• Korean Journal of Materials Research
• /
• v.31 no.11
• /
• pp.642-648
• /
• 2021

The precipitation effect of Al-6%Si-0.4%Mg-0.9%Cu-(Ti) alloy (in wt.%) after various heat treatments was studied using a laser flash device (LFA) and differential scanning calorimetry (DSC). Solid solution treatment was performed at 535 ℃ for 6 h, followed by water cooling, and samples were artificially aged in air at 180 ℃ and 220 ℃ for 5 h. The titanium-free alloy Al-6%Si-0.4%Mg-0.9%Cu showed higher thermal diffusivity than did the Al-6%Si-0.4%Mg-0.9%Cu-0.2%Ti alloy over the entire temperature range. In the temperature ranges below 200 ℃ and above 300 ℃, the value of thermal diffusivity decreased with increasing temperature. As the sample temperature increased between 200 ℃ and 400 ℃, phase precipitation occurred. From the results of DSC analysis, the temperature dependence of the change in thermal diffusivity in the temperature range between 200 ℃ and 400 ℃ was strongly influenced by the precipitation of θ'-Al₂Cu, β'-Mg₂Si, and Si phases. The most important factor in the temperature dependence of thermal diffusivity was Si precipitation.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2003.05a
• /
• pp.669-674
• /
• 2003

The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady-state within about five hours after exposure. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2000.10a
• /
• pp.425-428
• /
• 2000

When concrete structures are exposed to sulfate or marin environments, sulfate ions penetrated into concrete make it deteriorate. An accelerated test under potential difference method was performed to evaluate not only the sulfate ion diffusivity in ordinary portland cement and ground granulated blast-furnace slag cement concretes but the effect of slag replacement and water-cement ratio on the sulfate ions diffusivity. As the result of this study, we assumed the sulfate ion diffusivity was significantly related with total passed charge and initial current in concrete. Moreover sulfate ions penetration resistance of ordinary portland cement concrete was superior to that of ground granulated blast-furnace slag cement concrete.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1996.10a
• /
• pp.260-265
• /
• 1996

Polyproplyene Fibers have many advantages such as light weight, low cost, chemical stability and duragbility. It has been reported that polypropylene fiber can increase the toughness of concrete and the resistance to crack formation. This study has been performed to investigate the dirability related properties such as permeability and diffusivity of polypropylene fiber reinforced concrete. The permeability and diffusivity were measured with GWT, Poroscope, and electrical conductivity of concrete. From the test result, it is found that the addition of the polypropylene fiber improved the permeability and diffusivity of concrete, when the workability reduction was corrected by water reducer. The relationships between the permeability and diffusivity, and other properties of polypropylene fiber reinforced concrete showed that the tesst results are interrelated each other.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.29 no.4A
• /
• pp.365-371
• /
• 2009

It is time-consuming to estimate chloride diffusivity of concrete by concentration difference test. For the reason chloride diffusivity of concrete is mainly tested by electrically accelerated method, which is accelerating the movement of chloride ion by potential difference. In this study, portland cement concrete and concrete containing with ground granulated blast-furnace slag (40 and 60% of cement by weight) with water-cementitious material ratio 40, 45, 50 and 60% were manufactured. To compare with chloride diffusivity calculated from the electrically accelerated test and immersed test in artifical seawater, chloride diffusivity tests were conducted. From the results of regression analysis, regression equation between accelerated chloride diffusivity and immersed chloride diffusivity was linear function. And the determinant coefficient was 0.96 for linear equation.

• Korean Journal of Materials Research
• /
• v.30 no.8
• /
• pp.435-440
• /
• 2020

The relationship between the precipitation of secondary phase and the thermal properties of Al-4.5%Cu alloy (in wt.%) after various heat treatments has been studied. Solid solution treatment of alloy was performed at 808 K for 6 hours, followed by warm water quenching; then, the samples were aged in air at 473 K for different times. The thermal diffusivity of the Al-4.5%Cu alloy changed with the heat treatment conditions of the alloy at temperatures below 523 K. The as-quenched specimen had the lowest thermal diffusivity, and as the artificial aging time increased, the thermal diffusivity of the specimen increased in the temperature range between 298 and 523 K. For the specimen aged for five hours, the thermal conductivity was 12% higher than that of the as-quenched specimens at 298 K. It is confirmed that the thermal diffusivity and thermal conductivity of the Al-4.5%Cu alloy significantly depend on their thermal history at temperatures below 523 K. The precipitation and dissolution of the Al₂Cu phase were confirmed via DSC for the alloys, and the formation of coefficient of thermal expansion peaks in TMA was caused by precipitation. The precipitation of supersaturated solid solution of Al-4.5%Cu alloys had an additional linear expansion of ≈ 0.05 % at 643 K during thermal expansion measurement.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.15 no.2
• /
• pp.154-160
• /
• 1982

One dimensional unsteady heat conduction was studied on soybean curd as a water-protein-fat food system. This heterogeneous soybean curd could be treated as homogeneous material as for the unsteady heat conduction by 'effectiver' thermal diffusivity. Measurements were made with a apparatus designed and constructed by the author and also made with ice to establish the reliability, the reproducibility and the accuracy of the apparatus. It was found that the effective thermal diffusivity of soybean curd was substantially dependent on the fraction of protein and fat as well as water.

• Journal of the Korea Concrete Institute
• /
• v.21 no.5
• /
• pp.639-647
• /
• 2009

In order to evaluate the durability of reinforced concrete structures under chloride attack from sea water and frost damage, it is important to analyze both the microstructural characteristics of concrete and its diffusion resistance of concrete against chloride ingress. In this study, a relation between micro-pore structures of concrete obtained by the Mercury Intrusion Porosimetry and accelerated chloride diffusivity as well as long term chloride diffusivity were studied for ground granulated blast furnace slag(GGBS) concrete. Different water-cement ratio of 40, 45, 50% and different unit cement concrete of 300, 350, 400 or 450 kg/$m^3$ of the GGBS concrete along with OPC concrete were used and freeze and thawing, and the change in diffusivity and microstructure were observed for both GGBS concrete and damaged GGBS concrete due to rapid freezing and thawing.

• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.1
• /
• pp.1-8
• /
• 2012

The thermal properties including volumetric heat capacity, thermal conductivity, thermal diffusivity, and diurnal and annual damping depths of 10 representative soil series of Korea were calculated using some measurable soil parameters based on the Taxonomical Classification of Korean Soils. The heat capacity of soils demonstrated a linear function of water content and ranged from 0.2 to $0.8cal\;cm^{-3}^{\circ}C^{-1}$ for dry and saturated medium-textured soil, respectively. A small increase in water content of the dry soils caused a sharp increase in thermal conductivity. Upon further increases in water content, the conductivity increased ever more gradually and reached to a maximum value at saturation. The transition from low to high thermal conductivity occurred at low water content in the soils with coarse texture, and at high water content in the other textures. Thermal conductivity ranged between $0.37{\times}10^{-3}cal\;cm^{-1}s^{-1}^{\circ}C^{-1}$ for dry (medium-textured) soil and $4.01{\times}10^{-3}cal\;cm^{-1}s^{-1}^{\circ}C^{-1}$ for saturated (medium/coarse-textured) soil. The thermal diffusivity initially increased rapidly with small increases in water content of the soils, and then decreased upon further increases in the soil-water content. Even in an extreme soil with the highest diffusivity value ($1.1{\times}10^{-2}cm^2s^{-1}$), the daily temperature variation did not penetrate below 70 cm soil depth and the yearly variation not below 13.4 m as four times of damping depths.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2005.09b
• /
• pp.924-925
• /
• 2005