• 콘크리트학회논문집
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• 제14권2호
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• pp.148-155
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• 2002

본 연구는 폐지섬유보강 시멘트복합체의 수분 민감성 및 열화특성에 대하여 연구하였다. 폐지섬유는 건조공정에 의해 생산되었으며 슬러리-탈수 공법을 사용하여 폐지섬유보강 시멘트복합체를 제조하였다. 폐지섬유보강 시멘트복합체의 수분 민감성 덴 열화특성을 알아보기 위하여 수분민감성, 건조-습윤반복, 동결융해, 장기 오븐 건조의 영향을 실험실에서 촉진시험을 통하여 실시하였다. 폐지섬유보강 시멘트복합체에 대한 수분영향 및 열화에 대한 시험결과는 순수목질섬유보강 시멘트복합체와 통계적으로 비교 분석하였다 시험결과 폐지섬유보강 시멘트복합체는 수분노출 덴 장기 열화상태에서도 적절한 성능을 갖는 것으로 나타났다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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• pp.671-676
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• 2000

This study was to determine the technical feasibility of using wastepaper fibers, obtained through dry processing of wastepaper, as reinforcement in thin cement produces. Dry-processed waste papers have high levels of noncellulosic impurities, and the recycling process also breads and damages the fibers. To produce wastepaper fiber-cement composites, first the influential variables in the slurry-dewatering method of processing the composites were identified in an experimental study based on factorial design. Among the proportioning and processing variables investigated, fiber mass fraction and level of substitution of virgin fibers with recycled ones were found to have statistically significant effects on mechanical and physical properties of composites. Subsequently, response surface analysis techniques were used to devise an experimental program that helped determine the optimum combinations of the selected influential variables based on mechanical and physical properties, and cost.

• 펄프종이기술
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• 제41권4호
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• pp.82-90
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• 2009

It is very important to utilize effectively fibrous waste paper in terms of cost savings, environmental effects, and governmental policies. The quality of final products and runnability of papermaking process are primarily affected by constitutions of fibrous raw materials. In specific, board grade paper depends directly on compositions of waste paper bales. At present, the raw materials of board grade paper are mainly derived from lots kinds of wastepaper. Some papermaking countries, like EU, USA and Japan have advanced classification and management systems of recycled fiber, but Korea has not yet organized systematically. In this study, evaluation of wastepaper bale compositions and their fiber properties were carried out for effective utilization of fibrous raw materials for board grade paper production. 3 kinds of wastepaper bales were classified to fibrous or non-fibrous materials. In case of fibrous materials, KOCC, kraft sack paper and white duplex board matters were main component in total weight basis, and in case of non-fibrous materials, vinyl, plastic and cloth matters were main component, in turns. 3 representative kinds of waste paper were disintegrated and classified, and then prepared to handsheet for evaluation of recycled fiber property. Consequently, fines and ash content of waste paper, isolated from KOCC and white duplex board were higher than that of kraft sack paper. pH values of all kinds of waste fibers were neutral or weak alkaline.

• 펄프종이기술
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• 제38권2호
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• pp.52-60
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• 2006

Environment-friendly shock-absorbing materials were made of wastepaper such as Korean old corrugated containers(KOCC) and Korean old newsprint (KONP) with a vacuum forming method. The plate-like cushioning materials made of KOCC and KONP respectively by vacuum forming showed superior shock-absorbing properties with lower elastic moduli compared to expanded polystyrene (EPS) and pulp mold. Even though the plate-like materials had many free voids in their fiber structure, their apparent densities (${\approx}0.1g/cm^3$) were a little higher than that of EPS (${\approx}0.03g/cm^3$) and much lower than that of pulp mold(${\approx}0.3g/cm^3$). However, the elastic moduli of the cushioning materials made of wastepaper were much lower than that of EPS or pulp mold. This finding implies that the cushioning materials made of KOCC fibers containing more lignin than KONP show better shock-absorbing properties than KONP. Moreover, the cushioning materials made of KOCC and KONP respectively showed greater porosity than pulp mold. The addition of cationic starch to the cushioning materials contributed to the increase in the elastic modulus to the same level as that of EPS. Furthermore, the deterioration in fiber quality by repeated use of wastepaper played a positive role in improving shock-absorbing ability.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.471-474
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• 2006

Environment-friendly shock-absorbing materials were made of wastepaper such as old corrugated containers (OCC) and old newspapers (ONP) with a vacuum forming method. The plate-like cushioning materials made of OCC and ONP respectively by vacuum forming showed superior shock-absorbing properties with lower elastic moduli compared to expanded polystyrene (EPS) and pulp mold. Even though the plate-like materials had many free voids in their fiber structure, their apparent densities (${\approx}0.1g/cm^{3}$) were a little higher than that of EPS (${\approx}0.03g/cm^{3}$) and much lower than that of pulp mold (${\approx}0.3g/cm^{3}$). However, the elastic moduli of the cushioning materials made of wastepaper were much lower than that of EPS or pulp mold. This finding implies that the cushioning materials made of OCC fibers containing more lignin than ONP show better shock-absorbing properties than ONP Moreover, the cushioning materials made of OCC and ONP respectively showed greater porosity than pulp mold. The addition of cationic starch to the cushioning materials contributed to an increase in the elastic modulus to the same level as that of EPS. Furthermore, the deterioration in fiber quality by repeated use of wastepaper played a great role in improving shock-absorbing ability.

• 펄프종이기술
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• 제33권1호
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• pp.45-52
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• 2001

Recycling of wastepaper is very important for the environmental protection. However inferior strength and slower drainage characteristic that are brought by the hornification and the increase of fines respectively limited the increase of wastepaper recycling. The purpose of this study is to obtain some fundamental information that is helpful to develop the technologies which can improve the characteristics of recycled fibers. Softwood bleached kraft pulp was curlated with Hobart mixer at several different consistency. The curlation of fibers can cause the internal fibrillation and decreasing the crystallinity without serious damage of fiber surface. Curl index, kink index, freeness and WRV were increased, but crystallinity was decreased with the increase of curlation consistency.

• Journal of the Korean Wood Science and Technology
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• 제28권3호
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• pp.34-41
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• 2000

최근 들어 범용 플라스틱계 고분자의 환경오염이 심각한 사회적 문제를 유발함에 따라 많은 연구자들이 생분해성 고분자 소재 개발에 관한 연구를 시행하고 있으며, 본 연구에서는 폐지를 이용한 생분해성 고분자물질의 제조를 위하여 폐지의 화학적 성상 및 최적 전처리조건을 검토하기 위해 시행하였고, 그 결과는 다음과 같다. 각 공시재료별 화학적 조성분 분석 결과 신문폐지와 골판폐지의 리그닌 함량이 사무실 폐지에 비해 높게 나타났다. 또한 건식해리 펄프에 비해 습식해리 펄프의 회분 함량이 낮게 나타났다. 생분해성 고분자의 제조를 위해서는 반드시 폐지의 화학적 전처리가 요구되며, 습식해리 시료가 건식해리 시료에 비해 전처리 효과가 우수하였다. 본 연구에서 행해진 화학적 전처리 중 아염소산나트륨으로 가온($70^{\circ}C$)처리한 전처리방법이 가장 우수한 것으로 판명되었다. 한편 산소-알카리 전처리는 탈리그닌처리 효과는 우수하였지만, 수율이 과도하게 저하되고, 탄수화물의 붕괴에 따른 셀룰로오스의 중합도 저하로 인해 전처리 공정으로서 부적합하다고 판단되었다.

• Journal of the Korean Wood Science and Technology
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• 제32권1호
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• pp.9-16
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• 2004

본 연구는 폐지로부터 용액화물을 제조하고, 제조된 용액화물의 성분 분리 및 성상분석을 통해 용액화물의 효율적인 이용방안을 위한 기초자료 제공에 그 연구 목적이 있다. 폐지의 액화에 있어 건식해리된 폐지보다 습식해리된 폐지의 액화가 비교적 용이하였으며, 이러한 이유는 습식해리된 폐지의 약품 침투가 비교적 용이하기 때문으로 판단된다. 폐지의 최적 액화조건은 폐지 1 g에 대해 크레졸 2 ㎖, 물 4 ㎖, 인산 0.5 ㎖로 첨가하여 190℃에서 60분간 액화 시킨 조건이 가장 우수하였다. 폐지 액화물 중 리그닌은 용제인 크레졸 층으로, 탄수화물은 수층으로 용해되어 각각 분리되며, 두 성분의 분리·회수는 비교적 용이하였다. 액화 폐지 중의 리그닌은 80% 이상 회수되었고, 회수된 리그닌의 분자량은 1,000 정도의 저분자량을 나타냈었다.

• 펄프종이기술
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• 제36권1호
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• pp.24-29
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• 2004

Alkaline cellulolytic enzymes from cultured medium of Coprinus cinereus 2249 were purified with gel and ion-exchange chromatography and characteristics of those enzyme proteins were investigated. A fiber length distribution and a crystallinity of cellulose and sugar composition of enzyme treated Mixed Office Wastepaper(MOW) and Unbleached Kraft Pulp(UKP) were analysed. The conclusion could summarized as follows; \circled1 Alkaline and acidic, endo- and exo-glucanases were purified from cultured medium of Coprinus cinereus 2249. \circled2 The approximate molecular weight of alkaline endo-glucanase was 42 kDa, and also that of alkaline exo-glucanase was 50 kDa. A fiber length distribution and a crystallization of cellulose and sugar composition of enzyme treated MOW and UKP were not so much changed with original paper and pulp.

• 펄프종이기술
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• 제32권4호
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• pp.18-26
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• 2000

In order to investigate the influencing factors in flotation fractionation, flotations were performed at varied conditions. The selectivity of fines fractionation was mainly affected by long fiber flocculation degree and if there were not sufficient flocculation of long fibers, more loss of long fibers could not be avoided. The amount of flotation rejects were totally dependent on the stability of froth floated on the stock surface. Only small size fines could stabilize the froth as they hindered the drainage of liquid lamella in flotation-froth. More flotation reject and better flocculation of long fibers were two important factors for improving flotation. Changing a flotation flux or an air-mixing ratio to increase the flocculation of fibers increased long fiber ratio in the reject. In order to satisfy the both conditions of reducing long fiber loss and of increasing flotation reject, search of fractionation promoter is needed.