• Title/Summary/Keyword: waste carbon materials

검색결과 229건 처리시간 0.022초

초임계 탄산가스/유기용매/이색성 염료의 혼합계를 이용한 폴리(비닐 알코올) 편광필름의 제조 및 편광특성 (Preparation and Polarization Properties of Poly(vinyl alcohol) Polarizing Film Using the Mixed System of Supercritical $CO_2$/Organic Solvents/Dichroic Dye)

  • 박기상;최이준;장진호;박일현
    • 폴리머
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    • 제35권5호
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    • pp.458-466
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    • 2011
  • 초임계 탄산가스/유기용매 혼합계 상에서 이색성 염료인 C. I. direct black 22(DB22)로 고검화도의 폴리(비닐 알코올)(PVA)을 염색하여 내구성이 강한 편광필름을 제조하였다. 특히, 초임계 탄산가스 상으로 이색성 염료를 녹이기 위한 분산제로 에틸렌 글리콜과 디메틸 설폭사이드의 무게비=4 : 6의 혼합용매계를 사용하였을 때 염색 압력을 200 bar까지 낮출 수 있었다. 초임계 유체계의 사용으로, 최대 염색은 연신 전 투과도로 1% 미만까지, 폐수 발생량은 1/10 수준까지, 감소가 가능하였고, 이와 같이 염색된 PVA 필름을 500% 연신한 후 측정된 편광효율은 94%, 평균 투과도(single piece transmittance)는 30%로 각각 얻어졌으며, 또한 이색성 염료로서의 DB22의 한계 및 개선 방안 등도 검토하였다.

속경화용 탄소섬유/에폭시 프리프레그의 다단 압축 성형기술 (Multi-stage Compression Molding Technology of Fast Curing CF/Epoxy Prepreg)

  • 곽성훈;문지훈;홍상휘;권순덕;김병하;김태용
    • Composites Research
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    • 제34권5호
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    • pp.269-276
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    • 2021
  • 프리프레그 압축성형(PCM, Prepreg Compression Molding) 공정은 고품질 CFRP(Carbon Fiber Reinforced Plastic) 제품을 제조할 수 있는 고속성형기술이다. 오토클레이브 공정에 비해 폐기물 발생이 적고 사이클타임을 크게 줄일 수 있어 항공우주 및 자동차 산업에서 다양한 연구가 진행되고 있다. 본 연구에서는 PCM 공정의 품질을 높이기 위해 프리프레그의 경화거동을 따라 프레스의 압축압력을 단계별로 증가시키는 성형법에 대해 연구하였고, 이러한 다단 압축 성형법이 우수한 품질의 CFRP 제품을 생산하고 사이클타임을 단축할 수 있는 좋은 수단임을 확인하였다. 그리고 상온에서 적층한 프리프레그를 금형에 투입하여 예열과 성형을 동시에 함으로써 별도의 예열 공정 없이 제품을 성형할 수 있었다. 또한 평판 성형에 최적화된 공정조건을 3차원 형상물에 동일하게 적용한 결과 외관상 평판과 유사한 제품을 공정조건 수립 과정 없이 만들 수 있었다.

시멘트산업공정에서의 $CO_2$배출량 저감을 위한 청정기술 적용에 관한 연구 (A Study on the Reduction of $CO_2$ Emission by the Application of Clean Technology in the Cement Industry)

  • 박영규;김정인
    • 청정기술
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    • 제16권3호
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    • pp.182-190
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    • 2010
  • 시멘트공정 내 청정기술인 폐기물 재자원화 및 에너지회수공정을 이용하여 $CO_2$발생량 저감을 위한 타당성을 연구하였다. 원료투입물 대체방법으로써 용융슬래그를 시멘트 클링커 제조용 주원료로 사용하기 위한 전과정평가(life cycle assessment: LCA)를 실시하였다. 이를 통하여 시멘트소성로 내 탈탄산 과정에서 발생하는 이산화탄소의 양을 60% 이상 줄일 수 있었다. 이전 연구에서 환경영향평가 실시 후 우선순위로 선정된 시멘트 공정의 에너지효율 개선 및 대체에너지를 적용하여 현 시점에서 가장 빠른 시일 내에, 가장 경제적인 방법으로, 탄소중립적 에너지소비체계로의 전환을 위해 화석연료로 분류된 천연가스를 사용하여 가장 효율적인 녹색전략으로 $CO_2$배출량 저감을 위한 연구를 수행하였다.

코코넛 껍질-전도성 고분자 복합소재로부터 탄소 소재의 제조 및 전기화학적 특성 분석 (Preparation of Hybrid Carbon from Conducting Polymer-Coconut Shell Composites and Their Electrochemical Properties)

  • 박정은;신수빈;윤예원;박지원;배준원
    • 공업화학
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    • 제35권1호
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    • pp.37-41
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    • 2024
  • 열대성 과일로 널리 재배되고 있는 코코넛(coconut)의 독특한 껍질(shell)은 과육 섭취 후 얻어지는 부산물로 활용 가치가 클 것으로 기대된다. 이 코코넛 껍질을 전도성 고분자와 혼합하여 복합소재를 간단한 방식으로 제조하고 섭씨 600도 정도의 상대적 저온에서 탄화하여 수득되는 소재의 전기화학적 특성 및 활용 가능성을 고찰하였다. 먼저, 외형적 요소를 주사전자현미경(scanning electron microscope, SEM)으로 관찰하였다. 탄소의 미세구조를 라만(Raman) 분광 분석을 통하여 추론하였다. 전기전도 가능성을 간단한 옴의 관계(Ohmic relation)를 통하여 확인하였다. 나아가, 탄화된 재료가 리튬 이차 전지의 음극(anode) 소재로 활용될 수 있는지 여부를 반쪽 전지(half-cell) 충방전(charge/discharge) 테스트를 통해 살펴보았으며, 최대 충전 용량은 약 750 mAh로 높게 나타났으나, 충전이 진행됨에 따라 빠른 감소를 보였다. 본 연구는 향후 목질계 폐기물의 활용에 대한 중요한 정보를 제공할 것이다.

연속섬유 시트로 보강된 RC 부재의 모서리 형상에 따른 보강 효율에 관한 연구 (Strengthening Efficiency for the Various Corner Shapes of RC Member confined with Continuous Fiber Sheets)

  • 고훈범;이진섭
    • 한국건축시공학회지
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    • 제8권2호
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    • pp.113-119
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    • 2008
  • Recently, fiber reinforced polymers(FRP) composite materials are used extensively in the rehabilitation of concrete structural members. A main application is to wrap beams and columns using the continuous fibers sheets to improve their strength and ductility. The corner chamfering affects significantly the performance of the continuous fibers sheets, and could lead to environmental problem with waste and dust. The main purpose of this paper is to verify the effect of corner conditions on the strength of the continuous fiber sheets, and to introduce new attached components which can avoid environmental problem. A total of 15 specimens were tested and carefully checked for three types of continuous fiber sheets(carbon, glass, and aramid) and three types of corner conditions(non-chamfering, chamfering, and device attaching). It is proved that the devices proposed in this research have some capabilities to use for RC member. But additional research will be needed for commercializing.

Application of Biocathodes in Microbial Fuel Cells: Opportunities and Challenges

  • Gurung, Anup;Oh, Sang-Eun
    • 한국토양비료학회지
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    • 제45권3호
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    • pp.410-420
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    • 2012
  • The heavy reliance on fossil fuels, especially oil and gas has triggered the global energy crisis. Continued use of petroleum fuels is now widely recognized as unsustainable because of their depleting supplies and degradation to the environment. To become less dependent on fossil fuels, current world is shifting paradigm in energy by developing alternative energy sources mainly through the utilization of renewable energy sources. In particular, bioenergy recovery from wastes with the help of microorganism is viewed as one of the promising ways to mitigate the current global warming crisis as well as to supply global energy. It has been proved that microorganism can generate power by converting organic matter into electricity using microbial fuel cells (MFCs). MFC is a bioelectrochemical device that employs microbes to generate electricity from bio-convertible substrate such as wastewaters including municipal solid waste, industrial, agriculture wastes, and sewage. Sustainability, carbon neutral and generation of renewable energy are some of the major features of MFCs. However, the MFC technology is confronted with a number of issues and challenges such as low power production, high electrode material cost and so on. This paper reviews the recent developments in MFC technology with due consideration of electrode materials used in MFCs. In addition, application of biocathodes in MFCs has been discussed.

반탄화 공정 변화에 따른 바이오매스 연료의 특성 연구 (Study on the Characteristics of Bio-mass according to Various Process of Torrefaction)

  • 엄태인;채종성;김정규;최수아;오세천
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.375-378
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    • 2014
  • In this study, we carried out torrefaction experiment using PKS(Palm Kernel Shell), and Bagasse as a raw material of oversee of herbaceous biomass and using waste wood and logging residue as a raw material of domestic of woody biomass. And then, by analyzing the physical & chemical properties, we investigated the characteristics as a fuel. By using the result of thermo gravimetric analysis, the biomass residue was torrefied for 30 minutes at a temperature range of $250-350^{\circ}C$ in anaerobic condition. As a result, torrefied materials of moisture content are lower than raw, but of fixed carbon, calorific value and ash are higher than raw.

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순천만 생태복원에 따른 경제적 가치 평가 (The Economic Valuation of Ecosystem Restoration in Suncheon Bay)

  • 황민섭;이명균;정태용
    • 한국환경복원기술학회지
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    • 제17권4호
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    • pp.69-79
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    • 2014
  • Coastal wetlands are among the most productive biomes in the Earth. The economic values include the direct use of a coastal wetland's ecosystem services, such as food, raw materials, recreation, and tourism. Other values comprise the indirect use of a coastal wetland's ecosystem services, such as carbon sequestration, waste-water treatment, and erosion prevention. In particular, Suncheon Bay is recently attracting attention as the most successful case of the preservation and restoration. This study applies Travel Cost Method (TCM) to estimate the economic value by drawing the demand curve for trips to Suncheon Bay. The TCM is an approach used for economic valuation of non-market goods and services. Based on the results of TCM, this study shows that the economic benefit from recreational uses of the site adds up to \174.7 billion per year. It is also significant in the sense that monetary information is suggested to help local policy makers evaluate the realistic values of coastal wetlands.

A brief review on Oyster shells origin and sedimentary evolution for the formation of limestone

  • Ramakrishna, Chilakala;Thriveni, Thenepalli;Whan, Ahn Ji
    • 에너지공학
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    • 제27권3호
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    • pp.48-56
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    • 2018
  • The shell waste biomineralization process has known a tremendous metamorphosis and also the nanostructure with the identification of matrix proteins in oyster shells. However, proteins are represented in minor shell components and they are the major macromolecules that control biocrystal synthesis. Aragonite and calcite were derived from molluscan shells and evaluated the source of carbonate minerals and it helps for the formation of limestone. The oyster shell wastes are large and massive. The paleoecological study of oyster beds has discovered a near-shore and thin Upper Rudeis formation with storm influence during the accumulation of oysters with highly altered by disarticulation, bioerosion, and encrustation. It is possible even in the Paleozoic mollusks provided sufficient carbonate entirely to the source of microcrystalline of limestone. The present review is to discuss paleoecologically a number of oyster shell beds accumulated and sediment to form the different types of limestone during the Middle Miocene time.

Effect of Dissolved Oxygen (DO) on Internal Corrosion of Water Pipes

  • Jung, Hae-Ryong;Kim, Un-Ji;Seo, Gyu-Tae;Lee, Hyun-Dong;Lee, Chun-Sik
    • Environmental Engineering Research
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    • 제14권3호
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    • pp.195-199
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    • 2009
  • A series of laboratory-scale corrosion experiments was carried out to observe the effect of dissolved oxygen (DO) in the presence of other water quality parameters, such as hardness, Cl-, and pH using various pipe materials. In addition, a simulated loop system was installed at a water treatment plant for pilot-scale experiment. Laboratory-scale experiment showed that corrosion rates for galvanized steel pipe (GSP), carbon steel pipe (CSP), and ductile cast iron pipe (DCIP) were decreased to 72%, 75%, and 91% by reducing DO concentration from 9${\pm}$0.5 mg/L to 2${\pm}$0.5 mg/L. From the pilot scale experiment, it was further identified that the average ionization rate of zinc in GSP decreased from 0.00533 to 0.00078 mg/$cm^2$/d by controlling the concentration of DO. The reduction of average ionization rate for copper pipe (CP) and stainless steel pipe (SSP) were 71.4% for Cu and 63.5% for Fe, respectively. From this study, it was concluded that DO could be used as a major parameter in controlling the corrosion of water pipes.