• Korea-Australia Rheology Journal
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• v.20 no.4
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• pp.235-243
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• 2008

The aim of this study is to explore the possibility of incorporating supercritical carbon dioxide ($scCO_2$) into twin screw extrusion process for the production of polypropylene-clay nanocomposite (PPCN). The $CO_2$ is used as a reversible plasticizer which is expected to rapidly transport polymeric chains into the galleries of clay layers in its supercritical condition inside the extruder barrel and to expand the gallery spacings in its sub-critical state upon emerging from die. The structure and properties of the resulting PPCNs are characterized using wide-angle X-ray diffraction (WAXD), transmission electron microscopy (TEM), rheometry, thermogravimetry and mechanical testing. In the processing of the PPCNs with $scCO_2$, optimum $scCO_2$ concentration and screw speed which maximized the degree of intercalation of clay layers were observed. The WAXD result reveals that the PP/PP-g-MA/clay system treated with $scCO_2$ has more exfoliated structure than that without $scCO_2$ treatment, which is supported by TEM result. $scCO_2$ processing enhanced the thermal stability of PPCN hybrids. From the measurement of linear viscoelastic property, a solid-like behavior at low frequency was observed for the PPCNs with high concentration of PP-g-MA. The use of $scCO_2$ generally increased Young's modulus and tensile strength of PPCN hybrids.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.2
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• pp.180-187
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• 2005

This paper is focused on the development of the flexible electrode for disc-type polymer actuators using Segmented Polyurethane(SPU). This paper consists of two parts. The one is about the mechanical property such as elastic modulus. these parameters mainly affect behaviors of polymer actuators and the other is about the electro-chemical property such as the surface resistance of the composite electrode affects the strength of electrostatic force, results in the deformation of polymer actuators. The Young's modulus was measured by UTM. As result, by increasing the modulus of a body of polymer actuators, the maximum displacement of polymer actuators are decreased. The surface resistance of the electrode was measured by 4 point probe system. Compared with the conductive silver grease, the displacement of polymer actuators using carbon black(CB) composite electrodes is comparably small but CB composite electrode should be the practical approach for the improvement of the performance of all-solid actuators, compared with another types of electrode materials.

• Korea-Australia Rheology Journal
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• v.18 no.4
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• pp.171-181
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• 2006

We present a short review for authors' previous work on direct numerical simulations for inertialess hard particle suspensions formulated either with a Newtonian fluid or with viscoelastic polymeric fluids to understand the microstructural evolution and the bulk material behavior. We employ two well-defined bi-periodic domain concepts such that a single cell problem with a small number of particles may represent a large number of repeated structures: one is the sliding bi-periodic frame for simple shear flow and the other is the extensional bi-periodic frame for planar elongational flow. For implicit treatment of hydrodynamic interaction between particle and fluid, we use the finite-element/fictitious-domain method similar to the distributed Lagrangian multiplier (DLM) method together with the rigid ring description. The bi-periodic boundary conditions can be effectively incorportated as constraint equations and implemented by Lagrangian multipliers. The bulk stress can be evaluated by simple boundary integrals of stresslets on the particle boundary in such formulations. Some 2-D example results are presented to show effects of the solid fraction and the particle configuration on the shear and elongational viscosity along with the micro-structural evolution for both particles and fluid. Effects of the fluid elasticity has been also presented.

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3163-3172
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• 2010

In this work, a novel method to synthesis of an acrylic superabsorbent hydrogel was reported. In the two stage hydrogel synthesis, first copolymerization reaction of acrylonitrile (AN) and acrylamide (AM) monomers using ammonium persulfate (APS) as a free radical initiator was performed. In the second stage, the resulted copolymer was hydrolyzed to produce carboxamide and carboxylate groups followed by in situ crosslinking of the polyacrylonitrile chains. The results from FTIR spectroscopy and the dark red-yellow color change show that the copolymerization, alkaline hydrolysis and crosslinking reactions have been do take place. Scanning electron microscopy (SEM) verifies that the synthesized hydrogels have a porous structure. The results of Brunauer-Emmett-Teller (BET) analysis showed that the average pore diameter of the synthesized hydrogel was 13.9 nm. The synthetic parameters affecting on swelling capacity of the hydrogel, such as AM/AN weight ratio and hydrolysis time and temperature, were systematically optimized to achieve maximum swelling capacity (330 g/g). The swollen gel strength of the synthesized hydrogels was evaluated via viscoelastic measurements. The results indicated that superabsorbent polymers with high water absorbency were accompanied by low gel strength. The swelling of superabsorbent hydrogels was also measured in various solutions with pH values ranging from 1 to 13. Also, the pH reversibility and on-off switching behavior makes the hydrogel as a good candidate for controlled delivery of bioactive agents. Finally, the swelling of synthesized hydrogels with various particle sizes obey second order kinetics.

• Korean Journal of Food Science and Technology
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• v.32 no.6
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• pp.1313-1318
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• 2000

총고형분 함량$(TS:\;50{\sim}57%)$을 달리하여 숙성시킨 고추장의 유동특성, 정적 및 동적점탄특성을 관찰하였다. 고추장의 TS가 증가함에 따라서 점조도 지수(K)와 겉보기 점도$({\eta}_{a.5})$는 증가하였으며 유동성 지수(n)는 1보다 훨씬 낮은 0.24-0.31의 범위를 나타내어 고추장은 shear-thinning 성질을 보여주었다. 고추장의 항복응력 측정에서는 고추장의 TS가 증가함에 따라 Casson 항복응력$({\sigma}_{oc})$은 증가하는 경향을 나타내었으며, 또한 고추장의 액상 매개체인 serum 점도$({\eta}_{se})$는 고추장의 TS와 매우 좋은 상관관계$(R^2=0.97)$를 나타내었다. 고추장의 동적점탄성 실험에서는 주파수$({\omega})$가 증가함에 따라 저장탄성률(G#)와 손실탄성률(G@)은 증가하였으며 양(+) 기울기로 G#수치가 G@수치보다 높게 나타났다. 이는 고추장이 약한 겔과 같은 구조적 특성을 갖고 있으며 또한 shear-thinning 거동을 가지고 있음을 나타낸다. 정적점탄성 실험에서 고추장의 총고형분 함량에 따라서 순간탄성 변형$(J_0)$과 지연탄성변형$(J_1)$은 총고형분 함량이 증가함에 따라서 감소하였으며 점도$({\eta}_N)$와 지연시간 $({\tau}_1)$은 증가하였다. 따라서 고추장은 농도가 증가함에 따라 보다 탄력적이며 안정된 구조를 형성하고 있음을 알 수 있었다.

• International Journal of Reliability and Applications
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• v.17 no.2
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• pp.137-147
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• 2016

The engine mount of a car subjected to a pre-load related to the weight of the engine, and acts to insulate the vibration coming from the engine by moving on large or small displacement depending on the driving condition of the car. The vibration insulation of the engine mount is an effect obtained by dissipating the mechanical energy into heat by the viscosity characteristic of the rubber and the microscopic behavior of the additive carbon black. Therefore, dynamic stiffness from the intrinsic properties of rubber filled with carbon black at the design stage is an important design consideration. In this paper, we introduced a hyper-elastic, visco-elastic and elasto-plastic model to predict the dynamic characteristics of rubber, and developed a fitting program to determine the material model parameters using MATLAB. The dynamic characteristics analysis of the rubber insulator of the ACTIVE MOUNT was carried out by using MSC.MARC nonlinear structural analysis software, which provides the dynamic characteristics material model. The analysis results were compared with the dynamic characteristics test results of the rubber insulator, which is one of the active mount components, and the analysis results were confirmed to be valid.

• Smart Structures and Systems
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• v.23 no.6
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• pp.683-693
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• 2019

In August 2012, during the passage of the typhoon Haikui (1211), large amplitude vibrations were observed on long hangers of the Xihoumen suspension Bridge, which destroyed a few viscoelastic dampers originally installed to connect a pair of hanger ropes transversely. The purpose of this study is to identify the cause of vibration and to develop countermeasures against vibration. Field measurements have been conducted in order to correlate the wind and vibration characteristics of hangers. Furthermore, a replica aeroelastic model of prototype hangers consisting of four parallel ropes was used to study the aeroelastic behavior of hanger ropes and to examine the effect of the rigid spacers on vibration mitigation. It is shown that the downstream hanger rope experiences the most violent elliptical vibration for certain wind direction, and the vibration is mainly attributed to wake interference of parallel hanger ropes. Based on wind tunnel tests and field validation, it is confirmed that four rigid spacers placed vertically at equal intervals are sufficient to suppress the wake-induced vibrations. Since the deployment of spacers on hangers, server hanger vibrations and clash of hanger ropes are never observed.

• Macromolecular Research
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• v.17 no.5
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• pp.332-338
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• 2009

Rheological behavior of natural hydrogel produced from seeds of three Salvia spp. (S. miltiorrhiza (SM), S. sclarea (SS), S. viridis (SV)) was investigated by using a Rheometer equipped with a cone and plate geometry measuring system under never-dried condition. Different chemical contents of such hydrogels give significant effects on their rheological properties. Because of incomplete penetration of water inside the hydrogels after drying before-dried hydrogels were used for rheological analysis. To know molecular interactions which predominated in the gel formation, some constituents were externally added to the 1.0% (w/w) hydrogel. Addition of urea to disrupt hydrogen bonds reduced 3.4-67% viscosity of the untreated hydrogels and changed viscoelastic properties from gel to liquid-like behavior. Neutral salts added to the hydrogel solution at 0.1 M also lowered the viscosity in a manner related with increase in size of cations and temperature. Changing from gel state to liquid-like state was also easily confirmed by oscillation measurement (storage, G', and loss, G", modulii) typically observed in the cases of potassium sulfate and potassium thiocyanate. Influence of pH variation on the viscosity explained that weak alkaline condition (pH 8-9) creates a higher resistance to flow due to increasingly electrostatic repulsions between negative charges ($COO^-$) Importance of calcium bridges was also demonstrated by recovery of viscosity of the hydrogels by addition of calcium after acidification. The summarized results indicate that electrostatic repulsion is a major contributor for production of hydrogel structure.

• Steel and Composite Structures
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• v.34 no.5
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• pp.643-655
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• 2020

In the present work, the buckling behavior of a single-layered graphene sheet (SLGS) embedded in visco-Pasternak's medium is studied using nonlocal four-unknown integral model. This model has a displacement field with integral terms which includes the effect of transverse shear deformation without using shear correction factors. The visco-Pasternak's medium is introduced by considering the damping effect to the classical foundation model which modeled by the linear Winkler's coefficient and Pasternak's (shear) foundation coefficient. The SLGS under consideration is subjected to compressive in- plane edge loads per unit length. The influences of many parameters such as nonlocal parameter, geometric ratio, the visco-Pasternak's coefficients, damping parameter, and mode numbers on the buckling response of the SLGSs are studied and discussed.

• International Journal of Highway Engineering
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• v.7 no.4 s.26
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• pp.203-210
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• 2005

The penetration and viscosity tests have been used for the evaluation of the aged asphalt binder performance change. The improved test method has been required because the conventional tests could not evaluate the viscoelastic characteristics and the real behaviour of the aged asphalt binder. The conventional test methods using a different short term aged asphalt binder were tested and the test results were expressed as the penetration index and the residual penetration. The oscillatory and rotational mode tests were performed to find out the rheological characteristics of the short term aged asphalt binder in this study. The test results showed that the change of testing frequency, the speed of the vehicle effects the complex modules and phase angles. The creep compliance and shear viscosity also showed the different test results when the short term aged asphalt binders were tested. The rheological behavior should consider when the pavement design is conducted.