• 제목/요약/키워드: viscosity increase

검색결과 1,120건 처리시간 0.022초

유기 Hectorite Gel의 Rheology에 미치는 극성연가제에 관한 연구

  • 김창규
    • 대한화장품학회지
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    • 제10권1호
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    • pp.49-74
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    • 1984
  • Rheology of gels prepared with stearyl dimethyl benzyl ammonium hectorite (SDBAH) and various polar additives in n-butyl acetate was investigated by measuring the viscosity and rheogram. Including generally recognized polar additives, additional studies on the rheogram and viscosity were made with ether-type methyl cellosolve and carbitol, with dimethyl sulfoxide (DMSO) having sulfonyl group, and furthermore with above-mentioned polar additives containing small quantity of water, It was observed that molecular size, dipole moments and dielectric constants of polar additives had a great influence on viscosity increase and rheology of SDBAH gel, and the increase of SDBAH interlayer spacing was important factor in gel formation and viscosity change. It was also shown that thixotropy effect was increased with the increase of polar additive concentration, finally changed to rheopexy from thixotropy as the concentration of polar additives was increased more than about 40% of SDBAH weight. In addition thixotropy changed to rheopexy as the increase of shear rate. It was further found that the aqueous solutions of polar additives (water content, 5-25%) had more effects on rheology than additives without water, and particularly 95clo DMSO solution was the most effective. And the optimum concentration of polar additives showing maximum viscosity in the same SDBAH concentration system was examined.

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Extensional and Complex Viscosities of Linear and Branched Polycarbonate Blends

  • Park, Jung-Hoon;Hyun, Jae-Chun;Kim, Woo-Nyon;Kim, Sung-Ryong;Ryu, Seung-Chan
    • Macromolecular Research
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    • 제10권3호
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    • pp.135-139
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    • 2002
  • Blends of the linear bisphenol-A polycarbonate (L-PC) and randomly branched bisphenol-A polycarbonate (Br-PC), prepared by co-rotating twin screw extrusion, were investigated using differential scanning calorimetry (DSC), sag resistance time tester, extensional rheometry, and advanced rheometric expansion system (ARES). From the DSC results, the glass transition temperature (T$_{g}$) of the L-PC/Br-PC blend was increased with the increase of Br-PC in the blend, and the blend showed a single T$_{g}$, which suggests a miscible blend. The sag resistance time of the L-PC/Br-PC blend was increased with the increase of Br-PC in the blends. From the results of rheological measurements of the L-PC/Br-PC blends, the extensional viscosity and the complex viscosity of the blends were found to increase with the increase of Br-PC in the blends. The increase of extensional viscosity and complex viscosity was related with the increase of sag resistance time with the Br-PC in the L-PC/Br-PC blends.nds.

구강편평세포암종 환자에서의 혈액 점도와 혈액 변형성 변화에 대한 연구 (CHANGE OF BLOOD VISCOSITY AND DEFORMABILITY IN ORAL SQUAMOUS CELL CARCINOMA PATIENTS)

  • 윤필영;명훈;이종호;정필훈;김명진
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제30권3호
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    • pp.181-185
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    • 2004
  • Malignant tumor have hypoxic cell fraction, which makes radio-resistant and hypoxia in tumor is a result from the blood flow decrease caused by increase in blood flow resistance. Blood viscosity increase is major factor of increased blood flow resistance and it could be attributed to the decrease in blood deformability index. For the evaluation of the change of blood viscosity and blood deformability in oral squamous cell carcinoma, we perform the test of the change of those factors between the normal control group and oral squamous cell carcinoma cell patient group. Relative viscosity measured against distilled water was $5.25{\pm}0.14$ for normal control group, and $5.78{\pm}0.26$ for the SCC patient group and there was statistical significance between the groups. However, there was no significant difference between the groups in blood viscosity between the groups by tumor size (T1+T2 vs T3+T4). Also, there was no significant difference between the normal control group and SCC patient group in blood deformability index and between the groups by tumor size (T1+T2 vs T3+T4). Increase in blood viscosity was confirmed with this study and it can be postulated that modification blood viscosity might contribute to decrease of hypoxia fraction in oral squamous cell carcinoma, thus improve the effect of radiotherapy and it can be assumed that the main factor of blood viscosity increase is not decrease of blood deformability in oral squamous cell carcinoma.

Viscosity and Volume Effects on Convective Flows in PGSE-NMR Self-Diffusion Measurements at High Temperature

  • Seo, Ji Hye;Chung, Kee-Choo
    • 한국자기공명학회논문지
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    • 제16권2호
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    • pp.122-132
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    • 2012
  • The effects of the sample viscosity and volume on the convective flows induced by temperature gradient in PGSE-NMR self-diffusion measurements at high temperature have been investigated. The experimental results showed that the viscosity of the liquid sample strongly affects the magnitude of the convective flows as well as the diffusion coefficient itself. It was also found that the convective flows increase as the sample volume increase.

단위수량 및 증점제량이 콘크리트의 블리딩에 미치는 영향 (Influence of Unit Water and Viscosity Agents Contents on the Bleeding of Concrete)

  • 김은호;심보길;황인성;전충근;한천구
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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    • pp.232-328
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    • 2001
  • This paper investigates the influences of water content and viscosity agent on the bleeding of concrete. According to test results, fluidity shows decline tendency as water content decreases, and dosage of viscosity agent increases. PEO viscosity agent does not affect the air contents while, MC viscosity agent causes air loss. As for bleeding, bleeding decreases with decrease of water content. As dosage of viscosity agent increase, bleeding decreases, regardless of viscosity kinds. It is thought that viscosity agents have the favorable effect of reducing bleeding, if fluidity and air loss are improved.

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강관다단공법에 적용되는 씰링재 (벤토나이트-시멘트 슬러리)의 점성 특성에 대한 실험 (An experimental study on the viscosity features of sealant (bentonite-cement slurry) in umbrella arch method)

  • 사공명;이준석;박정준;조충식
    • 한국터널지하공간학회 논문집
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    • 제20권5호
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    • pp.773-786
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    • 2018
  • 본 연구에서는 강관다단공법에 사용되는 씰링재의 점도특성에 대한 연구를 수행하였다. 씰링재는 차수 및 공벽 안정성 확보 기능과 더불어 후속공정인 그라우트재 주입 시 주입이 원활히 될 수 있도록 최소한의 강도를 보유하여야 한다. 교반조건에 따른 씰링재의 특성을 점도를 통하여 간접적으로 파악하였다. 초기 물과 벤토나이트의 사전 교반 특성에 따라 점도의 급격한 증가 시점이 상이하게 나타났다. 사전교반 시간이 길수록 벤토나이트가 팽윤 할 기회가 많아지므로 상대적으로 짧은 시간에 점도의 급격한 증가 현상이 나타났다. 또한 급격한 점도 증가 이전 단계에서는 물/시멘트/벤토나이트 혼합물이 틱소트로피 거동을 보이다가 점도 증가 이후부터는 레오펙시 거동을 보인다. 또한 사전 교반 시간은 혼합물이 재료분리 거동에도 영향을 미침이 확인이 되었다. 따라서 본 연구결과를 바탕으로 씰링재의 요구성능 및 배합절차에 대해서 추가 논의가 필요하며, 향후 시멘트와 벤트나이트의 상호작용에 대해 심도 깊은 연구를 통하여 현장에서 적용 가능한 가이드 도출이 필요하다.

구강편평세포암종 이식 누드마우스에서의 혈액 점도 변화 (BLOOD VISCOSITY CHANGE IN ORAL SQUAMOUS CELL CARCINOMA XENOTRANSPLANTED NUDE MICE)

  • 명훈;이종호;정필훈;김명진
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제30권2호
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    • pp.81-84
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    • 2004
  • It is well known that malignant tumor have hypoxic cell fraction, which is radio resistant and is one of the most important cause of local recurrence after radiotherapy. One of the causes of hypoxia in tumor is blood flow decrease due to increase in blood flow resistance and one of the causes of increased blood flow resistance could be attributed to the increase in blood viscosity. For the evaluation of the change of blood viscosity in oral cancer, experiments were carried out to test the change of blood viscosity among the normal control and xenografted oral cancer nude mice. Relative viscosity measured against distilled water was $3.30{\pm}0.14$ for normal control, and $3.67{\pm}0.62$ for tumor bearing mice at the first time of blood sampling in experimental period ($100mm^3$ $200mm^3$). There was no statistically significant difference between the control group and experimental group (p>0.05). However, as the tumor grew, significant difference of blood viscosity was detected at the third time of blood sampling (control group:$3.37{\pm}0.59$, and experimental group: $4.31{\pm}0.41\;300mm^3$

혈전증(血栓症) 및 고점도혈증(高粘度血症)에 관(關)한 보양환오탕(補陽還五湯)의 실험적(實驗的) 연구(硏究) (Study on the effect of Boyanghwanotang on Thrombosis and Elevated Blood Viscosity)

  • 송효정
    • 대한한방내과학회지
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    • 제10권1호
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    • pp.137-155
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    • 1989
  • In order investigate the effect of Boyanghwanotang (BT) on thrombosis, Sprague-Dawley rats injected endotoxin into the caudal vein were oral administrated solid extract of BT-182. 4mg/200g (Sample A) and 364.8mg/200g (Sample B), and then observed Platelet, fibrinogen, prothrombin time and FDP. Another group injected hydrocortisone acetate into the muscular rump were adopted to observe the effect of BT on elevated blood Viscosity, administrated Sample A and Sample B, thereafter measured body weight, body temperature, whole blood viscosity, plasma viscosity, hematocrit, RBC, WBC, hemoglobin, glucose, albumin, total protein, triglyceride, cholesterol and prothrombin time. 1. Platelet was increased significantly in Sample B compared with the control group. 2. Fibrinogen of the trial groups compared with the control group was increased, and revealed a significance in Sample B. 3. Prothrombin time was decreased significantly in the trial groups compared with the control group. 4. FDP was decreased in the trial groups compared with the control group. 5. Body weight was increased significantly in Sample B after 7 days, body temperature revealed a significance in the trial groups after 5 days. 6. Whole blood viscosity and plasma viscosity of lower shear rates, both were highly decreased in the trial groupn than the control group. 7. The increase of WBC and decrease of hematocrit, RBC and hemoglobin was showed in the trial groups, and Sample B revealed a significance on the increase of WBC and decrease of RBC. 8. The increase of prothrombin time and decrease of glucose, albumin, total protein, triglyceride and cholesterol was showed in the trial group, and Sample B revealed a Significance on the increase of prothrombin time and decrease of albumin, total protein and triglyceride. 9. As compare with Sample A and Sample B, generally Sample B was highly Significant. According to the above results, it was considered that Boyanghwanotang may be the curative effects for thrombosis and elevated blood viscosity.

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식품공정의 에너지 절감과 품질향상에 관한 연구(1). 세선 가열법의 식품 생물공학에의 응용 (On Energy Saving and Quality Improvement of Food Process (1). Applications of Hotwire Monitoring System for Food Biotechnology)

  • 허종화;크라우
    • KSBB Journal
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    • 제5권4호
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    • pp.403-410
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    • 1990
  • Application of the Rheocatch Hotwire Monitoring System for food biotechnology process was evaluated. The growth of microogranism, E coli (JM 83 and Sigma) and Corynesccfertun glutamicum, were monitored. in the fermentor. The cell growth could not be detected the temperature differences between the hotwire and samples($\Delta$T) as indicated by the monitoring system during the fermentation processes. The cell concentration of less than 2g/dl was not sufficient to generate the measurable temperature difference in the fermentor. In order to calibrate the Rheocatch Monitoring System, the temperature difference as a function of solute concentration (microbial cells, sodium cholide, sucrose and dextran) was studied. The relationship between $\Delta$T and the concentration of microbial cells, sucrose and dextran can be expressed in a power series. Further studied with dextran indicated that viscosity and/or kinematic viscosity increase exponentially with an increase in $\Delta$T This is regardless of the concentration and molecular weight of dextran. $\Delta$T linearly increases with the logarithm of molecular weight, while the logarithm of viscosity and the logarithm of kinematic viscosity increase with the logarithm of molecular weight.

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Effect of surfactant adsorption on the rheology of suspensions flocculated by associating polymers

  • Otsubo, Yasufumi;Horigome, Misao
    • Korea-Australia Rheology Journal
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    • 제15권4호
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    • pp.179-185
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    • 2003
  • Associating polymers act as flocculants in colloidal suspensions, because the hydrophobic groups (hydrophobes) can adsorb onto particle surfaces and create intermolecular cross-linking. The steady-shear viscosity and dynamic viscoelasticity were measured for suspensions flocculated by multichain bridging of associating polymers. The effects of surfactant on the suspension rheology are studied in relation to the bridging conformation. The surfactant molecule behaves as a displacer and the polymer chains are forced to desorb from the particle surfaces. The overall effect of surfactant is the reduction of suspension viscosity. However, the additions of a small amount of surfactant to suspensions, in which the degree of bridging is low, cause a viscosity increase, although the number of chains forming one bridge is decreased by the forced desorption of associating polymer. Since the polymer chains desorbed from one bridge can form another bridge between bare particles, the bridging density over the system is increased. Therefore, the surfactant adsorption leads to a viscosity increase. The surfactant influences the viscosity in two opposing ways depending on the degree of bridging.