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Effect of Tungsten on PtRuW/C Catalysts for Promoting Methanol Electro-oxidation (메탄올 전기산화반응 증진을 위한 PtRuW/C 촉매에서 텅스텐의 효과에 관한 연구)

  • Noh, Chang Soo;Sohn, Jung Min;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.23 no.6
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    • pp.561-566
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    • 2012
  • PtRuW/C catalysts were prepared with the different molar ratios of Pt : Ru : W and their compositions were analyzed by energy dispersive X-ray (EDX). The uniform distribution of particles was observed using transmission electron microscopy (TEM). An average crystalline size of 3.5~5.5 nm was calculated based on x-ray diffraction (XRD) data. The electrochemical properties such as electrochemically active surface areas, current densities, specific activities and poisoning rates, were analyzed via CO stripping, linear sweep voltammetry and chronoamperometry. From the analysis, we observed that ternary alloy catalysts, except $PtRu_2W_2/C$, have higher current densities, specific activities and stabilities than those of commercial binary catalysts. Among all in-house catalysts, Pt5Ru4W/C showed the highest specific activity of $121.05mA{\cdot}m^{-2}$ and the lowest poisoning rate of $0.01%{\cdot}s^{-1}$.

Inhibitory Activities of Ethanol Extracts from Saururus chinensis L. against Stress-Induced Hemorrhagic Gastritis (삼백초 에탄올 추출물의 위출혈성 스트레스 위염 억제 효과)

  • Park, So-Young;Cho, Young-Je
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.6
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    • pp.800-808
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    • 2015
  • In this study, gastritis inhibitory substance was ethanol-extracted from Saururus chinensis in order to examine the effect as a part of natural bioactive substance research. In an oral administration experiment, S. chinensis was administered at doses of 0.25 g/kg B.W. to 2 g/kg B.W., resulting in stabilization at 1.5 g/kg B.W. and an $LD_{50}$ of 1.81 g/kg B.W. In a chronic toxicity experiment, 0.5 g/kg B.W. of S. chinensis was administered for 13 weeks, but toxicity was not observed. S. chinensis ethanol-extracts were administered at a concentration of 250 or 500 mg/kg B.W. before induction of gastritis. Gastrorrhagia, stomach edema, cytokine production, and cell damage were reduced in a concentration-dependent manner. Therefore, S. chinensis ethanol extracts inhibit cell damage by stress-induced hemorrhagic gastritis in a concentration-dependent manner via inhibition of cytokine expression.

Antiplatelet fraction from Ulmi cortex and its active components (유백피의 항혈전 활성 분획 및 유효성분에 관한 연구)

  • Kim, Dong-Seon;Yang, Won-Kyung;Sung, Yoon-Young;Lim, Sun Mi;Kim, Ho Kyoung
    • The Korea Journal of Herbology
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    • v.28 no.3
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    • pp.39-44
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    • 2013
  • Objectives : The purpose of this study was to identify active fraction and components from antiplatelet Ulmi cortex extract. Methods : The 70% ethanol extract of Ulmi cortex was subjected to column chromatography over D101 resin and eluted with an 20% (W1), 30% (W2), 40% (W3), 50%(W4), 70% (W5), and 100% ethanol (W6) to yield 6 fractions. W6 was further fractioned and its active components were purified using semi-preparative HPLC. The isolated compounds were identified by MS and NMR, and their contents were simultaneously analyzed using HPLC/UV. Antiplatelet aggregation activities of the fractions and the compounds were evaluated using rat platelet-rich plasma in presence of collagen ($5{\mu}g/ml$), arachidonic acid (0.05 U/ml), or thrombin ($100{\mu}M$). Results : Among six fractions, W3 prominently inhibited platelet aggregation. At the concentration of $200{\mu}g/ml$, W3 strongly inhibited arachidonic acid- and collagen-induced platelet aggregations by 78.2% and 65.9%, respectivley, and weakly inhibited thrombin-inducded platelet aggregation by 32.6%. Catechin, epicatehin, and catechin-7-O-${\beta}$-D-glucopyranoside were isolated from W3 and their contents were revealed to be 15.1%, 0.87%, and 0.32%. Catechin and epicatechin at the concentrations of $100{\mu}M$ strongly inhibited collagen-induced platelet aggregation by 79.9% and 86.6%, respectively, but weakly inhibited arachidonic acid- and thrombin-induced platelet aggregations. Conclusions : A main active principle of anitplatelet Ulmi Cortex extract is W3 fraction, of which main active component is catechin considering its antiplatelet activity and content.

ABSOLUTE PARAMETERS AND MASS-RADIUS-LUMINOSITY RELATIONS FOR THE SUB-TYPES OF W UMα BINARIES

  • AWADALLA N. S.;HANNA M. A.
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.43-57
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    • 2005
  • The authors have assembled a sample of 80 W UMa binary systems (42 W-subtype and 38 A-subtype) whose light curves have all been solved by means of the recent W-D code and combined with up-to-date radial velocity solutions. The absolute parameters (masses, radii and luminosities) have been derived (without any constraint on the physical parameters). The main results of this paper are: (1) the mass-luminosity relations for both W&A-subtypes. as well as for all W UMa contact binaries have been shown, (2) the mass-radius relations have been found for both subtypes, (3) some remarks on the evolution status have been presented.

ATOMIC CARBON IN THE W 3 GIANT MOLECULAR CLOUD

  • SAKAI TAKESHI;OKA TOMOHARU;YAMAMOTO SATOSHI
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.257-260
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    • 2005
  • We have mapped the W 3 giant molecular cloud in the $C^o\;^3P_1-^3 P_o$ ([CI]) line with the Mount Fuji Submillimeter-wave Telescope. The [CI] emission is extended over the molecular cloud, having peaks at three star forming clouds; W 3(Main), W 3(OH), and AFGL 333. The [CI] emission is found to be strong in the AFGL 333 cloud. We have also observed the $C^{18}O,\;CCS,\;N_2H^+$, and $H^{13}CO^+$ lines by using the Nobeyama Radio Observatory 45 m telescope. In the AFGL 333 cloud, we find two massive cores, which are highly gravitationally bound and have no sign of active star formation. The high [$C^o$]/[CO] and [CCS]/[$N_2H^+$] abundance ratios suggest that the AFGL 333 cloud is younger than the W 3(Main) and W 3(OH) clouds.

Real time Shot Change Detection in focus of H/W prepare for DTV broadcasting (DTV방송에 대비한 H/W중심의 MPEG Bitstream에서의 실시간 장면변환 검출방법)

  • 장경훈;이동호
    • Proceedings of the IEEK Conference
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    • 2000.09a
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    • pp.725-728
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    • 2000
  • 본 논문에서는 영상검색 기법에서 핵심인 Shot Change Detection 과 Non Linear Browsing 을 H/W기반으로 구현하여, S/W 적으로는 비실시간으로만 가능하였던 video indexing 을 DTV 에 적용하여 실시간으로 구현하는 방법을 제시한다. 이를 위해 H/W part 는 실시간으로 들어오는 방송용 MPEG-2 bitstream 을 full decoding 이 아닌 최소화된 VLD(Variable Length Decoding) 수준의 parsing 으로 picture 내의 luminance와 chrominance 의 DC 값, macroblock type, motion vector 정보를 얻어내어 각각의 histogram을 계산하여 memory interface를 통해 S/W 측에 넘겨주게 되고 S/W 는 각 상황에 맞게 indexing algorithm 을 변화시키며 최적의 video indexing 방법으로 확장할 수 있도록 하였다.

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A Study on the Balancing of V/W-type Reciprocating Air Compressor (V/W형 왕복동 공기압측기의 평형에 관한 연구)

  • 김형진;김성춘;김정만;김의간
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.14 no.1
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    • pp.24-31
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    • 2004
  • Recently, as the marine compressor power is increased, vibration problems on the marine vessel with V/W type reciprocating compressor have been occurred. A research on the balancing of marine V/W type reciprocating compressor has hardly been reported though a number of researches on the balancing of rotating machinery have been conducted. As a V/W type compressor has high capacity with long stroke, compact size and high center of gravity, It is easy to have a vibration problem by a little bit unbalanced force and moment. In this study, calculation methods for balance weight of the V/W type reciprocating compressors, which have different piston weight and asymmetry structure, are formulated. And their reliability were verified by comparing calculated balance weight with the experimental results of the real marine V/W type reciprocating compressors.

A NEW CHARACTERIZATION OF PRÜFER v-MULTIPLICATION DOMAINS

  • CHANG, GYU WHAN
    • Korean Journal of Mathematics
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    • v.23 no.4
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    • pp.631-636
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    • 2015
  • Let D be an integral domain and w be the so-called w-operation on D. In this note, we introduce the notion of *(w)-domains: D is a *(w)-domain if $(({\cap}(x_i))({\cap}(y_j)))_w={\cap}(x_iy_j)$ for all nonzero elements $x_1,{\ldots},x_m$; $y_1,{\ldots},y_n$ of D. We then show that D is a $Pr{\ddot{u}}fer$ v-multiplication domain if and only if D is a *(w)-domain and $A^{-1}$ is of finite type for all nonzero finitely generated fractional ideals A of D.

Synthesis and Characteristics of W-l5wt%Cu Nanocomposite Powder by Oxide Reduction (산화물환원에 의한 W-15wt%Cu 나노복합분말의 합성과 특성)

  • 윤의식
    • Journal of Powder Materials
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    • v.4 no.4
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    • pp.304-309
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    • 1997
  • The synthesis of W-l5wt%Cu nanocomposite powder by hydrogen reduction of ball milled W-Cu oxide mixture was investigated in terms of powder characteristics such as particle size, mixing homogeneity and micropore structure. It is found that the micropores in the ball milled oxide (2-50 nm in size) act as an effective removal path of water vapor, followed by the formation of dry atmosphere at reaction zone. Such thermodynamic condition enhances the nucleation of W phase but suppresses the growth process, being in favor of the formation of W nanoparticles (about 21 nm in size). In addition, the superior mixing homogeneity of starting oxide mixture turned out to Play a significant role for forming extraordinary chemical homogeneity of W-l5wt%Cu nanocomposite powder.

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Draft Prediction of Bulldozer Blade by Model Tests (모델 테스트에 의한 Bulldozer Blade의 견인력(牽引力) 예측(豫測))

  • Lee, K.S.;Roh, S.C.
    • Journal of Biosystems Engineering
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    • v.18 no.3
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    • pp.209-219
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    • 1993
  • A series of soil bin experiment was carried out on sand to investigate if true model theory is applicable to blade-soil system and finally to find mathematical relationship between the dimensionless terms which contain the blade-soil parameters. The following conclusions were derived from the study. 1. It was proved that the draft of the prototype blade can be predicted without distortion by those of model blades with the length scale of 1.2, 2 and 2.4. 2. For the sand, bulk density was found to be a good measure of soil physical properties which are pertinent to predict the draft of the blade-soil system. 3. The mathematical relationship between $D/{\gamma}W$ and d/W, ${\beta}$, and $V^2/Wg$ are as follows ; $$\frac{D}{{\gamma}W^3}=124.98[\frac{d}{W}]^2+7.16[\frac{d}{W}]+0.43 \\ \frac{D}{{\gamma}W^3}=-0.00099{\beta}^2+0.13{\beta}-2.01 \\ \frac{D}{{\gamma}W^3}=0.041[\frac{V^2}{Wg}]^2+0.08[\frac{V^2}{Wg}]+1.3$$

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