• 제목/요약/키워드: wastewater organic matter

검색결과 295건 처리시간 0.023초

초순수 제조 공정에서 역삼투 막의 저농도 유기물 제거 (Removal of low concentration organic matter by reverse osmosis membranes in ultrapure water production process)

  • 이홍주;김수한
    • 상하수도학회지
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    • 제28권4호
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    • pp.391-396
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    • 2014
  • Ultrapure water (UPW) is water containing nothing but water molecule ($H_2O$). The use of UPW is increasing in many industries such as the thermal and nuclear power plants, petrochemical plants, and semiconductor manufacturers. In order to produce UPW, several unit processes such as ion exchange, reverse osmosis (RO), ultraviolet (UV) oxidation should be efficiently arranged. In particular, RO process should remove not only ions but also low molecular weight (LMW) organic matters in UPW production system. But, the LMW organic matter removal data of RO membranes provided by manufacturers does not seem to be reasonable because they tested the removal in high concentration conditions like 1,000 ppm of isopropyl alcohol (IPA, MW=60.1). In this study, bench-scale experiments were carried out using 4-inches RO modules. IPA was used as a model LMW organic matter with low concentration conditions less than 1 ppm as total organic carbon (TOC). As a result, the IPA removal data by manufacturers turned out to be trustable because the effect of feed concentration on the IPA removal was negligble while the IPA removal efficiency became higher at higher permeate flux.

급속교반조건에서 Alum 응집제의 가수분해종 분포특성과 유기물특성변화 (Characterization of Natural Organic matter by Rapid Mixing Condition)

  • 송유경;정철우;손희종;손인식
    • 상하수도학회지
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    • 제20권4호
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    • pp.559-571
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    • 2006
  • The overall objective of this research was to find out the interrelation of coagulant and organic matter during rapid mixing process and to identify the change of organic matter by mixing condition and to evaluate the effect of coagulation pH. During the coagulation, substantial changes in dissolved organics must be occurred by coagulation due to the simultaneous formation of microflocs and NOM precipitates. Increase in the organic removal efficiency should be mainly caused by the removal of microflocs formed during coagulant injection. That is, during the mixing period, substantial amount of dissolved organics were transformed into microflocs due to the simultaneous formation of microflocs and NOM precipitates. The results also showed that 40 to 80% of dissolved organic matter was converted into particulate material after rapid mixing process of coagulation. During the rapid mixing period, for purewater, formation of dissolved Al(III) (monomer and polymer) constant by rapid mixing condition, but for raw water, the species of Al hydrolysis showed different result. During the rapid mixing period, for high coagulant dose, Al-ferron reaction increases rapidly. At A/D(Adsorption and Destabilization) and sweep condition, both $Al(OH)_3(s)$ and dissolved Al(III) (monomer and polymer) exist, concurrent reactions by both mechanism appear to cause simultaneous precipitation.

축산폐수의 혐기성 고정법에 있어서 암모니아성 질소의 영향 (Effect of ammonium nitrogen in anaerobic biofilter using live-stock-wastewater)

  • 엄태규;임정원
    • 상하수도학회지
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    • 제11권4호
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    • pp.43-53
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    • 1997
  • In this research, the synthetic livestock wastewater was prepared to study the characteristics of organic matter removal, the change of VFA production, and the amount of gas production with respect to the change of ammonium nitrogen concentration in the waste using anaerobic fixed bed process, which is an anaerobic biofilm process. The HRT and operation temperature were 1 day and $35{\pm}1^{\circ}C$, respectively. Also, the characteristics of organic matter removal and the inhibitory effect on microorganism in the anaerobic process were studied on the organic loading and ammonium nitrogen concentration. The results obtained were as follows: For COD loading of $10kg/m^3$-day and five levels of ammonium nitrogen concentration ranging from 1,000 to 5,000 mg/L, organic removal efficiencies were about 81, 74, 67, 58, and 51%, and gas productions were 3,860, 3,520, 3,240, 3,020, and 2,790 ml/l-day, respectively. Average methane contents in the gas produced on COD loading of $10kg/m^3$-day was about 76%. Throughout the whole period of experiment, remaining VFA (as COD base) in the effluent was over 90% of remaining COD. This result indicated the inhibitory effect of high concentration of ammonium nitrogen through the facts that accumulated VFA was almost COD and organic removal efficiency decreased also with the increase of ammonium nitrogen. Especially, that implys which high concentration of ammonium nitrogen not only inhibits methane forming bacteria, but also acid forming bacteria.

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다양한 하수를 대상으로 유기물 성상과 질산화 반응조 내 유기물 변화 (Analysis of COD fraction and change of COD in nitritation reactor using various wastewater)

  • 임지열;길경익
    • 한국습지학회지
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    • 제17권4호
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    • pp.421-427
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    • 2015
  • ASM 모델에서는 유기물을 특성에 따라 분류하는데, 일반적인 COD와 BOD로의 분류로는 ASM에서 요구하는 조건을 충족시키지 못한다. 본 연구에서는 하수종말처리장 수처리 및 슬러지 처리 계통 하수를 대상으로 미생물 호흡률을 기반으로 하여 ASM에서 요구하는 유기물 분류에 대한 실시하였다. 분석 결과 유기물 성상 분석 결과 각 하수마다 유기물 구성에서 차이를 보이는 것으로 나타났다. 이는 각 공정의 하수를 처리할 때 반드시 파악해야 하는 중요한 하수특성이라고 할 수 있다. 따라서 본 연구를 통해 규명한 각 하수별 유기물 성상은 하수종말처리장의 원활한 운영을 위해 중요한 기초 자료로 활용될 수 있을 것으로 판단된다. 질산화 반응조 내 반응시간에 따른 유기물 및 암모니아성 질소 변화 분석을 통해 SS이 질산화에 영향을 미치는 주요 인자임을 확인 할 수 있었다. 이는 질산화 반응이 유도 가능한 체류시간 선정에 밀접한 관계가 있는 것으로 사료된다.

Burkholderia cepacia를 이용한 축산폐수의 처리 (Livestock Wastewater Treatment by Burkholderia cepacia)

  • 정팔진;조선영;현미희;김민정;이은주;전민식
    • 한국물환경학회지
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    • 제20권6호
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    • pp.547-554
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    • 2004
  • We found that the Bacterium Burkholderia cepacia in livestock wastewater treatment plant was predominant species. We investigated the growth rate of this and treatment characteristics for organic matter and nitrogen removal in livestock wastewater using this microorganism. First, we cultured B. cepacia. And then, to conducted treatment for livestock wastewater by using B. cepacia., we changed C/N from 0.2~4.4. When we operated A and B process, changing F/M ratio from 1.2 to 4.4. In experiment of C/N variations, when C/N was 1.8, we found that the optimal condition for organic matter and nutrient removal effect was higher and the removal efficiency of $SCOD_{cr}$, $SBOD_5$,$NH_4-N$ was 78.4%, 95% and 74.8%. So, It is possible to treat the wastewater having the lower C/N contents such as livestock wastewater using this microorganism. In experiment of A and B process for livestock wastewater, we found that the removal efficiency of organic matter and nitrogen in operating mode of A process was higher than that of B process. Also, the optimal F/M operating A process was 0.013 and the removal efficiency of $SBOD_5$, $SCOD_{cr}$, TN and TP were 97%, 60%, 95% and 91%.

축산폐수성상에 따른 SBR 처리특성 (The Characteristics of SBR Treatment with Different Types of Piggery Wastewater)

  • 전병희;부경민;김양훈;임정훈;김창원
    • 한국물환경학회지
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    • 제18권4호
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    • pp.435-440
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    • 2002
  • A pilot scale SBR (effective volume, $20m^3$) for the treatment of piggery wastewater treatment was performed with three different kinds of wastewater; fermenter effluent, scraper type and slurry type. The react phase in SBR was performed by sub-cycle operation consisting of repeated short cycle of anoxic-aerobic step. The fermenter effluent was characterized by the rapid nitrification and $NO_X-N$ accumulation due to depletion of organic matter in wastewater. The scraper type wastewater showed appropriate nitrogen removal efficiency, however, a poor response capacity for high loading rate often resulted in increased nitrogen concentration in effluent. Moreover, severe P release was the most serious problem in scraper type wastewater. SBR treated slurry type wastewater with high nitrogen removal efficiency to satisfy effluent quality requirement. It was thought that high concentration of organic matter in slurry made it possible to uptake P during SBR operation, where P concentration of 140mgP/l was decreased to 8mgP/l. As results, SBR was suitable to treat slurry type wastewater which has been discharged to the ocean till now.

강변여과에 의한 이.취미 물질 제어 특성에 관한 타당성 연구 (A Feasibility study on Removal Characteristics of Taste and Odor using Bank Filtration Treatment)

  • 맹승규;박노석;임재림;김성수;정우창
    • 상하수도학회지
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    • 제24권3호
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    • pp.307-317
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    • 2010
  • This study was conducted in order to investigate bulk organic matter characteristics and behavior of geosmin and 2-methylisoborneol (2-MIB) during riverbank filtration, which are general surrogates of taste and odor in drinking water. Column studies were used to simulate bank filtration systems. Most of the aliphatic organic matter was removed effectively after soil passage, and it is believed to be polysaccharides according to LC-OCD and F-EEM analysises. Removal efficiencies of geosmin and 2-MIB within the filtration column reached above 95%. It was found that the removal of total dissolved organic matter has a correlation with that of geosmin and 2-MIB in the near of filtration surface (about 50cm).

유동상 Media를 이용한 기존하수처리장의 Retrofitting 가능성 평가 (Evaluation on the Possibility of a Retrofitting Treatment Using Moving Media of Existing Wastewater Treatment)

  • 고태호;박운지;이찬기
    • 산업기술연구
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    • 제25권A호
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    • pp.133-139
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    • 2005
  • In this study, as MBBR(Moving Bed Biofilm Reactor) process using waste tire media is suggested for retrofitting with advanced wastewater treatment and the removal property of organic matter and nutrient and the capacity of media are evaluated through long-term operation with pilot plant following seasons, the application capacity of retrofitting with MBBR process to a existing wastewater treatment is studied. As a result of the long-term operation of the process, it is proved that there is no loss and abrasion of media, and also that it is possible to secure the sufficient attached bio-mass. The values of organic matter and nutrient in effluent are suitable for the strict discharged water quality standards in every season including winter.

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XAD 수지분획에 의한 용존유기물질 특성 연구 (Study on the characterization of dissolved organic matters by XAD resin fractionation)

  • 박정민;허성남;임태효;신찬기
    • 환경위생공학
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    • 제22권4호
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    • pp.23-32
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    • 2007
  • Changes in the characteristics of dissolved organic matter was studied at selected stations in the Nakdong river basin using physical and chemical methods. Characteristics of dissolved organic matters were analysed and assessed. Production of disinfection byproducts were also investigated. Distribution of the organic compounds according to the Molecular weight(MW) indicate that MWs higher than 100K were highest with cattle excrement wastewater and MW between 100-10K were highest with waters from forest streams. Low MW compounds (Jess than 1K) were highest with the effluents from environmental facilities. Results of resin fractionation study show that acidic hydrophobic substances(AHS) were dominant in many stations. The values were higher in the samples from mainstreams and sidestreams where the influence of organic matter is higher than the water from environmental facilities. Hydrophilic neutral substances(HoN) such as hydrocarbon, pesticides and detergents were higher in the wastewater treatment facilities. HoN values of water from the forest streams were 4.7% indicating there is no synthetic pollutant.