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Development of analytical method for the isotope purity of pure D2 gas using high-precision magnetic sector mass spectrometer

  • Chang, Jinwoo;Lee, Jin Bok;Kim, Jin Seog;Lee, Jin-Hong;Hong, Kiryong
    • Analytical Science and Technology
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    • v.35 no.5
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    • pp.205-211
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    • 2022
  • Deuterium (D) is an isotope with one more neutron number than hydrogen (H). Heavy elements rarely change their chemical properties with little effect even if the number of neutrons increases, but low-mass elements change their vibration energy, diffusion rate, and reaction rate because the effect cannot be ignored, which is called an isotope effect. Recently, in the semiconductor and display industries, there is a trend to replace hydrogen gas (H2) with deuterium gas (D2) in order to improve process stability and product quality by using the isotope effect. In addition, as the demand for D2 in industries increases, domestic gas producers are making efforts to produce and supply D2 on their own. In the case of high purity D2, most of them are produced by electrolysis of heavy water (D2O), and among D2, hydrogen deuteride (HD) molecules are present as isotope impurities. Therefore, in order to maximize the isotope effect of hydrogen in the electronic industry, HD, which is an isotope impurity of D2 used in the process, should be small amount. To this end, purity analysis of D2 for industrial processing is essential. In this study, HD quantitative analysis of D2 for high purity D2 purity analysis was established and hydrogen isotope RM (Reference material) was developed. Since hydrogen isotopes are difficult to analyze with general gas analysis instrument, they were analyzed using a high-precision mass spectrometer (Gas/MS, Finnigan MAT271). High purity HD gas was injected into Gas/MS, sensitivity was determined by a signal according to pressure, and HD concentrations in two bottles of D2 were quantified using the corresponding sensitivity. The amount fraction of HD in each D2 was (4518 ± 275) μmol/mol, (2282 ± 144) μmol/mol. D2, which quantifies HD amount using the developed quantitative analysis method, will be manufactured with hydrogen isotope RM and distributed for quality management and maintenance of electronic industries and gas producers in the future.

Growth and Yield Response of Perilla Plants Grown under Different Substrates in Hydroponic System (잎들깨 수경재배에서 배지 종류에 따른 식물 생육 및 수량의 반응)

  • Shin, Minju;Jeong, Ho Jeong;Roh, Mi Young;Kim, Jin Hyun;Song, Kwan Jeong
    • Journal of Bio-Environment Control
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    • v.31 no.4
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    • pp.292-299
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    • 2022
  • This study was conducted to analyze physical and chemical properties of horticultural substrates and response of hydroponically grown two cultivars of 'Namcheon' and 'Somirang' perilla by four different substrates: coir (chip:dust = 5:5), perlite, granular rockwool, and commercial mixed substrate (cocopeat:peatmoss:vermiculite:perlite: zeolite = 50:25:10:10:5). There were no significant differences in EC and pH according to substrates. Container capacity was the greatest in granular rockwool, and it showed appropriate levels in mixed substrate and coir. Air space was higher in coir and perlite than the other treatments. Bulky density reached a proper standard in all substrates excepting coir. The leaf length and width of 'Namcheon' indicated the most in mixed substrate, though the value of 'Somirang'was greatest in coir substrate. The leaf weight of both cultivars was highest in mixed substrate, and relatively low in coir and perlite. The total yield of leaves was separated by two groups: higher group, which are mixed substrate and granular rockwool, and lower group, which are coir and perlite. There was a large gap by 28% between these two groups. Therefore, this study suggests that substrates with high water holding capacity such as mixed substrate or granular rockwool are most suitable for the hydroponic cultivation of perilla, which require sufficient moisture supply to the root zone.

Effects of fermented soybean meal with Bacillus velezensis, Lactobacillus spp. or their combination on broiler performance, gut antioxidant activity and microflora

  • Tsai, C.F.;Lin, L.J.;Wang, C.H.;Tsai, C.S.;Chang, S.C.;Lee, T.T.
    • Animal Bioscience
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    • v.35 no.12
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    • pp.1892-1903
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    • 2022
  • Objective: A series of experiment were conducted to evaluate the effects of replacing a part of soybean meal (SBM) at 6% of broiler diets with fermented soybean meal (FSBM) obtained by single or two-stage fermentation by measuring growth performance, antioxidant activity in the jejunum and distal intestinal microflora. Methods: Soybean meal samples were prepared by single-stage fermentation using Bacillus velezensis (Bv) (FSBMB), or Lactobacillus spp. (as commercial control) (FSBML). Additional SBM sample was prepared by two-stage fermentation using Bv and subsequently using Lactobacillus brevis ATCC 367 (Lb) (FSBMB+L). Enzyme activity, chemical composition, trichloroethanoic acid-nitrogen solubility index (TCA-NSI) and antioxidant activity were measured. Then, in an in vivo study, 320 Ross308 broilers were divided into four groups with ad libitum supply of feed and water. Four groups were fed either a corn-soybean meal diet (SBM), or one of fermented SBM diets (FSBMB+L, FSBMB, and FSBML). Growth, serum characteristics, microflora, and the mRNA expression of selected genes were measured. Results: Compared to SBM, FSBMB+L contained lower galacto-oligosaccharide, allergic protein, and trypsin inhibitor, and higher TCA-NSI by about three times (p<0.05). Reducing power and 1,1-diphenyl-2-picrylhydrazyl free radical scavenging ability correlated positively with the TCA-NSI content in FSBM. Growth performances were not significantly different among four groups. In jejunum of 35-day-old broilers, partial replacement of SBM by FSBMB+L increased the activity of superoxide dismutase and catalase (CAT), and the FSBMB group had the highest catalase activity (p<0.05). Partial replacement of SBM by FSBM increased relative mRNA expressions of nuclear factor erythroid 2-related factor 2 (Nrf2), heme oxygenase-1 (HO-1), and peptide transporter 1 (PepT1) (p<0.05); however, FSBMB+L increased CAT mRNA level to 5 times of the control (p<0.05). Conclusion: Using Bv- and Lb-processed SBM through two-stage fermentation to partially replace 6% of diets will improve the gut's antioxidant activity under commercial breeding in broilers.

Development of 3D Underground Information Construction and Visualization System Based on IUGIM (지하공간통합지도 기반 3차원 지하정보 구축 및 가시화시스템 개발)

  • Kang, Kyung Nam;Kim, Wooram;Hwang, Seung Hyun;An, Joon Sang
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.39 no.6
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    • pp.497-505
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    • 2021
  • Due to recent underground space accidents, are a frequent occurence in Korea, the government established the basic plan for the construction of the IUGIM (Integrated Underground Geospatial Information Map) in 2015 as a measure for safety management of underground spaces. The development of IUGIM was partially completed as of 2021. The underground space management entity and related organizations are utilizing it. This study is being carried out as part of a plan to improve the usability of IUGIM, and to build a visualization system that compares real-time field data with stored data. A system, equipped with a visualization function for borehole data and 6 types of underground facilities built and managed on IUGIM; a tool capable of comparative analysis with real-time data measured in the field, is being built. The 6 types of underground facilities are water supply pipe, sewage pipe, power pipe, gas pipe, communication pipe, and heating pipe. The completed system was demonstrated at three locations in Seocho-gu, Gangnam-gu in Seoul. The field demonstration was carried out by accessing the mobile center and downloading IUGIM data, visualizing IUGIM data (surface creation, borehole information, underground facilities), and visualizing the GPR(Ground Penetrating Radar)-based data acquired at the field. As a result of the empirical results of IUGIM data and GPR-based field data, it was judged to be suitable. As a result of this study, it is judged that it can be helpful for safe construction at the excavation site.

Transition of Rice Cultural Practices during Chosun Dynasty through Old References II. Investigation of Rice Culture Practice in Ancient China (주요 고농서를 통한 조선시대의 도작기술 전개과정 연구 II. 고대중국의 도작기술 개요 탐색)

  • Lee, Sung-Kyum;Guh, Ja-Ok;Lee, Eun-Woong;Lee, Hong-Suk
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.3
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    • pp.280-285
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    • 1991
  • The rice culture techniques of the ancient China which have played a key role directly and indirectly, in development of ancient farming and its techniques of Korea, were established before Christ in terms of dry-farming and the spirit of the farming-first principle. Especially techniques of rice culture were developed by cultivation methods for deep plowing, storage of water and preservation use of soil fertility. Therefore, the techniques of transplanting methods, seeding in rows, use of iron-made farming tools and dam construction for irrigation were advanced. And rice varieties were differentiated to avoid disasters or to supply of rice for various uses in many areas. Also, because north China was the origin of Chinese agriculture in which population density was low and flat land was wide that were the cradle of Chinese agriculture, ‘Hwayungsunubeob’(firing and drawning weed control method) and fallowing were quickened as intensive techniques of rice culture. In connection with the view of agricuture with 'the theory of the cosmic dual forces and the five primary substances' of Han Mooje and Chamwye scholars, the techniques of seeding and selection of crops were gradually developed. From ‘Jeminyosul’ of the 6th century to ‘Wangjongnongseo’ of the 14th century, the techniques of rice culture have been developed continuously and additively, but were not improved thereafter Won dynasty. From this point of time, the time of agriculture in the end of Koryo age and by ‘Nongsajiksul’ were initiated.

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MXene Based Composite Membrane for Water Purification and Power Generation: A Review (정수 및 발전을 위한 맥신(MXene) 복합막에 관한 고찰)

  • Seohyun Kim;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.4
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    • pp.181-190
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    • 2023
  • Wastewater purification is one of the most important techniques for controlling environmental pollution and fulfilling the demand for freshwater supply. Various technologies, such as different types of distillations and reverse osmosis processes, need higher energy input. Capacitive deionization (CDI) is an alternative method in which power consumption is deficient and works on the supercapacitor principle. Research is going on to improve the electrode materials to improve the efficiency of the process. A reverse electrodialysis (RED) is the most commonly used desalination technology and osmotic power generator. Among many studies conducted to enhance the efficiency of RED, MXene, as an ion exchange membrane (IEM) and 2D nanofluidic channels in IEM, is rising as a promising way to improve the physical and electrochemical properties of RED. It is used alone and other polymeric materials are mixed with MXene to enhance the performance of the membrane further. The maximum desalination performances of MXene with preconditioning, Ti3C2Tx, Nafion, and hetero-structures were respectively measured, proving the potential of MXene for a promising material in the desalination industry. In terms of osmotic power generating via RED, adopting MXene as asymmetric nanofluidic ion channels in IEM significantly improved the maximum osmotic output power density, most of them surpassing the commercialization benchmark, 5 Wm-2. By connecting the number of unit cells, the output voltage reaches the point where it can directly power the electronic devices without any intermediate aid. The studies around MXene have significantly increased in recent years, yet there is more to be revealed about the application of MXene in the membrane and osmotic power-generating industry. This review discusses the electrodialysis process based on MXene composite membrane.

Site Suitability Assessment Using the Habitat Suitability Index for Oyster (Crassostrea gigas) in Jaran Bay, Korea (서식지 적합 지수를 이용한 자란만 굴(Crassostrea gigas)의 어장적지평가)

  • Yong-Hyeon Choi;Sok Jin Hong;Dae In Lee;Won Chan Lee;Seung Ryul Zeon;Yoon-Sik Cho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.5
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    • pp.427-434
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    • 2023
  • Oysters are an important organism, accounting for an average of 76% of shellfish aquaculture production. In this study, optimal habitat was searched for by calculating the Habitat Suitability Index (HSI) using water temperature, salinity, hydrodynamics, DO, SS and Chl.a in Jaran Bay. As a result, the inside of Jaran Bay was found to be a more suitable habitat than the outside with a wide entrance and rapid hydrodynamics. Oyster production and HSI showed a significant correlation (0.710, p<0.05). Hydrodynamics helps the growth of aquaculture organisms, such as food supply through seawater exchange in the bay, which showed a high correlation (0.709, p<0.05) with oyster production. It was found to have a greater effect on habitat suitability than Chl.a. The results of this study are expected to be helpful for the efficient conservation, use and management of coastal fisheries.

Effect of Fertilizer Deep Placement on Rice and Soybean Yield Using Newly Developed Device for Deep Fertilization (신개발 심층시비장치를 이용한 심층시비가 벼와 콩 수량에 미치는 영향)

  • Sung-Chang Hong;Min-Wook Kim;Jin-Ho Kim
    • Korean Journal of Environmental Agriculture
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    • v.42 no.1
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    • pp.44-51
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    • 2023
  • Nitrogen fertilizer is an essential macronutrient that requires repeated input for crop cultivation. Excessive use of nitrogen fertilizers can adversely affect the environment by discharging NH3, NO, and N2O into the air and leaching into surrounding water systems through rainfall runoff. Therefore, it is necessary to develop a technology that reduces the amount of nitrogen fertilizer used without compromising crop yields. Fertilizer deep placement could be a technology employed to increase the efficiency of nitrogen fertilizer use. In this study, a deep fertilization device that can be coupled to a tractor and used to inject fertilizer into the soil was developed. The deep fertilization device consisted of a tractor attachment part, fertilizer amount control and supply part, and an underground fertilizer input part. The fertilization depth was designed to be adjustable from the soil surface down to a depth of 40 cm in the soil. This device injected fertilizer at a speed of 2,000 m2/hr to a depth of 25 to 30 cm through an underground fertilizer injection pipe while being attached to and towed by a 62-horsepower agricultural tractor. Furthermore, it had no difficulty in employing various fertilizers currently utilized in agricultural fields, and it operated well. It could also perform fertilization and plowing work, thereby further simplifying agricultural labor. In this study, a newly developed device was used to investigate the effects of deep fertilizer placement (FDP) compared to those with urea surface broadcasting, in terms of rice and soybean grain yields. FDP increased the number of rice grains, resulting in an average improvement of 9% in rice yields across three regions. It also increased the number of soybean pods, resulting in an average increase of 23% in soybean yields across the three regions. The results of this study suggest that the newly developed deep fertilization device can efficiently and rapidly inject fertilizer into the soil at depths of 25 to 30 cm. This fertilizer deep placement strategy will be an effective fertilizer application method used to increase rice and soybean yields, in addition to reducing nitrogen fertilizer use, under conventional rice and soybean cultivation conditions.

Ground Subsidence Risk Grade Prediction Model Based on Machine Learning According to the Underground Facility Properties and Density (기계학습 기반 지하매설물 속성 및 밀집도를 활용한 지반함몰 위험도 예측 모델)

  • Sungyeol Lee;Jaemo Kang;Jinyoung Kim
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.4
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    • pp.23-29
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    • 2023
  • Ground subsidence shows a mechanism in which the upper ground collapses due to the formation of a cavity due to the movement of soil particles in the ground due to the formation of a waterway because of damage to the water supply/sewer pipes. As a result, cavity is created in the ground and the upper ground is collapsing. Therefore, ground subsidence frequently occurs mainly in downtown areas where a large amount of underground facilities are buried. Accordingly, research to predict the risk of ground subsidence is continuously being conducted. This study tried to present a ground subsidence risk prediction model for two districts of ○○ city. After constructing a data set and performing preprocessing, using the property data of underground facilities in the target area (year of service, pipe diameter), density of underground facilities, and ground subsidence history data. By applying the dataset to the machine learning model, it is evaluated the reliability of the selected model and the importance of the influencing factors used in predicting the ground subsidence risk derived from the model is presented.

Growth and Seedling Quality of Hovenia dulcis Thunb. Container Seedlings (1-0) According to Fertilization Levels of Water-soluble Fertilizers (수용성 비료의 시비수준에 따른 헛개나무 용기묘(1-0)의 생장 및 묘목품질)

  • Hyeok Lee;Jun-Hyuck Yoon;Do-Hyung Lee
    • Journal of Korean Society of Forest Science
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    • v.112 no.2
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    • pp.136-144
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    • 2023
  • This study aimed to determine the optimal fertilization level for the production of Hovenia dulcis Thunb. seedlings. The height, root collar diameter, biomass, seedling quality index, and chlorophyll content of Hovenia dulcis container seedlings (1-0) according to six fertilization treatments (control, 0.5, 1.0, 1.5, 2.0, 2.5 g·L-1) were investigated. The height, root collar diameter, and biomass of Hovenia dulcis container seedlings increased with increasing fertilization, but there were no significant differences among the ≥1.5 g·L-1 treatments, and the 2.5 g·L-1 fertilization treatment was associated with significantly lower height growth. The seedling-quality index showed a high but non-significant difference in the ≥1.5 g·L-1 treatment range, and the chlorophyll content was highest in the 1.5 g·L-1 treatment group. Considering the environmental and cost aspects of fertilization, the appropriate level of fertilization required for superior container seedling production of Hovenia dulcis was 1.5 g·L-1, and a minimum fertilization treatment of ≥0.5 g·L-1 should be applied to meet the minimum seedling specifications. These results are expected to be used as basic data for establishing an efficient seedling-production system and stable supply of Hovenia dulcis, which is used as a medicinal and honey plant.