• Title/Summary/Keyword: waste treatments

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A study on the Dioxin behavior in the process of representative pyrolysis/gasfication/melting plant (대표적인 열분해가스화 용융시설의 공정별 다이옥신 배출거동에 관한 연구)

  • Shin, Chan-Ki;Shin, Dae-Yun
    • Journal of environmental and Sanitary engineering
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    • v.22 no.1 s.63
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    • pp.1-16
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    • 2007
  • The incineration process has commonly used for wastes amount reduction and thermal treatments of pollutants as the technologies accumulated. However, the process is getting negative public images owing to matter of hazardous pollutants emission. Specially dioxins became a main issue and is mostly emitted from municipal solid wastes incineration. In this reason, pyrolysis/gasfication/melting process is presented as a alternative of incineration process. The pyrolysis/gasfication/melting process, a novel technology, is middle of verification of commercial plant and development of technologies in Korea. But the survey about the pollutant emission from the process, and background data in these facilities is necessary. So in this survey, it Is investigated that the behavior of dioxins in three pyrolysis/gasfication/melting plant (S, T, P) of pilot scale. In case of S plant, concentration of dioxins shows high at latter part of cogenerated boiler and stack which are operate on low temperature conditions than a latter parts of pyrolysis and melting furnace which are operate on high temperature condition. Concentration of gas phage dioxins had increased after combusted gas passed cogenerated boiler and this is attributed to react of precursor materials such as chlorobenzene and chlorophenol. Concentration of dioxins in T plant showed lower levels at latter part of cooling equipment which are operate with water spray type on low temperature conditions than a latter parts of gasfied melting furnace which are operate on high temperature condition. Removal efficiency of dioxins at gas treatment equipment was 78.8 %. Concentration of dioxins in P plant was low at latter part of SDA/BF which is operate at low temperature conditions than a latter parts of pyrolysis gasfied chamber which are operate at high temperature condition. Removal efficiency of dioxins of SDA/BF was 85.9 % and therefore, it showed high efficiency at those of stoker type incineration facility. However, concentration of dioxins which emitted at high temperature condition were low in three facilities and satisfied present standard emission level of dioxins. To consider the distribution ratio of dioxins, Particulate phase dioxins at S and P plants showed similar ratio with which shows in current stoker type for middle scale domestic waste incineration facility. It is necessary to continuos monitoring the ratio of distribution of dioxins in T plant in because ratio of gas phage dioxins showed high.

Discoloration of Azo-Dyes Using Zerovalent Iron (영가철을 이용한 아조계 염료의 탈색)

  • Jeong, Yong-Sik;Lim, Woo-Taik;Kim, Jong-Hyun;Oh, Hyung-Suk;Kim, Young-Hun
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1262-1267
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    • 2008
  • Reductive discolorization studies were conducted. Azo-dyes usually have biological toxicity and it is known that the dyes are hardly removed by biological treatments. One of the simplest way to remove the color is to break the azo-bond and it is possible to break the bond with zero-valent metals. Three types of azo-dyes (Cibacron Briliant Yellow 3G-P (CBY3G-P), Benzopurpurin 4b (B-4B), Chicago sky blue 6b (CSB6B)) were tested. All tested azo-dyes were highly pH dependent and lower pH was preferred. The reaction mechanism was reductive cleavage and amines were expected as products. The dissolved iron ions from zero-valent iron can also remove the color through coagulation and precipitation and a set of experiments were conducted to evaluate the contribution by the dissolved iron. The results indicated that the contribution were also dependent on the type of dyes. This study showed that the reductive cleavage using zero-valent iron could be an alternative for the azo-dye waste water.

Effect of Pile Temperature Control on Changes of Physicochemical Parameters of Composted Poultry Waste (계분의 콤포스터 처리시 내부온도 조절이 생산물의 물리·화학적 성상에 미치는 영향)

  • Kwak, Wansup;Kim, Taegyu;Kim, Changwon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.2 no.2
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    • pp.39-51
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    • 1994
  • When broiler litter was composted under the control of peak temperature of piles(uncontrolled, controled below $70^{\circ}C$ and below $60^{\circ}C$), changes of physical and chemical parameters were determined throughout the processing period. Broiler litter was composted in each of three $1.0{\times}1.0{\times}1.2m$ dimensional facilities for 8 weeks. After 5 to 6 weeks of composting, broiler litter was converted into the final compost with no ammonia odour, rice hull size of particle, and faint brown color. Central temperature of piles reached to the peak(about $69{\sim}70^{\circ}C$) within 3 to 4 days after composting and gradually decreased thereafter. The final product contained 26.5% of moisture, 9.0~9.1 of pH, and 14.0~14.3 of C/N ratio. The increase of C/N ratio with processing resulted from the considerable loss of N. The total wet weight of the final composts was an average of 38.3% of the initial weight, the dry weight of those 64.1%, and the organic matter weight of those 34.8%. Treatments of central temperature of composts did not affect changes of moisture, pH, C/N ratio, total wet weight, total dry weight, and total organic matter weight. In general, composted broiler litter was converted into the final product with little change in physical and chemical parameters after 5 to 6 weeks of processing. Nitrogen losses during the composting should be prevented for the improvement of the composting efficiency of broiler litter.

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Nutrient Transfer in the Application of the Swine Slurry Liquid Fertilizer in Rice Paddy (벼 재배에서 양돈분뇨 액비 시용시 양분이동)

  • Kwon, Soon-Ik;Kim, Kwon-Rae;Kim, Min-Kyeong;Jung, Goo-Bok;Hong, Seung-Gil;Shin, Joong-Du;Park, Woo-Kyun;Seong, Ki-Seog;Lee, Deog-Bae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.4
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    • pp.77-85
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    • 2010
  • Pig slurry has been considered as environmental waste to be treated in an appropriate manner. Recently, there has been the movement toward reusing the pig slurry as an alternative fertilizer sources for agricultural lands. For instance, SCB(Slurry Composting & Biofiltration) liquid fertilizer has been developed and widely used in Korea. However, the impacts of swine slurry liquid fertilizers on both agricultural environment and crop yield have not been investigated yet. Therefore, the current study was conducted to accumulate the basic data which can be subsequently used to determine appropriate application amount of swine slurry liquid fertilizers (SCB liquid fertilizer and storage liquid fertilizer) as well as the application method for each liquid fertilizer. For this, growth of rice was cultivated under the treatment of SCB liquid fertilizer, storage liquid fertilizer, and chemical fertilizer. Also, control treatment (no fertilizer) was included for comparison and all treatments were conducted in five replication. Rice growth was good with the treatment in the order of chemical fertilizer>storage liquid fertilizer>SCB liquid fertilizer>control and likewise, the yield amount of rice straw was in the same order of rice growth. The rice yield amount appeared to be no difference among the treatment except control which showed the least yield amount. Also there was no difference in nitrogen and phosphorus concentrations in rice among the treatment except control which showed the least concentration.

Development of Sausage Using National Resource By-Product (천연 부산물을 이용한 소시지 개발)

  • 김수민;조영석;이신호;김대곤;성삼경
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.4
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    • pp.635-640
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    • 2001
  • These studies were carried out to develop sausage using extracts from waste resources. The changes of pH and moisture contents were tended to be a similar to control, respectively ranged in pH 6.0~6.4 and 62~60% in moisture content. However, the water holding capacity of sausage added with chitosan and sesamol gradually were tended to be a little high, compared to control. The treatments using natural resource by-product revealed a low TBARS value, compared to control. This means that sausage added with natural by-product seem to be extend its shelf-life during storage. At the same time, the TBARS values were very similar to sausage added with 0.5% potassium sorbate. The residual nitrite contents of sausage added with natural resource by-product were tended to be a little lower than that of control. As storage time goes by, the nitrite contents of sausage product gradually were a little more decreased during storage at 3$0^{\circ}C$ than those of storage at 1$0^{\circ}C$. The lightness of sausage color gradually were a little more decreased during storage at 3$0^{\circ}C$ than those of storage at 1$0^{\circ}C$. The redness of sausage added with chitosan were a little highter, compared to control Sensory test suggested that the changes of sausage color, flavor, texture and taste were tended to be decreased gradually. In conclusion, sausage added with natural resource by-product was effective on the basis of the reduction in residual nitrite content and lipid oxidation.

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Production of Keratinolytic Protease by Bacillus pumilus RS7 and Feather Hydrolysate As a Source of Amino Acids (Bacillus pumilus RS7에 의한 난분해성 케라틴 분해효소의 생산 및 아미노산 공급원으로서 우모 분해산물)

  • Woo, Eun-Ok;Kim, Min-Ju;Son, Hyeng-Sik;Ryu, Eun-Youn;Jeong, Seong-Yun;Son, Hong-Joo;Lee, Sang-Joon;Park, Geun-Tae
    • Journal of Environmental Science International
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    • v.16 no.10
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    • pp.1203-1208
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    • 2007
  • Feathers are produced in huge quantities as a waste product at commercial poultry processing plants. Since feathers are almost pure keratin protein, feather wastes represent an alternative to more expensive dietary ingredients for animal feedstuffs. Generally they become feather meal used as animal feed after undergoing physical and chemical treatments. These processes require significant energy and also cause environmental pollutions. Therefore, biodegradation of feather by microorganisms represents an alternative method to prevent environment contamination. The aim of this study was to investigate cultural conditions affecting keratinolytic protease production by Bacillus pumilus RS7. We also assessed the nutritive value of microbial and alkaline feather hydrolysates, The composition of optimal medium for the keratinolytic protease was fructose 0.05%, yeast extract 0.3%, NaCl 0.05%, K2HPO4 0.03%, KH2PO4 0.04% and MgCl2 6H2O 0.01%, respectively. The optimal temperature and initial pH was $30^{\circ}C$ and 9.0, respectively. The keratinolytic protease production under optimal condition reached a maximum after 18 h of cultivation. Total amino acid content of feather hydrolysates treated by NaOH and B. pumilius RS7 was $113.8\;{\mu}g/ml$ and $504.9\;{\mu}g/ml$, respectively. Essential amino acid content of feather hydrolysates treated by NaOH and B. pumilius RS7 was $47.2\;{\mu}g/ml$ and $334.0\;{\mu}g/ml$, respectively. Thus, feather hydrolysates have the potential for utilization as an ingredient in animal feed.

Effect of Setting on the Texture Intensity of Smoked Alaska Pollock Roe Sausage with Cellulose Casing and Its Quality Characteristics during Storage (셀룰로오스 케이싱에 충전한 명란훈연소시지의 텍스쳐에 대한 세팅의 영향 및 저장기간에 따른 품질특성)

  • Park, Jong-Hyuk;Kim, Young-Myung;Kim, Sang-Moo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.1
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    • pp.96-103
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    • 2006
  • Alaska pollock roe is mainly used as the production salted instead of salt-seasoned seafood (Myungranjeot). Alaska pollock roes with broken egg membrane are usually discarded as a waste product. In order to utilize the broken roes of Alaska pollock, imitated fish sausage was manufactured for commercial production. Hardness, cohesiveness, elasticity, brittleness, and gumminess of Alaka pollock roe sausage were evaluated based on mixture design and regression models. The higher amounts of carrageenan and tile lower amounts of starch caused the higher the texture intensity of Alaska pollock roe sausage. The pHs of control, vacuum and $N_2$ packages, increased up to 6.28, 6.23 and 6.24, respectively, during 4 months storage and then decreased. The values of volatile basic nitrogen (VBN), thiobarbituric acid (TBA), and total viable cell counts increased during storage periods, while the parameters were higher in control than in vacuum and Na packages. Coliform bacteria was not detected in all treatments during storage periods.

Remodeling Process Model Applying Service Life and Functionality Evaluation for Military Facilities (내용연수와 기능성 평가를 활용한 군 시설물 리모델링 대상 선정 프로세스 모델)

  • Cho, Jongwoo;Lee, Hyun-Soo;Park, Moonseo;Kim, Jaegon;Moon, Hyo-Soo
    • Korean Journal of Construction Engineering and Management
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    • v.16 no.6
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    • pp.41-52
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    • 2015
  • The number of military facilities has been rapidly increased due to growing requirement of modernization and military welfare. However, adequate maintenance has not implemented to these facilities. As a result, they are deteriorated quickly and require performance enhancement treatments. There are two ways of performance enhancement, reconstruction and remodeling. Despite the research result that remodeling within the standard remodeling range is more economical, remodeling of military facilities is not considered equivalent to reconstruction as an option of performance improvement. Therefore, derived from the relationship between performance change during life cycle of building and range of remodeling needs, this study tries to propose Remodeling Process Model(RPM) which uses a method to choose remodeling in a Specific Point of Time(SPT) when remodeling is considered more economical than reconstruction. In addition, this study suggests practical service life and functionality evaluation standard together which require to realize the RPM. This RPM make it possible to avoid the cases that facilities which do not have any problem on structural reliability but have low level of functionality miss appropriate remodeling timing and inevitably choose reconstruction as a performance improvement option. It also present the possibility of simple reconstruction / remodeling decision-making for facility managers who administrate building having various type, compilation and elapsed time. Consequently, this process model focusing on remodeling more may contribute to reduce resource waste caused by reconstruction.

Composting Effectiveness of A Sundry System with A Bin-type Composter for Recyle of Animal Wastes (축분뇨처리를 위한 Bin형 부숙조- Sundry 시스템의 퇴비화효율 평가)

  • 최홍림;김현태;정영윤
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.35 no.2
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    • pp.92-103
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    • 1993
  • A sunday system with a horizontal bin-type composter was constructed and operated to evaluate its composting performance for four days for each test in October, 1992. A sundry system is one of popular systems for composting livestock manure, of which main benefit is to utilize unlimited, clean, and free solar radiation. A rectangular concrete bin(composter) with dimension of 300cm(length) X90cm(width) X60cm(height) was bedded alternatively with four lanes of aeration pipes and heating pipes, and was insulated at three walls with 50mm styrofoam. Each aeration pipe of a diameter of 25mm had 4mm perforated holes at every 15cm longitudinally, and supplied air of about 2m$^3$/min to the composter to maintain aerobic condition . A stirrer rotating at 1 rpm made one round trip every 20 minutes on the conveying chain along the the length of the composter. Five tests (Test 1~Test 5) were implemented to evaluate the composting effectiveness of a sundry system with a horizontal bin-type composter. Treatments of two levels of the mixture ratio of swine manure and paper sludge cakes(manure : paper sludge cakes= 1 : 4 and 1 : 2) and two levels of the water content(W/C ; 70% and 50%) were made to test the significance of the physicochemical properties for decomposition of the mixture materials. Temperature, C/N ratio, water content, microbial activity of the composting materials were taken measurements to evaluate its performance with the lapse of composting time for tests. A small-scale sundry system with a bin-type composter did not appear to be an appropriate system for composting livestock manure. Since heat generation by the composting materials could not overcome heat loss due to areation in a small-scale composter, a proper thermal enviroment could not be maintained to propagate massively thermopilic microorganism relatively in a short period of time. Different from the result of Chol et al.(1992) 6), a temperature variation of the composting materials did not show the peak clearly and C/N ratio didn't lower with time as expected. Mesophilic microoragnism seemed to play an important role for decomposition of the mixture materials. A sundry system with a bin-type composter may be good for a large-scale livestock farm household which may produce enough animal manure. Therefore a decision should be made very carefully to choose a system for composting livestock waste.

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Synthesis and Characterization of Collagen Peptide Based Copolymer from Shaving Scrap (셰이빙 스크랩으로부터 콜라겐 펩타이드계 공중합체 합성과 특성)

  • Park, Min Seok;Shin, Soo Beom;Kim, Ho Soo;Kim, Min Soo;Kim, Ha Sun;Jang, Jae Hyeok;Lee, Jin Kye;Lee, Dong Kuk
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.581-587
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    • 2022
  • The leather industry generates a large amount of hazardous leather waste of various types every year. Among them, shaving scrap is difficult to recycle because it contains chromium ions. Many studies in recent years have shown that shaving scraps can be processed into various types of valuable products, such as adsorbent, filler, and poultry feed. In this study, collagen peptides were extracted from shaving scraps and structurally modified to be developed as new materials with improved physicochemical properties. First, the chromium ions contained in the shaving scraps were removed using a sodium hydroxide solution, and purified through concentration and low-temperature crystallization. The purified collagen peptide was used to prepare the powder using a spray dryer. The extracted collagen peptides were structurally modified by introducing double bonds by reacting with methacrylic anhydride (MAA), and the product was confirmed by 1H NMR spectroscopy. Next, a copolymer was prepared by redox polymerization of the modified collagen peptide (MCP) and 2-ethylhexyl acrylate (2-EHA). The structure of the copolymer was qualitatively confirmed by FT-IR. In conclusion, this study confirmed that collagen peptides can be extracted from shaving scrap and converted into new eco-friendly materials through certain treatments.