• Title/Summary/Keyword: water chemical characteristics

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Isolation of Natural Antioxidants from the Root of Zingiber officinale R. (생강(Zingiber officinale R.)근경으로부터 항산화 활성물질의 분리)

  • Bang, Myun-Ho;Song, Jung-Choon;Kim, Sun-Lim;Hur, Han-Sun;Baek, Nam-In
    • Applied Biological Chemistry
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    • v.44 no.3
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    • pp.202-205
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    • 2001
  • The root of Zingiber officinale R. was extracted with 80% aqueous MeOH, and the concentrated extract was fractionated with EtOAc, n-BuOH and water phases. The EtOAc fraction exhibited most potent antioxidant activity among them, and two active compounds were isolated by activity-guided separation using repetitive silica gel column chromatography. On the bases of spectral data and the chemical characteristics, the structure of the compounds were determined as 6-shogaol and 12-shogaol, respectively. The $EC_{50}$ values of them were evaluated as 26.4 ${\mu}M$ and 22.5 ${\mu}M$, respectively, where these values were higher than the commercial antioxidants, such as, BHA, BHT and ${\alpha}-tocopherol$.

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Evaluation of Early-age Properties of Controlled Low Strength Material Using Non-destructive Testing (비파괴 기법을 이용한 유동성 채움재의 초기경화특성 평가)

  • Kim, Dong-Ju;Kim, Sang-Cheol;Han, WooJin;Lee, Jong-Sub;Byun, Yong-Hoon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.2
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    • pp.31-38
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    • 2020
  • Controlled Low Strength Material (CLSM) has high fluidity and self-compaction characteristics. CLSM is mainly used for backfilling the excavated road. Early-age properties of CLSM should be characterized for fast restoration of the road. In this study, shear wave monitoring and Vicat needle test are performed to investigate the early-age properties of CLSM depending on the setting time. CLSM consists of CSA cement, fly ash, silt and sand, accelerator, and water. Five fly ashes with different chemical properties are used for CLSM samples. The penetration of CLSM along setting time is obtained through the Vicat needle test. A pair of bender elements are placed in a mold for shear wave measurement, and the change in shear waves with the setting time is monitored. The experimental results show that, regardless of the type of fly ash, the penetration depth decreases and the shear wave velocity increases with the setting time. Depending on the type of fly ash, initial and final times and shear wave velocity change. After testing, the correlation between penetration and shear wave velocity is obtained with high coefficient of determination. The shear wave measurement technique using the bender element can be used to identify early-age properties.

Environmental Risk Assessment of Polyhexamethyleneguanidine Phosphate by Soil Adsorption/Desorption Coefficient

  • Chang, Hee-Ra;Yang, Kyung-Wook;Kim, Yong-Hwa
    • Korean Journal of Environmental Agriculture
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    • v.25 no.4
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    • pp.365-370
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    • 2006
  • This study was performed to determine the adsorption-desorption characteristics of polyhexame-thyleneguanidine phosphate in three different soil types of textural classification. Adsorption and desorption studies is impotent for prediction their fate and generating essential information on the mobility of chemicals and their distribution in the soil, water and air of our biosphere. The detection limit of the test substance quantified by a spectroscopic method using Eosin indicator was $0.25{\mu}g/mL$. The reproducibility of analytical method was confirmed by the preliminary test. The concentrations of polyhexamethylenequanidine phosphate in aqueous solution were $1.36{\pm}0.09,\;2.45{\pm}0.01,\;and\;$4.25{\pm}0.05{\mu}g/mL$ by a spectroscopic method using Eosin indicator. The adsorption percents of polyhexamethylenequanidine phosphate in soil were greater than 95.2% for all three test soils. The desorption percents from the adsorbed soil were less than 4.5, 4.7 and 4.7%. Therefore, the adsorption coefficient (K) were greater than 110, 111 and 116. The adsorption coefficient calculated as a function of the organic carbon content (Koc) of the test soils were greater than 9,181, 11,100, and 8,942, respectively. Therefore, the test substance, polyhexamethylenequanidine phosphate could be concluded as medium or high adsorption (>25%) and poorly desorption (<75%) in soil media. Therefore, this chemical is likely to be retained in soil media and may not pose a risk in the aquatic environment.

Biological Effectiveness of Methionine Hydroxy-analogue Calcium Salt in Relation to DL-Methionine in Broiler Chickens

  • Elwert, C.;de Fernandes, E. Abreu;Lemme, A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.10
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    • pp.1506-1515
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    • 2008
  • Two feeding trials were conducted to assess the relative bioavailability (RBV) of methionine hydroxy analogue calcium salt (MHA-Ca) in comparison to DL-methionine (DL-Met). Male Ross 308 (1-38 days) and Cobb 500 chickens (1-42 days) were used in studies 1 and 2, respectively. Experimental diets based on wheat and soybean meal or sorghum and soybean meal were fed during three phases. In both experiments graded levels of DL-Met and MHA-Ca were supplemented to Met+Cys deficient basal diets. Additionally, in experiment 1, increasing levels of a DL-Met preparation diluted with corn starch to 65% purity (DL-Met65) were supplemented. Birds were kept in floor pens and feed and water were available ad libitum. Body weights and feed consumption were recorded at the beginning and end of the experimental periods and weight gain and feed efficacy were computed subsequently. At the end of the experiments, a number of birds were slaughtered for carcass evaluation (dressing percentage, breast meat yield). Dose response data were analysed by both ANOVA and nonlinear common plateau asymptotic regression. In both experiments birds responded significantly to increasing levels of either methionine source. However, RBV of MHA-Ca compared to DL-Met was markedly (in many cases significantly) below 84%, the value which would have been expected from MHA-Ca's chemical characteristics. Excluding some extremely low RBV figures of trial 2, RBV of MHA-Ca averaged to about 63% in relation to DL-Met. In addition, supplementation of DL-Met65 allowed confirmation of nonlinear common plateau asymptotic regression to be suitable to determine RBV.

Study on Paraffin Wax Precipitation using Model Oils (모델오일을 이용한 파라핀 왁스의 침전 연구)

  • Oh, Kyeong-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.495-503
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    • 2017
  • Wax components can be precipitated when surrounding temperature decreases below wax precipitation temperature (WAT). WAT as well as pour point are important characteristics to evaluate the behavior of waxy oils. In this study, qualitative and quantitative evaluations of waxes in waxy model oils were presented after determining WAT and pour point. In case of anhydrous waxy model oils, ASTM D2500 may be most useful to determine WAT because of the transparent nature of model oils. With same apparatus, ASTM D97 is also applicable to determine the pour point of waxy oils in a serial determination. In case of emulsified model oils, however, it is difficult to measure WAT because of its opaque nature. This study employed FTIR spectroscopy to determine wax precipitation temperature and discussed the effect of emulsion state regarding the values of WAT. Further study would be needed to conclude the effect of water contents to WAT values in case of emulsified waxy oil.

Impact of wilting and additives on fermentation quality and carbohydrate composition of mulberry silage

  • Zhang, Ying Chao;Wang, Xue Kai;Li, Dong Xia;Lin, Yan Li;Yang, Fu Yu;Ni, Kui Kui
    • Asian-Australasian Journal of Animal Sciences
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    • v.33 no.2
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    • pp.254-263
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    • 2020
  • Objective: The objective of this study was to investigate the effects of wilting and additives on the fermentation quality, structural and non-structural carbohydrate composition of mulberry silages. Methods: The selected lactic acid bacteria strains Lactobacillus plantarum 'LC279063' (L1), commercial inoculant Gaofuji (GF), and Trichoderma viride cellulase (CE) were used as additives for silage preparation. Silage treatments were designed as control (CK), L1, GF, or CE under three wilting rates, that is wilting for 0, 2, or 4 hours (h). After ensiling for 30 days, the silages were analyzed for the chemical and fermentation characteristics. Results: The results showed that wilting had superior effects on increasing the non-structural carbohydrate concentration and degrading the structural carbohydrate. After ensiling for 30 days, L1 generally had a higher fermentation quality than other treatments, indicated by the lower pH value, acetic acid, propionic acid and ammonia nitrogen (NH3-N) content, and the higher lactic acid, water soluble carbohydrate, glucose, galactose, sucrose, and cellobiose concentration (p<0.05) at any wilting rate. Wilting could increase the ratio of lactic acid/acetic acid and decrease the content of NH3-N. Conclusion: The results confirmed that wilting degraded the structural carbohydrate and increased the non-structural carbohydrate; and L1 exhibited better properties in improving fermentation quality and maintaining a high non-structural carbohydrates composition compared with the other treatments.

Acute Toxicity of Dissolved Inorganic Metals, Organotins and Polycyclic Aromatic Hydrocarbons to Puffer Fish, Takifugu obscurus (황복(Takifugu obscurus)에 대한 중금속, 유기주석화합물 및 다환방향족탄화수소(PAHs)의 급성 독성)

  • Lee Jung-Suk;Lee Kyu-Tae;Kim Dong-Hoon;Kim Jin-Hyeong;Han Kyung-Nam
    • Environmental Analysis Health and Toxicology
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    • v.19 no.2
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    • pp.141-151
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    • 2004
  • We exposed juvenile puffer fish, Takifugu obscurus(30 days after hatching) to various aqueous pollutants including 4 kinds of inorganic metals (Ag, Cd, Cu and Hg), 2 organotin compound.; (tributyltin [TBT] and triphenyltin[TPhT]) and 5 polycyclic aromatic hydrocarbon (PAH) compounds (chrysene, fluoranthene, naphthalene, phenanthrene and pyrene) to estimate median lethal concentrations (LC50s) of each pollutant after the 96-hour acute exposure. Among the inorganic metals, Hg (52 $\mu\textrm{g}$/L; 96-h LC50) was most toxic to test animals and followed by Ag (164 $\mu\textrm{g}$/L), Cu (440 $\mu\textrm{g}$/L) and Cd (1180 $\mu\textrm{g}$/L). Aqueous TBT was more toxic between the two organotins; the 96-h LC50 for TBT (5.1 $\mu\textrm{g}$/L) was 3 times lower than that of TPhT (17.3 $\mu\textrm{g}$/L). The acute toxicity of PAH compounds was highest for chrysene (1.5 $\mu\textrm{g}$/L; 96-h LC50) and decreased in the order of pyrene (65 $\mu\textrm{g}$/L) > fluoranthene (158 $\mu\textrm{g}$/L) > phenanthrene (432 $\mu\textrm{g}$/L) > naphthalene (8690 $\mu\textrm{g}$/L). The toxicity of PAH compounds wat closely related to their physico-chemical characteristics such as $K_{ow}$ and water solubility, and well explained by simple QSAR relationship. The sensitivity of puffer fish to various inorganic and organic pollutants was generally comparable to various fish species widely used as standard test species in previous studies and further evaluation should be conducted to develop adequate testing procedure for T. obscurus when used in various toxicity tests.

Investigation for Pollution of Livestock Waste in Daechong Reservoir Area (대청호 유역의 축산폐수 오염에 관한 연구)

  • 이봉규;조우영;최윤식;심순보
    • Korean Journal of Veterinary Service
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    • v.15 no.2
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    • pp.203-214
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    • 1992
  • Livestock waste causes ground and surface water pollution, eutrophication of reservoir as well as adverse affects living environment of those who dwell nearby. In order to investigate the pollution load from livestock waste, physical and chemical characteristics of the waste were determinded in the survey of livestock farms. Once pollution load is obtained as a function of the origin units of livestock, the influence of livestock waste on the Daecheong reservoir was studied. 1. For Daecheong reservoir inflow area, the liverstock manure productions of beef cattle swine, dairy cattle and chicken were 1,135.6t/day, 480t/day, 241.3t/day, 48t/day respectively; Beef cattle was the mai or source of the pollution. Pollution loading productions due to the livestock waste around the were found to be 53.31t/day for BOD, 222.49t /day for COD, 261.99t/day for T-S, 9.64t/day for T-N, 6.54t/day for T-P 2. Bocheong stream turnd out to be the major contribution for pollution loading production to Daecheong reservoir with 10,748kg /day of BOD, 47,157kg /day of COD, 1,946kg /day of T-N, 1,271kg /day of T-p. 3. Actual pollution loadings from livestock wastes for the area of Daecheong reservoir were estimated as 1,997kg /day(BOD), 8,546kg /day(COD), 364kg /day(T-N), 243kg /day (T-P), respectively Therefore, advanced treatment for livestock waste is recommended for Daectleong reservoir inflow area to eliminate the nutrients which are major sources of eutrophication of the reservoir.

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Fabrication of Transparent Ultra-thin Single-walled Carbon Nanotube Films for Field Emission Applications

  • Jang, Eun-Soo;Goak, Jung-Choon;Lee, Han-Sung;Kim, Myoung-Su;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.353-353
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    • 2008
  • Carbon nanotubes (CNTs) are attractive for field emitter because of their outstanding electrical, mechanical, and chemical properties. Several applications using CNTs as field emitters have been demonstrated such as field emission display (FED), backlight unit (BLU), and X-ray source. In this study, we fabricated a CNT cathode using transparent ultra-thin CNT film. First, CNT aqueous solution was prepared by ultrasonically dispersing purified single-walled carbon nanotubes (SWCNTs) in deionized water with sodium dodecyl sulfate (SDS). To obtain the CNT film, the CNT solution in a milliliter or even several tens of micro-litters was deposited onto a porous alumina membrane through vacuum filtration process. Thereafter, the alumina membrane was solvated by the 3 M NaOH solution and the floating CNT film was easily transferred to an indium-tin-oxide (ITO) glass substrate of $0.5\times0.5cm^2$ with a film mask. The transmittance of as-prepared ultra-thin CNT films measured by UV-Vis spectrophotometer was 68~97%, depending on the amount of CNTs dispersed in an aqueous solution. Roller activation, which is a essential process to improve the field emission characteristics of CNT films, increased the UV-Vis transmittance up to 93~98%. This study presents SEM morphology of CNT emitters and their field emission properties according to the concentration of CNTs in an aqueous solutions. Since the ultra-thin CNT emitters prepared from the solutions show a high peak current density of field emission comparable to that of the paste-base CNT emitters and do not contain outgassing sources such as organic binders, they are considered to be very promising for small-size-but-high-end applications including X-ray sources and microwave power amplifiers.

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Growth Response on the Euonymus fortunei 'Emelad' n 'Gold' as affected by Artificial Plantings Soil Properties during Dry Spring Season (봄철 건조기 용기형 벽면녹화에서 식재지반 조성에 따른 황금줄사철의 적응성)

  • Ju, Jin-Hee;Kim, Hea-Ran;Park, Heon;Yoon, Yong-Han
    • Journal of Environmental Science International
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    • v.23 no.7
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    • pp.1299-1305
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    • 2014
  • For evaluating the effect of various artificial planting soil properties on the Euonymus fortunei 'Emelad'n Gold' growth, a container green wall system experiment was conducted in a wall of greenhouse at Konkuk University, Glocal campus. The experimental artificial planting grounds were prepared with different organic soil conditioner ratios (Control, $A_4O_1$, $A_2O_1$ and $A_1O_1$) and with drought tolerance and an ornamental value Euonymus fortunei 'Emelad'n Gold' was planted. The soil and plant characteristics were investigated from April to Jun 2010. The volumetric soil moisture contents were significantly increasing order as the amount of organic soil conditioner level increased in order to $A_1O_1$ > $A_2O_1$ > $A_4O_1$ > Control. At 4 treatment, soil chemical properties were inversely related to organic soil container ratios increase. The differences of root collar caliper, number of branch, and survival rate between the organic soil conditioner ratio were not significantly affected by organic soil conditioner. But, plant height, internode length, leaf length and leaf width were significantly shorter on plants planted $A_1O_1$ than plants planted other treatments. Therefore, Euonymus fortunei 'Emelad'n Gold' had good growth response regardless of organic soil conditioner ratio and the plant is expected to be a highly valuable shrub for the green wall system if it should be considered in integration with stormwater retention or as a soil conditioner for increasing soil water contents in artificial planting soil.