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Recent Progress on Adsorptive Removal of Cd(II), Hg(II), and Pb(II) Ions by Post-synthetically Modified Metal-organic Frameworks and Chemically Modified Activated Carbons

  • Rallapalli, Phani Brahma Somayajulu;Choi, Suk Soon;Ha, Jeong Hyub
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.133-144
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    • 2022
  • Fast-paced industrial and agricultural development generates large quantities of hazardous heavy metals (HMs), which are extremely damaging to individuals and the environment. Research in both academia and industry has been spurred by the need for HMs to be removed from water bodies. Advanced materials are being developed to replace existing water purification technologies or to introduce cutting-edge solutions that solve challenges such as cost efficacy, easy production, diverse metal removal, and regenerability. Water treatment industries are increasingly interested in activated carbon because of its high adsorption capacity for HMs adsorption. Furthermore, because of its huge surface area, abundant functional groups on surface, and optimal pore diameter, the modified activated carbon has the potential to be used as an efficient adsorbent. Metal-organic frameworks (MOFs), a novel organic-inorganic hybrid porous materials, sparked an interest in the elimination of HMs via adsorption. This is due to the their highly porous nature, large surface area, abundance of exposed adsorptive sites, and post-synthetic modification (PSM) ability. This review introduces PSM methods for MOFs, chemical modification of activated carbons (ACs), and current advancements in the elimination of Pb2+, Hg2+, and Cd2+ ions from water using modified MOFs and ACs via adsorption.

The Overland and Maritime Silk Routes in the Post-Mongol World

  • Joo-Yup LEE
    • Acta Via Serica
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    • v.8 no.2
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    • pp.155-174
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    • 2023
  • Trade along the Silk Routes reached its zenith during the Pax Mongolica, a period of relative stability in Eurasia that was created by the Mongol empire in the 13th and 14th centuries. It is generally believed that the Silk Routes declined after the disintegration of the Mongol empire in the second half of the 14th century and that they fell into disuse after the 1453 Ottoman conquest of Constantinople as the Europeans sought alternative maritime routes to Asia. This paper examines the aftermath of the Mongol-era overland and maritime Silk Routes from a non-Eurocentric perspective. Seen from the standpoint of various successors to the Mongol empire, such as the Timurid empire, the Mughal empire, the Uzbek khanate, the Ottoman empire, Manchu Qing, and Russia, the overland and maritime Silk Routes did not really collapse or sharply decline during the post-Mongol period. These Mongol successor states maintained close and thriving overland trade relations with each other or some important maritime trade relations with Southeast Asia. It may be argued that the Silk Routes in the post-Mongol world functioned rather independently of European seaborne commerce.

Effects of Isoflurane Anesthesia on Post-Anesthetic Sleep-Wake Architectures in Rats

  • Jang, Hwan-Soo;Jung, Ji-Young;Jang, Kwang-Ho;Lee, Maan-Gee
    • The Korean Journal of Physiology and Pharmacology
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    • v.14 no.5
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    • pp.291-297
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    • 2010
  • The sleep homeostatic response significantly affects the state of anesthesia. In addition, sleep recovery may occur during anesthesia, either via a natural sleep-like process to occur or via a direct restorative effect. Little is known about the effects of isoflurane anesthesia on sleep homeostasis. We investigated whether 1) isoflurane anesthesia could provide a sleep-like process, and 2) the depth of anesthesia could differently affect the post-anesthesia sleep response. Nine rats were treated for 2 hours with $ad$ $libitum$ sleep (Control), sleep deprivation (SD), and isoflurane anesthesia with delta-wave- predominant state (ISO-1) or burst suppression pattern-predominant state (ISO-2) with at least a 1-week interval. Electroencephalogram and electromyogram were recorded and sleep-wake architecture was evaluated for 4 hours after each treatment. In the post-treatment period, the duration of transition to slow-wave-sleep decreased but slow wave sleep (SWS) increased in the SD group, but no sleep stages were significantly changed in ISO-1 and ISO-2 groups compared to Control. Different levels of anesthesia did not significantly affect the post-anesthesia sleep responses, but the deep level of anesthesia significantly delayed the latency to sleep compared to Control. The present results indicate that a natural sleep-like process likely occurs during isoflurane anesthesia and that the post-anesthesia sleep response occurs irrespective to the level of anesthesia.

Enhancement of Thermoelectric Performance in Spark Plasma Sintered p-Type Bi0.5Sb1.5Te3.0 Compound via Hot Isostatic Pressing (HIP) Induced Reduction of Lattice Thermal Conductivity (열간등방가압 공정을 통한 P형 Bi0.5Sb1.5Te3.0 소결체의 격자 열전도도 감소 및 열전 특성 향상)

  • Soo-Ho Jung;Ye Jin Woo;Kyung Tae Kim;Seungki Jo
    • Journal of Powder Materials
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    • v.30 no.2
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    • pp.123-129
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    • 2023
  • High-temperature and high-pressure post-processing applied to sintered thermoelectric materials can create nanoscale defects, thereby enhancing their thermoelectric performance. Here, we investigate the effect of hot isostatic pressing (HIP) as a post-processing treatment on the thermoelectric properties of p-type Bi0.5Sb1.5Te3.0 compounds sintered via spark plasma sintering. The sample post-processed via HIP maintains its electronic transport properties despite the reduced microstructural texturing. Moreover, lattice thermal conductivity is significantly reduced owing to activated phonon scattering, which can be attributed to the nanoscale defects created during HIP, resulting in an ~18% increase in peak zT value, which reaches ~1.43 at 100℃. This study validates that HIP enhances the thermoelectric performance by controlling the thermal transport without having any detrimental effects on the electronic transport properties of thermoelectric materials.

IEEE 1500 Wrapper Design Technique for Pre/Post Bond Testing of TSV based 3D IC (TSV 기반 3D IC Pre/Post Bond 테스트를 위한 IEEE 1500 래퍼 설계기술)

  • Oh, Jungsub;Jung, Jihun;Park, Sungju
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.1
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    • pp.131-136
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    • 2013
  • TSV based 3D ICs have been widely developed with new problems at die and IC levels. It is imperative to test at post-bond as well as pre-bond to achieve high reliability and yield. This paper introduces a new testable design technique which not only test microscopic defects at TSV input/output contact at a die but also test interconnect defects at a stacked IC. IEEE 1500 wrapper cells are augmented and through at-speed tests for pre-bond die and post-bond IC, known-good-die and defect free 3D IC can be massively manufactured+.

Estrogen Attenuates the Pressor Response Mediated by the Group III Mechanoreflex (폐경전후 여성의 Group III 기계적 수용기 자극 시 운동승압반사의 비교)

  • Park, Seung-Ae;Kim, Jong-Kyung
    • Journal of Korean Academy of Nursing
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    • v.41 no.2
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    • pp.191-196
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    • 2011
  • Purpose: We investigated the effects of group III mechanoreceptors to cardiovascular responses in both pre-menopausal woman and post-menopausal woman during passive ankle dorsiflexion (PAD). Methods: Twenty healthy volunteers (10 post-menopausal women and 10 pre-menopausal women) were recruited for this study. Stroke volume (SV), heart rate (HR), cardiac output (CO), and total vascular conductances (TVC) were measured continuously throughout the experiment. To stimulate the group III mechanoreceptors, PAD was performed for one minute. Results: The results showed that mean arterial pressure (MAP) mediated by the mechanoreflex activation was significantly increased in both groups. However, this pressor response was significantly higher in post-menopausal women. This reflex significantly increased both SV and CO in pre-menopausal women, while there were no differences in post-menopausal women. There was no difference in HR in either group. The mechanoreflex significantly decreased TVC in post-menopausal woman, while there was no difference in pre-menopausal woman. Conclusion: The results indicate that the excessive pressor response mediated by the mechanoreflex occurs due to overactivity of group III mechanorecptors and the mechanism is produced mainly via peripheral vasoconstriction in post-menopausal women.

Post-buckling analysis of geometrically imperfect nanoparticle reinforced annular sector plates under radial compression

  • Mirjavadi, Seyed Sajad;Forsat, Masoud;Mollaee, Saeed;Barati, Mohammad Reza;Afshari, Behzad Mohasel;Hamouda, A.M.S.
    • Computers and Concrete
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    • v.26 no.1
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    • pp.21-30
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    • 2020
  • Buckling and post-buckling behaviors of geometrically imperfect annular sector plates made from nanoparticle reinforced composites have been investigated. Two types of nanoparticles are considered including graphene oxide powders (GOPs) and silicone oxide (SiO2). Nanoparticles are considered to have uniform and functionally graded distributions within the matrix and the material properties are derived using Halpin-Tsai procedure. Annular sector plate is formulated based upon thin shell theory considering geometric nonlinearity and imperfectness. After solving the governing equations via Galerkin's technique, it is showed that the post-buckling curves of annular sector plates rely on the geometric imperfection, nanoparticle type, amount of nanoparticles, sector inner/outer radius and sector open angle.

Maternal Body-mass Transfer to Offspring in the Matriphagous Spider, Amaurobius ferox (Amaurobiidae)

  • Kim, Kil-Won
    • Journal of Ecology and Environment
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    • v.32 no.3
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    • pp.177-182
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    • 2009
  • The optimal strategy for semelparous females may involve adjustments in the relative investment in two fitness components, the number of offspring and the post-hatching investment per capita. To determine the pattern of maternal resource allocation to offspring in the matriphagous spider, Amaurobius ferox (Amaurobiidae), I investigated the relationship between maternal body-mass and the number of offspring, and quantified the transfer of maternal body-mass to the offspring via different forms of maternal provisioning (trophic egg-laying and matriphagy). There was a positive relationship between female body-mass and the number of offspring. However, Amaurobius mothers did not produce more trophic eggs when they had larger broods. Rather, spiderlings in larger A. ferox broods consumed larger quantities of maternal body-mass via matriphagy. Mothers transferred $28.8{\pm}6.5%$ of their body-mass to the spiderlings via trophic egg-laying, and an estimated $39.0{\pm}12.5%$ of their body-mass was transferred to the spiderlings via matriphagy.

Botulinum toxin-A injection into the anterior belly of the digastric muscle for the prevention of post-operative open bite in class II malocclusions: a case report and literature review

  • Kang, Yei-Jin;Cha, Bong Kuen;Choi, Dong Soon;Jang, In San;Kim, Seong-Gon
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.41
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    • pp.17.1-17.5
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    • 2019
  • Background: Class II malocclusion patients with hyperdivergent facial types are characterized by short mandibular body lengths and anterior open bite. Accordingly, the treatment for hyperdivergent skeletal class II malocclusion is a lengthening of the mandibular body length and a counterclockwise rotation of the mandible. To prevent post-operative relapse, botulinum toxin-A (BTX-A) injection can be a retention modality. Case presentation: A class II open-bite patient received BTX-A injection to the anterior belly of her digastric muscle for the prevention of post-operative relapse. The relapse was evaluated via a clinical examination and a lateral cephalometric radiograph after the completion of post-surgical orthodontic treatment. The patient showed stable occlusion without any signs of relapse at 15 months post-operatively. Conclusion: In this case presentation, a single injection into the anterior belly of the digastric muscle was sufficient for the prevention of post-operative open bite.

Evaluation of Provider Skills in Performing Visual Inspection with Acetic Acid in the Cervical Cancer Screening Program in the Meknes-Tafilalet Region of Morocco

  • Selmouni, Farida;Sauvaget, Catherine;Zidouh, Ahmed;Plaza, Consuelo Alvarez;Muwonge, Richard;Rhazi, Karima El;Basu, Partha;Sankaranarayanan, Rengaswamy
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.9
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    • pp.4313-4318
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    • 2016
  • Background: This study documented the performance of providers of visual inspection with acetic acid (VIA) at primary health centers, assessing their compliance with the VIA skills checklist and determinants of non-compliance, and exploring their perceptions of VIA training sessions. Materials and Methods: A cross-sectional study was conducted among VIA providers in the $Mekn\grave{e}s$-Tafilalet region of Morocco. Structured observation of their performance was conducted through supervisory visits and multiple focus group discussions (FGDs). Results: Performance of all the recommended steps for effective communication was observed in a low proportion of procedures (36.4%). Midwives/nurses had higher compliance than general practitioners (GPs) (p<0.001). All recommended steps for VIA examination were performed for a high proportion of procedures (82.5%). Compliance was higher among midwives/nurses than among GPs (p<0.001) and among providers in rural areas than those in urban areas (p<0.001). For pre-VIA counselling, all recommended steps were performed for only 36.8% of procedures. For post-VIA counseling, all recommended steps were performed in a high proportion (85.5% for VIA-negative and 85.1% for VIA-positive women). Midwives/nurses had higher compliance than GPs when advising VIA-positive women (p=0.009). All infection prevention practices were followed for only 14.2% of procedures, and compliance was higher among providers in rural areas than those in urban areas (p<0.001). Most FGD participants were satisfied with the content of VIA training sessions. However, they suggested periodic refresher training and supportive supervision. Conclusions: Quality assurance of a cervical cancer screening program is a key element to ensure that the providers perform VIA correctly and confidently.