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Investigation of Compressive Strength and Foaming Characteristics of Acid Anhydride Epoxy Foam by Foaming Agent (발포제에 따른 산무수물계 에폭시 폼의 압축강도 및 포밍특성 분석)

  • Kwon, Dong-Jun;Kim, Jong-Hyun;Park, Sung-Min;Kwon, Il-Jun;Park, Joung-Man
    • Composites Research
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    • v.31 no.4
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    • pp.133-138
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    • 2018
  • Polymer foams were used to fill the void in the structure in addition to flame retardant and heat insulation. Polymer foams such as polyurethane, polyisocyanurate, poly(vinyl chloride), polyethylene terephthalate were used to weight lighting materials. In this study, epoxy foam was used to improve mechanical properties of polymer foam. Acid anhydride type hardener reacts with polyol. Using this phenomenon, if blowing agent was added into epoxy resin using acid anhydride type hardener, formation and compressive properties of epoxy foam was studied. Formation of polymer foam was compared with type of blowing agent and concentration of blowing agent via compressive test. As these results, optimized condition of epoxy foam was found and epoxy foam had better compressive property than other polymer foam.

An Investigation on the Nonlinear Shear Behavior of FRP Composites Considering Temperature Variation and Fabricating Parameters (FRP 복합재료의 온도변화 및 제작인자별 비선형 전단거동 조사)

  • Jung, Woo-Young;Hwang, Jin-Seop
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.3
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    • pp.833-841
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    • 2013
  • In the case of composite material, a variety of characteristics were expressed depending on the materials that were composed of. In this study, the materials showing non-linear shear behavior were investigated among FRP composite. Each specimen was designed and analyzed according to ASTM D4255 method: regulations on the 2-rail. The dependent variables included in this experiment were a variety of fiber, fiber volume ratio, fiber array direction, temperature, material homogeneity. For determination of characteristics based on the fiber array, fiber array direction of 0, 30, 45, and 60 degrees were selected for test specimen. Temperature of 25, 40, 60, and $80^{\circ}C$ were considered for investigation of FRP materials'shear behavior based on the external temperature. Nonlinear shear behavior was observed throughout the FRP composite material in this study. Also, using vinyl ester resins, high fiber volume ratio, and fiber array direction of 45 degree appeared to show the most prominent nonlinear shear behavior. As for the findings related to the temperature change, non-linear behavior was decreased as the external temperature increased. For factory manufactured product, non-linear behavior was relatively at parity in comparison to the behavior found in the hand lay-up FRP composite specimen.

All-Solid-State Ion-Selective Electrodes With Organic Solvents Soluble Conducting Polymer for Chemical Sensor (화학센서를 위한 유기 용해성이 좋은 도전성 고분자가 포함된 전체 고체상태 이온 선택성 전극에 대한 연구)

  • Kim, Joong-Il;Park, Jong-Ho;Jang, Won;Heo, Min;Na, Young-Ho;Shin, Jae-Ho;Kim, Do-Young;Um, Hwan-Sub;Lee, Sang-Woo;Kim, In-Tae
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.258-263
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    • 2013
  • New conducting polymers containing heterocyclic ring with carbazole, EDOT and benzobisthiazole were synthesized and characterized by organic spectroscopic methods. Potentiometric ion-selective membrane electrodes (ISMEs) have been extensively used for ion analysis in clinical, environmental, and industeial fields owing to its wide response range (4 to 7 orders of magnitude), no effect of sample turbidity, fast response time, and ease of miniaturization. Considerable attention has been given to alternative use of room temperature vulcanizing (RTV)-type silicone rubber(SR) owing to its strong adhesion and high thermal durability. Unfortunately, the high membrane resistance of SR-based (ISMs)(2 to 3 higher orders of magnitude compared to those of poly(vinyl chloride)(PVC)-based ones) has significantly restricted its application. Herein we demonstrate a new method to reduce membrane resistance via addition of new conducting polymer into the SR-based ISMs.

Effect of Mulching Material on the Growth and Quality of Oriental Melon (Cucumis melo L. var. makuwa Mak.) in Protected Cultivation (멀칭재료가 시설참외의 생육과 품질에 미치는 영향)

  • Su Gon Bae;Yong Seub Shin;Il Kweon Yeon;Han Woo Do
    • Journal of Bio-Environment Control
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    • v.10 no.4
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    • pp.237-243
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    • 2001
  • The experiment was conducted to investigate the effect of different mulching materials on the growth and quality of oriental melon in protected cultivation. Soil temperature, plant growth and fruit quality were affected by different mulching materials, clear polyethylene (P.E.) film (control), clear inset between black P.E. film, green P.E. film. and recycled ethylene vinyl acetate (E.V.A.) film. The highest night soil temperature was at 20 cm depth under green P.E. film, but was at 5 cm depth under other materials. Difference of soil temperature as affected by mulching materials decreased with increasing soil depth. Plant height, number of nodes, leaf area index (LAI), crop growth rate (CGR), and relative growth rate (RGR) at 30 days after transplanting were significantly greater in the recycled E.V.A. film treatment than in the other treatments. Fresh weight of weeds growth under the mulching materials was not affected by mulching material at 30 days after transplanting. However, it was the greatest under clear P.E. film mulching at 90 days after transplanting. Harvesting time of recycled E.V.A. film was 2 days earlier than that of clear P.E. film. Difference in fruit weight and length, and soluble solid content were not affected by the mulching materials. Marketable yield was 2,426 kg.10a$^{-1}$ in recycled E.V.A. film treatment, which was 6% greater than in clear P.E. film treatment.

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Effect of Daytime Temperature on Fruit Cracking of Paprika Cultivars (착색단고추 품종별 주간온도가 열과 발생에 미치는 영향)

  • 최영하;권준국;이재한;강남준;조명환;손병구
    • Journal of Bio-Environment Control
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    • v.13 no.3
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    • pp.172-177
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    • 2004
  • This experiment was conducted to investigate the effect of daytime temperature on fruit crack-ing in the paprika cv. Fiesta and cv. Jubilee under soil culture experiment of vinyl house for two years from 2003 to 2004. The rate of cracked fruit was higher in cv. Fiesta than cv. Jubilee and was the highest at the high daytime temperature of $34\pm$$1^{\circ}C$. and then rapidly increased after April becomes better weather conditions. The flesh hardness and the rate of flesh dry weight were lower in cv. Fiesta than cv. Jubilee and were the lowest at the high daytime temperature of $34\pm$1$^{\circ}C$. but the thickness of flesh was thicker in cv. Fiesta than cv. Jubilee and was the thinnest at the high daytime temperature of $34\pm$$1^{\circ}C$. Inorganic matter contents of flesh was observed no difference to the cultivars and also the temperature treatments. Root condition in harvesting time was better in cv. Fiesta than cv. Jubilee and was not difference in temperature treatments. Therefore, the rate of cracked fruit showed up a positive correlation to the flesh hardness, flesh dry weight, flesh firmness and root condition, and has not correlation to the flesh thickness and inorganic matter con-tents. In conclusion, differences in cultivar sensitivity and the highest rate of cracked fruit in daytime temperature of $34\pm$$1^{\circ}C$ may be partly due to difference in flesh characteristic and root condition but additional factors may be involved.

Study on the Surface Design Used in S.F.A.A. Collection (SFAA 컬렉션에 활용된 서페이스 디자인연구)

  • 김주희;금기숙
    • Journal of the Korean Society of Costume
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    • v.52 no.1
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    • pp.129-143
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    • 2002
  • Patterns are something that comes out of necessity in human life, which is closely associated with it. Thus come the SFAA (Seoul Fashion Artists Association) collection which uses patterns varying in form, color, way of expression and material. For this research, I first categorized the patterns the SFAA designers used into: natural patterns, symmetric patterns, traditional patterns, stripe, plaid, dot and abstract patterns. As a result of the process. the designers most favored the natural patterns and symmetric patterns, and dot patterns were rarely used. The designer who most favored patterns in general was Sul Yun-hyoung, and the designer Kim Chul-ung rarely favored the surface effect. The seven kinds of patterns naturally differ according to the designer. as Park Hang-chi liked to use the plaid patterns along with yam dyeing material, whereas Jin Teok expressed stripe patterns using the yarn dyeing fabric. Natural patters were presented in a bizarre way with Lie Sang-bong. who took the motives appearing in Eastern ceramic and paintings into the clothes, using the print method. The symmetric patterns, which the SFAA designers most preferred. was used evenly among designers like Chang Kwang-hyo, Gee Choon-hee. Rubina, and Haneza. In contrast. Lie Sang-bong. who used abstract patterns that do not give out meaning of the actual form of the pattern. rarely used symmetric patterns. The dot patterns were most often used by Park Youn-soo. and traditional patterns were overwhelmingly chosen by Sul Yun-hyoung. Secondly. in expressing the colors, SFAA designers were much more likely to choose achromatic colors. not choosing to show off colors. This is especially apparent in works by Haneza and Lie Sang-bong. In the SFAA collections, numerous methods were used to create. For instance, Sul Yun-hyoung used the oriental embroidery method. and Rubina and Lie Sang-bong used many unique dying methods. In terms of materials, Sul Yun-hyoung preferred silk. due to her methods, and Lie Sang-bong was one of the designers that used a number of different materials such as vinyl. Jacques Mueclier of the Paris Clothes Association in France, who was invited to SFAA collection once, remarked. "While the choice of material and the actual sewing done were excellent, there lacked much difference among the designers, as most of them choose flowing silhouette In terms of composition," which is all too correct. In addition, there were cases in the collection where the inherent feelings of cultural artifacts was expressed without alteration. Summing up, the research aimed to analyze the surface expression methods, forms and color of SFAA designs. and I hope that it can open up ways for new projects in the future.he future.

Surface Dose and Transmission Factor for Vacuum Cushion (Vacuum Cushion 사용시 표면선량과 투과율 평가)

  • 김미화;이병용;전미선
    • Progress in Medical Physics
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    • v.13 no.2
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    • pp.74-78
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    • 2002
  • The individual (customized) immobilization has been used to reproduce the patients' set-up on daily base. There are many various devices available commercially. To evaluate dosimetric characteristics of vacuum cushion, we analysed the surface dose and transmission factor for d$_{max}$ when patient is immobilized with vacuum cushion. Experiments were performed with 4 MV (Varian 4/100, USA), 6 MV, 15 MV (Varian CL2100C/D, USA) photon beams and five field sizes (5$\times$5, 10$\times$10, 20$\times$20, 30$\times$30, 40$\times$40 $\textrm{cm}^2$) on each occasion. Outputs were measured from surface of polysterene phantom to d$_{max}$ with four different thicknesses of cushion, which is 12, 32, 48 mm and only vinyl without styroforms. As results, the transmission factor for thicknesses of vacuum cushion was ranged from 0.9953 to 1.0043. The more the thickness of vacuum cushion is thick, the more surface dose delivered to patient is increased. The surface dose vary with the thickness of vacuum cushion for energy and field size. The skin reactions may result. But the variation is not serious in the clinic.

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The electrical characteristics of flexible organic field effect transistors with flexible multi-stacked hybrid encapsulation

  • Seol, Yeong-Guk;Heo, Uk;Park, Ji-Su;Lee, Nae-Eung;Lee, Deok-Gyu;Kim, Yun-Je;An, Cheol-Hyeon;Jo, Hyeong-Gyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.176-176
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    • 2010
  • One of the critical issues for applications of flexible organic thin film transistors (OTFTs) for flexible electronic systems is the electrical stabilities of the OTFT devices, including variation of the current on/off ratio (Ion/Ioff), leakage current, threshold voltage, and hysteresis under repetitive mechanical deformation. In particular, repetitive mechanical deformation accelerates the degradation of device performance at the ambient environment. In this work, electrical stability of the pentacene organic thin film transistors (OTFTs) employing multi-stack hybrid encapsulation layers was investigated under mechanical cyclic bending. Flexible bottom-gated pentacene-based OTFTs fabricated on flexible polyimide substrate with poly-4-vinyl phenol (PVP) dielectric as a gate dielectric were encapsulated by the plasma-deposited organic layer and atomic-layer-deposited inorganic layer. For cyclic bending experiment of flexible OTFTs, the devices were cyclically bent up to 105 times with 5mm bending radius. In the most of the devices after 105 times of bending cycles, the off-current of the OTFT with no encapsulation layers was quickly increased due to increases in the conductivity of the pentacene caused by doping effects from $O_2$ and $H_2O$ in the atmosphere, which leads to decrease in the Ion/Ioff and increase in the hysteresis. With encapsulation layers, however, the electrical stabilities of the OTFTs were improved significantly. In particular, the OTFTs with multi-stack hybrid encapsulation layer showed the best electrical stabilities up to the bending cycles of $10^5$ times compared to the devices with single organic encapsulation layer. Changes in electrical properties of cyclically bent OTFTs with encapsulation layers will be discussed in detail.

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Blood Compatibility of Polyurethane-poly(vinyl alcohol) Polymer Blends (폴리우레탄-폴리비닐알콜 블렌드의 혈액적합성)

  • 김승수;유영미;신재섭;정규식
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.82-89
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    • 2000
  • The blood compatibilities of PU/PVA polymer blends with different mixing ratios were evaluated using various methods, such as fibrinogen adsorption, plasma recalcification time, platelet adhesion, whole blood clotting time, and complement activation. In addition, PVA on the surface of the polymer blends was crosslinked by glutaraldehyde to restrain the mobility of PVA molecules for characterizing the effect of PVA in the polymer blends on blood compatibility. The fibrinogen adsorption on the polymer blends decreased with the increase of PVA amount in the polymer blends. The plasma recalcification times of the polymer blends with 10-50 wt% PVA were longer than those of PU, PVA, and polymer blends with higher amount of PVA. The morphological changes and adhesion of platelets on the polymer blends with 30-50 wt% PVA were less than those on the other materials. The blood clotting times and complement activation on the polymer blends with 30-50 wt% PVA were reduced, compared to the other materials. On the other hand, the blood compatibility of the crosslinked polymer blends was relatively decreased, compared to the non-crosslinked ones. According to these experimental results, the blood compatibility of the polymer blends with 30-50 wt% PVA was better than that of the other materials and such a blood compatibility of the polymer blends might be related to the mobility of PVA molecules on the surface.

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A Study on the Effect of Different Functional Groups in Anion Exchange Membranes for Vanadium Redox Flow Batteries (바나듐 산화환원 흐름전지를 위한 음이온교환막의 관능기에 따른 특성 연구)

  • Lee, Jae-Myeong;Lee, Mi-Soon;Nahm, Ki-Seok;Jeon, Jae-Deok;Yoon, Young-Gi;Choi, Young-Woo
    • Membrane Journal
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    • v.27 no.5
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    • pp.415-424
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    • 2017
  • Commonly cation exchange membranes have been used for vanadium redox flow batteries. However, a severe vanadium ion cross-over causes low energy efficiency. Thus in this study, we prepared 3 different anion exchange membranes to investigate the effect on the membrane properties such as vanadium ion cross-over and long term stability. The base membranes were prepared by an electrolyte pore filling technique using vinyl benzyl chloride (VBC), divinylbenzene (DVB) within a porous polyethylene (PE) substrate. Then 3 different functional amines were introduced into the base membranes, respectively. These resulting membranes were evaluated by physico-chemical properties such as ion exchange capacity, dimensional stability, vanadium ion cross-over and membrane area resistance. Conclusively, TEA-functionalized membrane showed longest term stability than other membranes although all the membranes are similar to coulombic efficiency.