• Title/Summary/Keyword: water chemical characteristics

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Distribution Characteristics of Polycyclic Aromatic Hydrocarbons(PAHs) in Riverine Waters of Ulsan Coast, Korea (울산연안 하천에서 다환방향족탄화수소 분포특성)

  • You, Young-Seok;Lee, Jeong-Hoon;Park, Jeong-Chae;Kim, Dong-Myung;Cho, Hyeon-Seo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.5
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    • pp.398-405
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    • 2012
  • PAHs(Polycyclic Aromatic Hydrocarbons) in coastal area and estuary adjacent to urban area and industrial activities region are mainly introduced into marine environment via atmosphere and river. This study which is evaluated the distribution characteristics of PAHs discharge from rivers and sewage disposal water which flowing into Ulsan bay, and were carried out in Jun of dry season and in Auguest of wet season, 2008. The water samples from eight main rivers and Youngyeon WWTP(Wastewater Treatment Plant) flowed into Ulsan bay were taken for analysis of dissolved PAHs. The range and mean values of dissolved PAHs concentrations showed 10.30 to 87.88 ng/L, its mean 36.94 ng/L in dry season and 10.30 to 69.57 ng/L, its mean 24.37 ng/L in wet season. The distribution of dissolved PAHs showd the high concentrations in the Gungcheoncheon which is flowed from urban and industrial area. The ranges and means values of the loading fluxes were estimated with 0.04 to 8.27 g/day, its mean 2.05 g/day in dry season, and 0.03 to 4.77 g/day, its mean 1.61 g/day, in wet season. The loading flux showed the highest value in Taewha river due to the high flow rate and the urban activity. The composition patterns of dissolved PAHs compound showed most of the trend occupying low molecuar weight PAHs than high molecular weight PAHs. These results were due to physical and chemical characteristics of PAHs compound, and were similar to those of other studies. The concentrations of dissolved PAHs in this study are lower than those of other studies, and the level of PAHs pollution appeared to be not serious in reverine waters of Ulsan coast.

A Study on Ecological Characteristics and Changes of Vegetation in Hamyangsangrim (함양상림 식생의 생태적 특성 변화 연구)

  • Kim, Dong-Wook;Lee, Seung-Joo;Lee, Soo-Dong;Kim, Ji-Seok;Han, Bong-Ho
    • Korean Journal of Environment and Ecology
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    • v.26 no.4
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    • pp.537-549
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    • 2012
  • The purpose of this study was to provide data for the basic research to found the effective conservation and management plan for the Hamyangsangrim designated as Natural Monument No. 154 and surround areas by analyzing the ecological characteristics such as landuse and actual vegetation, plant community structure, soil chemical property and also to identify the tendency of the ecosystem changes through comparison with past studies. According to analysis the results, the landuse and actual vegetation of survey site was classified as 8 types which were forest, artificial greenspace, plaza and open-space, bare ground and the pavement, water bodies, facilities, agricultural land and etc.. It was also categorized as 38 types according to detailed characteristic. 15 kinds of forest vegetation community types comprising silva were classified among them. The changes of actual vegetation showed little variation that the Quercus serrata-Carpinus tschonoskii forest was the most widely distributed in 2003(forest area ratio is 48.3%) and 2010(forest area ratio is 48.1%), whereas, the Quercus serrata forest declined a more dramatic from 11.6% to 23.2%. The Quercus serrata-Carpinus tschonoskii forest increased sharply(11.6% ${\rightarrow}$ 23.2%) and also the Quercus serrata-Zelkova serrata forest increased steadily(2.2% ${\rightarrow}$ 7.9%). The agricultural land around forest was transformed into artificial green zone. Moreover, water bodies, bare ground and the pavement of areas have increased. In addition, the urbanized area has decreased because the damaged areas inside forest have been restored to the woodlands. According to the result of typical 6 types vegetation communities change, the middle layer trees grew up to the canopy layer trees and was formed the canopy layer structure. The middle layer trees expanded their forces widely. Also new species appeared. And the shrub individuals also more dramatically increased due to the growth of shrubs. The force of Quercus serrata declined as well. However the force of Carpinus tschonoskii and Zelkova serrata expanded and increased in the forest. It must be the result of the ecological vegetation succession and environmentally soundly health recovery by influence of the projects of forest surrounding environment improvement and limitation of access to forest have managed and maintained since 2003. Those sorts of changes seems to be going to develop continuously. In the future Carpinus tschonoskii and Zelkova serrata will not be only codominant in the canopy layer but also Carpinus Tschonoskii, Zelkova serrata, Meliosma myriantha, Sapium japonicum. Styrax obassia and Acer pseudo-sieboldianum will be codominant in the middle layer. As a result, the forest's codominance species are going to be changed such like that.

Study on the Characteristics and Non-point Source Pollution Loads in Stormwater Runoff of Shihwa Lake (시화호 유역 비점오염물질의 유출특성 및 부하량 연구)

  • Ra, Kong-Tae;Kim, Kyung-Tae;Kim, Joung-Keun;Bang, Jae-Hyun;Lee, Jung-Moo;Kim, Sung-Keun;Kim, Eun-Soo;Yun, Min-Sang;Cho, Sung-Rok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.14 no.1
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    • pp.40-50
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    • 2011
  • We study the characteristic and total flux of non-point pollutants such as total suspended solids (TSS), chemical oxygen demand (COD), dissolved nutrients, total phosphorus (TP) and total nitrogen (TN) in the storm water runoff from urban streams and sewer outlets of Banweol Industrial Complex around Shihwa Lake. The concentrations of non-point pollutants were generally increased with increasing of the duration and intensity of rainfall. Mean TSS concentration of Ansan stream was higher than that of sewer outlets but mean concentrations of COD, TP and TN were approximately 2~5 times higher of sewer outlet than of urban stream. TSS showed statistically positive relationships with COD and TP but it had negative correlation with dissolved nutrients. There was a significant correlation between total flux of non-point pollutants in the storm water runoff and total basin area of each sewer outlet, showing that the highest runoff flux was observed at 3rd sewer outlet which represents the largest basin area from Banweol industrial complex. Total runoff fluxes for TSS, COD, TP and TN in this study were 187,536 kg, 17,118 kg, 922 kg, 13,519 kg, respectively. Given the basin area of sewer outlet in Banweol industrial complex which corresponds only 3% from total catchment area around Shihwa Lake, enormous amount of non-point pollutants will be entered into Shihwa Lake without any treatment. It is necessary to manage and reduce of various non-point sources and pollutants because the runoff of nonpoint pollutants during storm events should be deteriorating the water quality of Shihwa Lake. Our results provides useful informations on the development of best managements practices (BMPs) for effective implementation of total pollution loads management system of Shihwa Lake.

Characteristics in Chemical Properties of Agricultural Groundwater in Gyeongnam Province (경남지역 농업용 지하수의 수질특성)

  • Lee, Seong-Tae;Kim, Eun-Seok;Song, Won-Doo;Kim, Jin-Ho;Kim, Min-Kyeong;Lee, Young-Han
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.698-703
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    • 2012
  • This survey was conducted to obtain basic data of the quality of groundwater for agriculture in Gyeongnam province. Groundwater samples from paddy 15, upland 15, and plastic film house 30 sites were collected on April, July, and October in every two years from 2002 to 2008. According to the result of water quality analysis, groundwater quality was suitable for irrigation purpose averagely. The $NO_3$-N contents by land use were in the order of plastic film house > upland > paddy field and its contents were 6.53, 4.80, and $3.68mg\;L^{-1}$, respectively. In annual changes of water quality, pH was no significant change in paddy, upland, and plastic film house by 6.6~6.9. EC was increased in upland and plastic film house in 2008 and majors factors were $NO_3$-N and $Cl^-$. In upland and plastic film house, $NO_3$-N contents were 4.72 and $6.52mg\;L^{-1}$ in 2002, respectively, whereas they were 5.63 and $8.70mg\;L^{-1}$ in 2008, respectively. Of the investigated sites, $NO_3$-N was exceeded water quality standards for agriculture by 3.3~15.0% in plastic film house and $Cl^-$ was exceeded water quality standards for agriculture by 2.2% in upland of 2004. The $NO_3$-N contents were decreased with well depth and their contents were $5.38mg\;L^{-1}$ from 3~10 m, $4.87mg\;L^{-1}$ from 10~20 m, and $2.58mg\;L^{-1}$ from above 30 m. The $NO_3$-N contents by soil texture were highest in sandy loam by $5.73mg\;L^{-1}$ and lowest in clay loam by $4.13mg\;L^{-1}$. The $NO_3$-N contents by crops category were in order of fruit vegetables > leaf vegetables > rice > fruits > beans, contents of fruit vegetables and leaf vegetables were 5.81 and $5.30mg\;L^{-1}$, respectively.

Sanitary Characteristics of Seawater and Sediments in Tongyeong Harbor (통영항의 해수 및 저질의 위생학적 특성)

  • Park, Jun-Yong;Kim, hhhYeong-In;Bae, Ki-Sung;Oh, Kwang-Soo;Choi, Jong-Duck
    • Journal of Food Hygiene and Safety
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    • v.25 no.4
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    • pp.367-375
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    • 2010
  • The bacteriological and physiochemical analysis of sea water and sediments in Tongyeong harbor was conducted to evaluate sanitary conditions. The samples were collected at 8 stations established once a month from June, 2008 to May, 2009. During the study period, the range of temperature was from 6.7 to $25.2^{\circ}C$, transparency ranged from 1.2 to 2.6 m, chemical oxygen demand ranged from 1.90 to 2.92 mg/L, dissolved oxygen ranged from 6.2 to 10.5 mg/L, dissolved nitrogen ranged from 0.052 to 0.098 mg/L, phosphate ranged from 0.044 to 0.065 mg/L, respectively. Seafood, if eaten raw, carries the risk of food poisoning. Seafood poisoning is often cause by pathogenic microorganism originating from fecal contamination, such as Salmonella sp., Shigella sp. and norovirus. Fecal coliforms are an important indicator of fecal contamination. Therefore, data on fecal coliform are very important for evaluating the safety of fisheries in coastal areas. So, we investigated the sanitary indicate bacteria. The coliform group and fecal coliform MPN's of sea water in Tongyeong harbor were ranged from < 1.8~22,000/100 mL (GM 164.9 MPN/100 mL) and < 1.8~7,900 MPN/100 mL (GM 33.7 MPN/100 mL), respectively. Total coliform were detected 97.0% in 96 of samples and 68.9% of total coliforms were fecal coliforms. These results similar to another seawater detection ratio of total coloforms and fecal coliforms. The Vibrios was isolated and identified with VITEK system. Four hundred eighty strains that were obtained from sea water samples in Tongyeong harbor Detection ratio Vibrio alginolyticus, 34.2%, Vibrio parahaemolyticus, 13.8%, Vibrio vulnificus 10.0%, and V. mimicus 12.5% respectively. Vibrio cholerae O1, was not detected. During the study period, the ranges of water content, ignition loss, COD, and acid volatile sulfates in sediments in Tongyeoung harbor were 41.0~57.4%, 7.8~10.5%, 6.51~9.30 mg/g, 0.04~0.09 mg/g, respectively. Heavy metals in sediment of Tongyeoung harbor were Cd, $0.10{\pm}0.05$; Cu, $4.79{\pm}8.20$; As, $1.95{\pm}0.17$; Hg, $0.10{\pm}0.07$; $Cr^{6+}$, $0.34{\pm}0.12$; Zn, $125.33{\pm}16.40$; Ni, $16.43{\pm}1.93$ mg/kg.

Studies on the Rapid Discrimination of Yellow Pigments Colored on Yellow Croakers and Natural Yellow Pigment of Croakers (참조기의 천연색소와 인위적으로 착색된 황색색소류 판별법에 관한 연구)

  • Kim, Hee-Yun;Hong, Jin-Hwan;Kim, Dong-Sul;Han, Sang-Bae;Lee, Eun-Ju;Lee, Jeung-Seung;Kang, Kil-Jin;Chung, Hyung-Wook;Song, Kyung-Hee;Park, Hye-Kyung;Park, Jong-Seok;Kwon, Yong-Kwan;Chin, Myung-Shik;Park, Hee-Ok;Oh, Sae-Hwa;Shin, Il-Shik;Lee, Chang-Kook;Park, Hee-Yul;Ha, Sang-Chul;Jo, Jae-Sun
    • Korean Journal of Food Science and Technology
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    • v.34 no.6
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    • pp.977-983
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    • 2002
  • This study was performed to establish the precise and rapid method to distinguish croakers through the pigment analysis of colored imported white croakers for adultration. We surveyed the coloring behaviors, extraction test by water and organic solvent and using pigments such as targeting, curcumine, and azo dye products. The pigment of yellow croaker is not stained on wet cloth or tissue which is rubbed on epidermis of yellow croaker and was not eluted in water extraction test, while adulterated pigments were easily extracted by water and acetone, but edible diluted yellow, Yellow No. 4 and Yellow No. 5 were not extracted. Reactive pigment was detected easily by extraction with water and dispersed pigment was also detected by extraction test. As a result of discoloring characteristics of carotene having similar structure to yellow croaker and azo dye by oxidation and reduction, azo dyes were not discolored by oxidation with sodium percarbonate or peracetic acid but that were discolored by oxidation with Fenton reagent after 1hr and by hypochlorite promptly. On the other hand, carotenes were not discolored by sodium precarbonate and Fenton reagent but discolored by sodium hypochlorite after 2 hr and by peracetic acid promptly. Azo dyes were discolored by reduction with sodium hydrosulfite and sodium carbonate but carotenes were not discolored by these reagents. This discoloring test was applicable to detect adulterated pigments and other marine product.

Effluent Characteristics of Nonpoint Source Pollutant Loads at Paddy Fields during Cropping Period (영농기 광역논으로부터 비점오염물질 유출 특성)

  • Han, Kuk-Heon;Kim, Jin-Ho;Yoon, Kwang-Sik;Cho, Jae-Young;Kim, Won-Il;Yun, Sun-Gang;Lee, Jeong-Taek
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.1
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    • pp.18-24
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    • 2007
  • Paddy fields are apparently nonpoint source pollution and influence water environment. In order to improve water quality in rivers or lakes, to low nutrient load from paddy fields are required. To establish comprehensive plan to control agricultural non-point source pollution, it is imperative to get a quantitative evaluation on pollutants and pollution load from paddy fields. A field monitoring study was carried out to investigate the water balance and losses of nutrients from fields in Sumjin river basin. The size of paddy fields was 115 ha and the fields were irrigated from a pumping station. The observed total nitrogen loads from paddy fields were larger than those of the unit loads determined by Ministry of Environment data (MOE). It is because the nitrogen fertilization level at the studied field was higher than the recommended rate and the high irrigation and subsequent drainage amount. On the contrary, total phosphorus loads were less than those addressed by MOE since phosphorus fertilization level was lower than that of standard level. Therefore, it was found that fertilization, irrigation, and drainage management are key factors to determine nutrient losses from paddy fields. When the runoff losses of nutrients were compared to applied chemical fertilizer, it was found that 42 to 60% of nitrogen lost via runoff while runoff losses of phosphorus account for 1.3 to 7.6% of the total applied amount during the entire year.

A Study on the Estimation of Compression Index in the East-Southern Coast Clay of Korea (동남해안 점토의 압축지수 추정에 관한 연구)

  • Park, Choon-Sik;Kim, Sung-Su
    • Journal of the Korean Geotechnical Society
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    • v.35 no.8
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    • pp.43-56
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    • 2019
  • This research has been conducted to suggest an estimation equation of compression index to be practically applied to the southeastern areas by finding out physical and mechanical characteristics of 229 points on the southeastern coast areas (Busan area: 78 points, Gimhae area: 103 points, Geoje area: 18 points, Changwon area: 30 points) through indoor tests and analyzing its relation to the compression index. From the results, we could not only find out correlation between natural water content, liquid limit and initial void ratio versus compression index for soft ground on each of the southeastern coast areas, but also an integrated correlation equation of the southeastern coast areas. In addition, we have performed a comparative analysis of the existing estimated equation of compression index and that found in this paper. As a result, the existing estimated equation suggested by foreign researchers has shown considerable error to be applied to the soft ground on the southeastern coast areas in Korea. The estimated equation of compression index with the water content out of the existing estimated equations has shown minimum 10.8% to maximum 48.1% of error rate, minimum 13.4% to maximum 288.5% of error rate with liquid limit or minimum 9.4% to maximum 211.4% of error rate with initial void ratio. On the other hand, error rates calculated with the estimated equations of compression index from this research have shown minimum 10.5% to maximum 13.4% with water content, minimum 11.6% to maximum 21.3 with liquid limit or minimum 7.1% to maximum 11.7% with initial void ratio, for better results than those with existing estimated equations. In addition, relation between compression index and expansion index has shown Cs = (1/5 ~ 1/12)Cc similar to the existing relation of Cs = (1/5 ~ 1/10)Cc.

Studies on the Liquid Manure Application for Silage Corn (사일리지용 옥수수에 대한 액상분뇨 시비연구)

  • Shin, Dong-Eun;Kim, Dong-Am;Choi, Hong-Lim;Song, Kwan-Cheol;Lee, Hyuk-Ho;Kim, Weon-Ho;Chung, Eui-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.1
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    • pp.22-30
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    • 1999
  • This experiment was carried out to determine the forage yield and mineral contents of silage corn(Zea mays L.), and N balance, soil chemical characteristics and nitrate-N level in infiltration water by different types and N rates of liquid manure applied. Seven treatments consisting of chemical fertilizer $200kg\;N;ha^{-1}$, liquid cattle manure 200, 320 and $440kg\;N;ha^{-1}$, liquid swine manure 200, 320 and $440kg\;N;ha^{-1}$ were arranged in a randomized complete block design with three replications. The results obtained at National Livestock Research Institute, RDA, in Suweon from May 1997 to Aug. 1997 are summarized as follows : There were no significant differences in percentage of dry matter among the treatments, but significant dry matter yield differences were found (P<0.05), and also the mean dry matter yield of liquid swine manure plot was higher than that of liquid cattle manure plot. Potassium, calcium and magnesium contents of silage corn increased with increasing liquid manure application rates (P<0.05). Nitrate-N content of silage corn in the liquid cattle manure treatments was not influenced by liquid manure application rates, but that in the liquid swine manure treatments increased with increasing the N rates of liquid manure application. pH and contents of exchangeable canons of the soil after experiment were raised by increasing the amount of liquid manure application. Available $P_2O_5$ content in topsoil(0-10cm) was highest as $340mg\;kg^{-1}$ at the plot of liquid swine manure $440kg\;N;ha^{-1}$. Concentration of nitrate-N in infiltration water increased at the plot of liquid swine manure $440kg\;N;ha^{-1}$. Amount of nitrogen balance increased with increasing liquid manure application rates. Based on the results of this experiment, it is suggested that the mean dry matter yield of liquid swine manure plot was higher than that of liquid cattle manure plot, and the amount of nitrogen balance increased with increasing liquid manure application.

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Studies on the Characteristics of Phosphorus in the Upland Soil -II. Relation of Soil Phosphorus and Some Soil Chemical Properties (경작지(耕作地) 전토양(田土壤)의 인산특성(燐酸特性)에 관(關)한 연구(硏究) -II. 토양(土壤) 인산함량(燐酸含量)과 몇가지 토양(土壤) 화학성(化學性)과의 관계(關係))

  • Shin, Cheol-Woo;Kim, Jeong-Je
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.2
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    • pp.195-201
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    • 1988
  • A laboratory experiment was coducted to investigate the relation of various soil phosphorus and some soil chemical properties which affect the composition of inoganic phosphorus and soil phosphorus with 149 phosphorus accumulated soil samples. Soil pH and exchangeable Ca were showed positively high significant correlation with 1.25 $N-NH_4$ OAc-P, Saloid-P, Ca-P and Total-P, however the soil pH was not showed significant relationship with $0.01M-CaCl_2-P$, Al-P, and Fe-P, respectively. Active Al and available phosphorus, water soluble P, and inoganic phosphorus were showed negatively high significant correlation, but Al-P and Fe-P were not. Also active Fe were showed positively significant correlation at 1% level for Fe-P and total-P. In the relationahips between soil pH and active Al, and exchangeable Ca, active Al were showed negatively high significant correlation with log regression equation, and exchangeable Ca were showed positively high significant correlation with liner regression equation. P sorbed by soil from p 20ppm solution was showed negatively high significant correlation with available phosphorus, water soluble P and $0.01M-CaCl_2-P$ in soil and positively with active Al, but was not significant with Ca-P.

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