy-epoxy coating.

Kinetics of the water absorption in GGBS-concretes: A capillary-diffusive model

  • Villar-Cocina, E.;Valencia-Morales, E.;Vega-Leyva, J.;Antiquera Munoz, J.
    • Computers and Concrete
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    • v.2 no.1
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    • pp.19-30
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    • 2005
  • We study the kinetics of absorption of water in Portland cement concretes added with 60, 70 and 80% of granulated blast furnace slag (GGBS) cured in water and at open air and preheated at 50 and $100^{\circ}C$. A mathematical model is presented that allows describing the process not only in early ages where the capillary sorption is predominant but also for later and long times where the diffusive processes through the finer and gel pores are considered. The fitting of the model by computerized methods enables us to determine the parameters that characterize the process: i.e., the sorptivity coefficient (S) and diffusion coefficient (D). This allows the description of the process for all times and offers the possibility to know the contributions of both, the diffusive and capillary processes. The results show the influence of the curing regime and the preheating temperature on the behavior of GGBS mortars.

Thermodynamic Analysis of an Absorption Heat Pump System with New Working Pairs[I] (1, 2종 흡수식 히트펌프의 작동 매체에 따른 성능 해석[I])

  • Won, S.H.;Lee, W.Y.;Chung, H.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.1 no.3
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    • pp.219-227
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    • 1989
  • Performance analysis of an absorption heat pump system for solar energy recovery has been done by computer simulation to find improved working pairs. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio have been calculated to compare two aqueous solutions [LiCl-water, $LiCi-CaCl_2-Zn(NO_3)_2$-water] which were developed for cooling by others, with the conventional LiBr-water solution. As a result of this analysis, the performances of the new aqueous solutions were found to be better than that of LiBr-water solution not only in cooling systems, but also in heating and in heat transformer systems. Their theoretical thermodynamic performance data were given here with.

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흡.탈수 반복 환경에 있어서 유기도막의 방식성 평가

  • Park, Jin-Hwan;Lee, Geun-Dae;Jeon, Ho-Hwan
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2003.05a
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    • pp.262-268
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    • 2003
  • Organic coatings are widely used to control the corrosion of steel structure. The water in coatings may cause swelling or solvation of coatings, leading to the degradation of coatings. In addition, water affects the permeation of oxygen and other corrosive agents, and consequently the presence of such substances at coating-metal interface promotes corrosion of metal substrate. In this study, the anticorrosive properties of 4 types of coating, such as epoxy-epoxy, epoxy-urethane, urethane-epoxy, urethane-urethane, were evaluated. The evaluation tests were carried out under cyclic water-absorption/desorption conditions, consisting of alternative exposure to diluted 0.001M-LiCl($a_{1120}{\fallingdotseq}1$) and concentrated l0M-LiCl($a_{1120}{\fallingdotseq}0.05$). The anticorrosive performances of coatings were found to decrease in the order of urethane-urethane> urethane-epoxy> epoxy-epoxy coating.

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Optical Properties of Water (II) - Variation in the Coastal Sea Water Near Busan in Winter and Spring - (해수의 광학적 성질에 관한 연구 (II) - 부산근해의 하계 및 춘계 변화 -)

  • 양용림
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.12 no.1
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    • pp.7-12
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    • 1976
  • The optical properties of the sea water were studied by use of underwater photometers in the coastal waters of Busan, from December 1975 to May 1976. The absorption coefficient of the sea water in the area ranged from 0.223 to 0.901 and the mean was 0.355. Maximum valae of monthly mean was 0.454 in December, while the minium was 0.301 in January. The transparency in winter was higher than that in spring and the mean was 4. 7 meters. The relation between absorption coefficient (m) and transparency (D) was m= 1. 67/ D. The rate of light penetration at 5 m-layer in the area ranged from 1. 73 to 24.09 percent and the mean was 13.63 percent, while the rate at 10 m-layer ranged from 0.067 to 8.05 percent and the mean was 2.95 percent.

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Validation of Ocean Color Algorithms in the Ulleung Basin, East/Japan Sea

  • Yoo, Sin-Jae;Park, Ji-Soo;Kim, Hyun-Cheol
    • Korean Journal of Remote Sensing
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    • v.16 no.4
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    • pp.315-325
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    • 2000
  • Observations were made to validate ocean color algorithms in the Ulleung Basin, East Sea in May 2000. Small scale and meso-scale surveys were conducted for the validation of ocean color products (nLw: normalized water-leaving radiance and chlorophyll concentration). There were discrepancies between SeaWiFS and in situ nLw showing the current aerosol models of standard SeaWiFS processing software are less than adequate (Gordon and Wang, 1994). Applying the standard SeaWiFS in-water algorithm resulted in an overestimation of chlorophyll concentration. This is because that CDOM absorption was higher than the estimated chlorophyll absorption. TSS concentration was also high. Therefore, the study region deviated from Case 1 waters. The source of these materials seems to be the entrainment of coastal water by the Tsushima Warm Current. Study of the bio-optical properties in other season is desirable.

Thermal Design Analysis of an Absorption Heat Transformer for using Waste Hot Water (폐온수 이용 제 2 종 흡수식 열펌프의 열역학적 설계해석)

  • Kang, Byung-Ha;Kim, Young-In;Lee, Chun-Sik
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.14 no.4
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    • pp.285-292
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    • 1985
  • A computer program for thermal design analysis has been developed to predict the performance of an absorption heat transformer. The effects of temperature boost, cooling water temperature and effectiveness of components on the performance were investigated. Not only the detailed thermodynamic states such as temperatures, concentration of the solution, and mass flow rate at each point of the process but also the heat transfer rate in each component could be easily determined with given input parameters. The system's coefficient of performance (COP) was seen to increase with increased effectiveness of components, decreased temperature boost of hot water, and decreased cooling water temperature. Even though the COP increases with increased effectiveness of the components, the variation in the COP is not substantial above certain values of the effectiveness. A reference design point can be selected on this basis.

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Characterization of fine particulate matter during summer at an urban site in Gwangju using chemical, optical, and spectroscopic methods (화학적·광학적·분광학적 방법을 이용한 광주 도심지역 여름철 초미세먼지의 특성)

  • Son, Se-Chang;Park, Tae-Eon;Park, Seungshik
    • Particle and aerosol research
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    • v.17 no.4
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    • pp.91-106
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    • 2021
  • Daily PM2.5 was collected during summer period in 2020 in Gwangju to investigate its chemical and light absorption properties. In addition, real-time light absorption coefficients were observed using a dual-spot 7-wavelength aethalometer. During the study period, SO42- was the most important contributor to PM2.5, accounting for on average 33% (10-64%) of PM2.5. The chemical form of SO42- was appeared to be combination of 70% (NH4)2SO4 and 30% NH4HSO4. Concentration-weighted trajectory (CWT) analysis indicated that SO42- particles were dominated by local pollution, rather than regional transport from China. A combination of aethalometer-based and water-extracted brown carbon (BrC) absorption indicated that light absorption of BrC due to aerosol particles was 1.6 times higher than that due to water-soluble BrC, but the opposite result was found in absorption Ångström exponent (AAE) values. Lower AAE value by aerosol BrC particles was due to the light absorption of aerosol BrC by both water-soluble and insoluble organic aerosols. The BrC light absorption was also influenced by both primary sources (e.g., traffic and biomass burning emissions) and secondary organic aerosol formation. Finally the ATR-FTIR analysis confirmed the presence of NH4+, C-H groups, SO42-, and HSO42-. The presence of HSO42- supports the result of the estimated composition ratio of inorganic sulfate ((NH4)2SO4) and bisulfate (NH4HSO4).

Preparation and Super-Water-Absorbency of Poly(sodium acrylate-co-acrylamide-co-2-hydroxyethyl acrylate) (Poly(sodium acrylate-co-acrylamide-co-2-hydroxyethyl acrylate)의 제조와 고흡수 특성)

  • Zhang Yuhong;Deng Min;He Peixin
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.286-292
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    • 2006
  • Super water-absorbent resins were prepared by inverse suspension copolymerization of sodium acrylate, acrylamide and 2-hydroxyethyl acrylate using N, N'-methylene-bis-acrylamide as cross-linker. For the suspension copolymerization, monohexadecyl phosphate was employed as the dispersing agent, cyclohexane as the dispersing medium and potassium persulfate as the initiator. The dependence of water-absorption capacity on the amount of crosslinking agent, oil/water ratio, degree of neutralization and the composition of the copolymer were systematically investigated. Furthermore, the swelling kinetics of the super water-absorbent copolymer was carried out. The absorption of the resins is more than 1800 g/g for deionized water and 100 g/g for 0.9% NaCl solution, respectively. The copolymers showed an increased salt resistance and enhanced water retention of soil.

A Study on the Surface Characteristics of Phenolic Resin by Water Treatment (수처리에 의한 페놀수지의 표면특성에 관한 연구)

  • Choi, Chung-Seog;Shong, Kil-Mok;Kim, Hyung-Rae;Kim, Dong-Woo;Kim, Hyang-Kon;Kim, Dong-Ook
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1431-1433
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    • 2002
  • In this paper, we studied the characteristics of surface structure of phenolic resin by water treatment. Phenolic resin which is used as indoor insulators is easily deteriorated by humidity. Water treated sample for 200 hours is subjected to the penetration of water and cracked partially. Water treated sample for 400 hours is found more cracks than that for 200 hours. The initial leakage current of virgin sample is 0.11A, that of water treated sample for 200 hours is 0.07A, and that of water treated sample for 400 hours is 0.05A. FT-IR analysis indicates that absorption peak of carbonyl group appears in virgin sample, but the absorption peak does not appear in water treated sample for 200 hours.

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