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메탄올 전기산화반응 증진을 위한 PtRuW/C 촉매에서 텅스텐의 효과에 관한 연구 (Effect of Tungsten on PtRuW/C Catalysts for Promoting Methanol Electro-oxidation)

  • 노창수;손정민;박영권
    • 공업화학
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    • 제23권6호
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    • pp.561-566
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    • 2012
  • PtRuW/C 촉매를 Pt : Ru : W 비를 5 : 4 : 1, 2 : 1 : 1, 1 : 1 : 1, 1 : 2 : 2로 각각 합성하였다. 촉매의 조성은 EDX분석을 통해 이론값과 비슷하다는 것을 확인하였다. TEM분석과 XRD분석으로부터 3.5~5.5 nm의 균일한 입자 크기 및 결정질 분포를 가지고 있음을 확인하였다. 유효표면적, 전류밀도, 고유 활성 및 피독률과 같은 전기화학적 특성은 CO 스트리핑, 선형쓸음 전기량 측정법, 대시간 전류법 등과 같은 방법으로 분석하였다. 이러한 분석으로부터, $PtRu_2W_2/C$를 제외한 촉매는 상업촉매보다 우수한 반응성과 안정성을 가지고 있음을 확인하였다. 이 중 가장 우수한 촉매는 $Pt_5Ru_4W/C$였으며, $121.05mA{\cdot}m^{-2}$의 specific activity와 $0.01%{\cdot}s^{-1}$의 피독률을 보였다.

삼백초 에탄올 추출물의 위출혈성 스트레스 위염 억제 효과 (Inhibitory Activities of Ethanol Extracts from Saururus chinensis L. against Stress-Induced Hemorrhagic Gastritis)

  • 박소영;조영제
    • 한국식품영양과학회지
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    • 제44권6호
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    • pp.800-808
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    • 2015
  • 천연 생리활성 물질 탐색 연구의 일환으로 삼백초로부터 위염 억제 물질을 추출하여 효능을 검정하였다. 삼백초 추출물 0.25~2 g/kg B.W.를 마우스에 경구 투여한 결과 1.5 g/kg B.W. 미만 투여량의 급성독성 실험에서 안정성을 나타내었으며 $LD_{50}$은 1.81 g/kg B.W.였다. 삼백초 추출물 0.5 g/kg B.W.를 마우스에 경구 투여한 만성독성 실험에서는 13주간의 투여기간 동안 독성이 없는 것으로 나타났다. 위염을 유발시키기 전에 삼백초 추출물을 250 및 500 mg/kg B.W. 농도로 미리 섭취시킨 결과 위출혈 및 위부종과 세포손상이 농도 의존적으로 감소하였다. 또한 사이토카인의 발현도 억제되었다. 따라서 삼백초 추출물은 스트레스성 위염에 의한 출혈 및 세포손상을 농도 의존적으로 억제하는 효과가 있으며, 그 mechanism은 염증성 사이토카인의 발현 억제에 의한 것이라 생각되었다.

유백피의 항혈전 활성 분획 및 유효성분에 관한 연구 (Antiplatelet fraction from Ulmi cortex and its active components)

  • 김동선;양원경;성윤영;임선미;김호경
    • 대한본초학회지
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    • 제28권3호
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    • pp.39-44
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    • 2013
  • Objectives : The purpose of this study was to identify active fraction and components from antiplatelet Ulmi cortex extract. Methods : The 70% ethanol extract of Ulmi cortex was subjected to column chromatography over D101 resin and eluted with an 20% (W1), 30% (W2), 40% (W3), 50%(W4), 70% (W5), and 100% ethanol (W6) to yield 6 fractions. W6 was further fractioned and its active components were purified using semi-preparative HPLC. The isolated compounds were identified by MS and NMR, and their contents were simultaneously analyzed using HPLC/UV. Antiplatelet aggregation activities of the fractions and the compounds were evaluated using rat platelet-rich plasma in presence of collagen ($5{\mu}g/ml$), arachidonic acid (0.05 U/ml), or thrombin ($100{\mu}M$). Results : Among six fractions, W3 prominently inhibited platelet aggregation. At the concentration of $200{\mu}g/ml$, W3 strongly inhibited arachidonic acid- and collagen-induced platelet aggregations by 78.2% and 65.9%, respectivley, and weakly inhibited thrombin-inducded platelet aggregation by 32.6%. Catechin, epicatehin, and catechin-7-O-${\beta}$-D-glucopyranoside were isolated from W3 and their contents were revealed to be 15.1%, 0.87%, and 0.32%. Catechin and epicatechin at the concentrations of $100{\mu}M$ strongly inhibited collagen-induced platelet aggregation by 79.9% and 86.6%, respectively, but weakly inhibited arachidonic acid- and thrombin-induced platelet aggregations. Conclusions : A main active principle of anitplatelet Ulmi Cortex extract is W3 fraction, of which main active component is catechin considering its antiplatelet activity and content.

ABSOLUTE PARAMETERS AND MASS-RADIUS-LUMINOSITY RELATIONS FOR THE SUB-TYPES OF W UMα BINARIES

  • AWADALLA N. S.;HANNA M. A.
    • 천문학회지
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    • 제38권2호
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    • pp.43-57
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    • 2005
  • The authors have assembled a sample of 80 W UMa binary systems (42 W-subtype and 38 A-subtype) whose light curves have all been solved by means of the recent W-D code and combined with up-to-date radial velocity solutions. The absolute parameters (masses, radii and luminosities) have been derived (without any constraint on the physical parameters). The main results of this paper are: (1) the mass-luminosity relations for both W&A-subtypes. as well as for all W UMa contact binaries have been shown, (2) the mass-radius relations have been found for both subtypes, (3) some remarks on the evolution status have been presented.

ATOMIC CARBON IN THE W 3 GIANT MOLECULAR CLOUD

  • SAKAI TAKESHI;OKA TOMOHARU;YAMAMOTO SATOSHI
    • 천문학회지
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    • 제38권2호
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    • pp.257-260
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    • 2005
  • We have mapped the W 3 giant molecular cloud in the $C^o\;^3P_1-^3 P_o$ ([CI]) line with the Mount Fuji Submillimeter-wave Telescope. The [CI] emission is extended over the molecular cloud, having peaks at three star forming clouds; W 3(Main), W 3(OH), and AFGL 333. The [CI] emission is found to be strong in the AFGL 333 cloud. We have also observed the $C^{18}O,\;CCS,\;N_2H^+$, and $H^{13}CO^+$ lines by using the Nobeyama Radio Observatory 45 m telescope. In the AFGL 333 cloud, we find two massive cores, which are highly gravitationally bound and have no sign of active star formation. The high [$C^o$]/[CO] and [CCS]/[$N_2H^+$] abundance ratios suggest that the AFGL 333 cloud is younger than the W 3(Main) and W 3(OH) clouds.

DTV방송에 대비한 H/W중심의 MPEG Bitstream에서의 실시간 장면변환 검출방법 (Real time Shot Change Detection in focus of H/W prepare for DTV broadcasting)

  • 장경훈;이동호
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2000년도 제13회 신호처리 합동 학술대회 논문집
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    • pp.725-728
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    • 2000
  • 본 논문에서는 영상검색 기법에서 핵심인 Shot Change Detection 과 Non Linear Browsing 을 H/W기반으로 구현하여, S/W 적으로는 비실시간으로만 가능하였던 video indexing 을 DTV 에 적용하여 실시간으로 구현하는 방법을 제시한다. 이를 위해 H/W part 는 실시간으로 들어오는 방송용 MPEG-2 bitstream 을 full decoding 이 아닌 최소화된 VLD(Variable Length Decoding) 수준의 parsing 으로 picture 내의 luminance와 chrominance 의 DC 값, macroblock type, motion vector 정보를 얻어내어 각각의 histogram을 계산하여 memory interface를 통해 S/W 측에 넘겨주게 되고 S/W 는 각 상황에 맞게 indexing algorithm 을 변화시키며 최적의 video indexing 방법으로 확장할 수 있도록 하였다.

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V/W형 왕복동 공기압측기의 평형에 관한 연구 (A Study on the Balancing of V/W-type Reciprocating Air Compressor)

  • 김형진;김성춘;김정만;김의간
    • 한국소음진동공학회논문집
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    • 제14권1호
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    • pp.24-31
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    • 2004
  • Recently, as the marine compressor power is increased, vibration problems on the marine vessel with V/W type reciprocating compressor have been occurred. A research on the balancing of marine V/W type reciprocating compressor has hardly been reported though a number of researches on the balancing of rotating machinery have been conducted. As a V/W type compressor has high capacity with long stroke, compact size and high center of gravity, It is easy to have a vibration problem by a little bit unbalanced force and moment. In this study, calculation methods for balance weight of the V/W type reciprocating compressors, which have different piston weight and asymmetry structure, are formulated. And their reliability were verified by comparing calculated balance weight with the experimental results of the real marine V/W type reciprocating compressors.

A NEW CHARACTERIZATION OF PRÜFER v-MULTIPLICATION DOMAINS

  • CHANG, GYU WHAN
    • Korean Journal of Mathematics
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    • 제23권4호
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    • pp.631-636
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    • 2015
  • Let D be an integral domain and w be the so-called w-operation on D. In this note, we introduce the notion of *(w)-domains: D is a *(w)-domain if $(({\cap}(x_i))({\cap}(y_j)))_w={\cap}(x_iy_j)$ for all nonzero elements $x_1,{\ldots},x_m$; $y_1,{\ldots},y_n$ of D. We then show that D is a $Pr{\ddot{u}}fer$ v-multiplication domain if and only if D is a *(w)-domain and $A^{-1}$ is of finite type for all nonzero finitely generated fractional ideals A of D.

산화물환원에 의한 W-15wt%Cu 나노복합분말의 합성과 특성 (Synthesis and Characteristics of W-l5wt%Cu Nanocomposite Powder by Oxide Reduction)

  • 윤의식
    • 한국분말재료학회지
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    • 제4권4호
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    • pp.304-309
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    • 1997
  • The synthesis of W-l5wt%Cu nanocomposite powder by hydrogen reduction of ball milled W-Cu oxide mixture was investigated in terms of powder characteristics such as particle size, mixing homogeneity and micropore structure. It is found that the micropores in the ball milled oxide (2-50 nm in size) act as an effective removal path of water vapor, followed by the formation of dry atmosphere at reaction zone. Such thermodynamic condition enhances the nucleation of W phase but suppresses the growth process, being in favor of the formation of W nanoparticles (about 21 nm in size). In addition, the superior mixing homogeneity of starting oxide mixture turned out to Play a significant role for forming extraordinary chemical homogeneity of W-l5wt%Cu nanocomposite powder.

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모델 테스트에 의한 Bulldozer Blade의 견인력(牽引力) 예측(豫測) (Draft Prediction of Bulldozer Blade by Model Tests)

  • 이규승;노상철
    • Journal of Biosystems Engineering
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    • 제18권3호
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    • pp.209-219
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    • 1993
  • A series of soil bin experiment was carried out on sand to investigate if true model theory is applicable to blade-soil system and finally to find mathematical relationship between the dimensionless terms which contain the blade-soil parameters. The following conclusions were derived from the study. 1. It was proved that the draft of the prototype blade can be predicted without distortion by those of model blades with the length scale of 1.2, 2 and 2.4. 2. For the sand, bulk density was found to be a good measure of soil physical properties which are pertinent to predict the draft of the blade-soil system. 3. The mathematical relationship between $D/{\gamma}W$ and d/W, ${\beta}$, and $V^2/Wg$ are as follows ; $$\frac{D}{{\gamma}W^3}=124.98[\frac{d}{W}]^2+7.16[\frac{d}{W}]+0.43 \\ \frac{D}{{\gamma}W^3}=-0.00099{\beta}^2+0.13{\beta}-2.01 \\ \frac{D}{{\gamma}W^3}=0.041[\frac{V^2}{Wg}]^2+0.08[\frac{V^2}{Wg}]+1.3$$

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