• Title/Summary/Keyword: vapor SAM

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PHOTOCATALYTIC DEGRADATION OF 2-CHLOROPHENOL USING TiO₂THIN FILMS PREPARED BY CHEMICAL VAPOR DEPOSITION AND ION BEAM SPUTTERING METHOD

  • Jung, Oh-Jin;Kim, Sam-Hyeok;Jo, Ji-Eun;Hwang, Chul-Ho
    • Environmental Engineering Research
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    • v.7 no.4
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    • pp.227-237
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    • 2002
  • Chemical vapor deposition (CVD), ion beam sputtering (IBS) and sol-gel method were used to prepare TiO$_2$ thin films for degradation of hazardous organic compounds exemplified by 2-chlorophenol (2-CP). The influence of supporting materials and coating methods on the photocatalytic activity of the TiO$_2$ thin films were also studied. TiO$_2$ thin films were coated onto various supporting materials including steel cloth (SS), copper cloth, quartz glass tube (QGT), and silica gel (SG). Results indicate that SS (37 μm)- TiO$_2$ thin film prepared by IBS method improves the photodegradation of 2-CP. Among all supporting materials studied, SS(37 μm) is found to be the best support.

Effect of Fe Catalyst on Growth of Carbon Nanotubes by thermal CVD

  • Yoon, Seung-Il;Heo, Sung-Taek;Kim, Sam-Soo;Lee, Yang-Kyu;Lee, Dong-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.760-763
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    • 2007
  • The properties of carbon nanotube obtained by thermal chemical vapor deposition (CVD) process were investigated as a function of ammonia $(NH_3)$ gas in hydrocarbon gas, Fe catalyst thickness, and growth temperature. Fe catalyst was prepared by DC magnetron sputter and pre-treated with ammonia gas. CNTs were then grown with ammonia-acetylene gas mixture by thermal CVD. The diameter of these CNTs shows a strong correlation with the gas rate, the catalyst film thickness and temperature. From our results, it was found that the factors of grown CNTs positively acted to improve CNT quality.

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Decontamination of Interior of Field Tent Employed Geobacillus stearothermophilus Spores using a Hydrogen Peroxide Vapor System (과산화수소증기 시스템을 이용한 야전용 천막 내 Geobacillus stearothermophilus 아포 제독)

  • Yoon, Sung Nyo;Kim, Yun Ki;Jeung, Jeung Hoon;Yoo, Hyun Sang;Min, Kyung Yool;Kim, Min Cheol;Kim, Se Kye;Ryu, Sam Gon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.19 no.5
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    • pp.669-674
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    • 2016
  • The purpose of this study is to demonstrate the suitability of hydrogen peroxide($H_2O_2$) vapor system for platform interior decontamination. Geobacillus stearothermophilus biological indicator(BI) strips and a field tent were used as a biological simulant and as a simulated platform, respectively. Decontamination was performed based on injection rates and tent sizes with exposure time 60 minutes. We standardized the conditions for the field tent decontamination : 8.0 g/min for $30m^3$($H_2O_2$ vapor concentration of 150~500 ppm, relative humidity of 50 %) and 12.0 g/min for $60m^3$($H_2O_2$ vapor concentration of 250~400 ppm, relative humidity of 55 %). Thus we suggest the system is one of the possible candidates for decontamination of platform interiors.

Study on Poly(3,4-ethylenedioxythiophene) Thin Film Vapour Phase-Polymerized with Iron(III)Tosylate on AcOH-Catalyzed 3-Aminopropyltriethoxysilane Self-Assembled Monolayer

  • Choi, Sangil;Kim, Wondae;Kim, Sungsoo
    • Journal of Integrative Natural Science
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    • v.5 no.4
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    • pp.233-236
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    • 2012
  • In this study, PEDOT thin films polymerized with Iron(III)tosylate ($Fe(PTS)_3$) and grown on acetic acid-catalyzed 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM) surfaces by VPP method have been investigated. PEDOT thin films were synthesized on APS self-assembled $SiO_2$ wafer surface at two different concentrations (20 wt% and 40 wt%) and growth time (3 and 30 minutes), and then they were compared. PEDOT vapour phase-polymerized with 40 wt% $Fe(PTS)_3$ oxidant completely formed a thin film on acetic acid-catalyzed APS-SAM surface while with 20 wt% $Fe(PTS)_3$ did not at all. It means that the oxidant can be uniformly coated on acetic acid-catalyzed APS-SAM surface at the 40 wt% concentration, which gives rise to the uniform growth of PEDOT thin film on it.

Anti-corrosive surface treatment of Mg alloy steel using organic self assembly monolayer technique (유기 단분자막을 이용한 마그네슘 합금 판재 (AZ31)의 내식성 표면처리 기술 연구)

  • Park, Jong-Won;Lee, Gyeong-Hwang;Park, Yeong-Hui
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.113-114
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    • 2009
  • 기존의 습식 및 건식 표면처리 공정의 단점을 극복하고, 마그네슘 합금의 가장 큰 문제점인 내식성개선을 위해 열화학기상증착(thermal Chemical Vapor Deposition)법을 이용하여 자기조직화 유기 단분자막(Self-Assembled organic Monolayer, SAM)을 제작하여 마그네슘 합금(AZ31)의 내식성을 검토하였다.

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An Availability Assessment of Protection Wall Installed in LPG Filling Station (LPG 충전소 내 설치된 방호벽의 효용성 평가)

  • Lee, Jin-Han;Jo, Young-Do;Moon, Jong-Sam;Kim, Lae Hyun
    • Journal of the Korean Institute of Gas
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    • v.22 no.5
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    • pp.38-45
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    • 2018
  • Jet fire, pool fire, and vapor cloud explosion are major accident scenarios in LPG filling station. The protection wall would mitigate radiation effect in a jet fire. In case of a pool fire, the protection wall would restrict expanding the pool area. The protection wall might both obstruct the dispersion of released vapor and protect blast overpressure in a vapor cloud explosion scenario. In this paper, An availability assessment method of the protection wall how much reduce damage to receptors is proposed. Additionally application cases are presented for the effectiveness of protection wall in the LPG filling station. The study shows that the protection wall can effectively reduce the death probabilities of receptors located behind the wall in cases of the jet fires and the vapor cloud explosions.

Correlations Between Pore Structure of Activated Carbon and Adsorption Characteristics of Acetone Vapor (활성탄의 세공구조와 Acetone Vapor 흡착특성의 상관관계)

  • Lee, Song-Woo;Bae, Sang-Kyu;Kwon, Jun-Ho;Na, Young-Soo;An, Chang-Doeuk;Yoon, Young-Sam;Song, Seung-Koo
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.620-625
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    • 2005
  • This study is to investigate the correlation between pore structures of activated carbons and adsorption characteristics of acetone vapor using the dynamic adsorption method. The experimental results showed that the breakthrough time of ACT activated carbon made by Takeda was the longest, because ACT has more micropores below pore diametr $10{\AA}$ than the compared activated carbons. The equilibrium adsorption capacity had direct correlation to the breakthrough time. The relation between BET specific surface area and the equilibrium adsorption capacity was hard to say linear. Therefore, it was difficult to estimate the adsorption ability of activated carbons only by BET specific surface area. The correlation factor between the cumulative surface area and the equilibrium adsorption capacity decreased with enlarging the range of pore size, and there was the highest correlation factor in the range of below $10{\AA}$.

Synthesis and characterization of $SnO_2$ nanowires on Si substrates in a thermal chemical vapor deposition process (열화학기상증착법을 이용한 Si 기판 위의 $SnO_2$ 나노와이어 제작 및 물성평가)

  • Lee, Deuk-Hee;Park, Hyun-Kyu;Lee, Sam-Dong;Jeong, Soon-Wook;Kim, Sang-Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.91-94
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    • 2007
  • Single-crystalline $SnO_2$ nanowires were successfully grown on Si(001) substrates via vapor-liquid-solid mechanism in a thermal chemical vapor deposition. Large quantity of $SnO_2$ nanowires were synthesized at temperature ranges of $950{\sim}1000^{\circ}C$ in Ar atmosphere. It was found that the grown $SnO_2$ nanowires are of a tetragonal rutile structure and single crystalline by diffraction and transmission electron microscopy measurements. Broad emission located at about 600 m from the grown nanowires was clearly observed in room temperature photoluminescence measurements, indicating that the emission band originated from defect level transition into $SnO_2$ nanowires.

Two-phase Pressure Drop in Horizontal Rectangular Channel (수평 사각 채널에서의 상 압력 강하)

  • Lim, Tae-Woo;You, Sam-Sang;Kim, Hwan-Seong
    • Journal of Fisheries and Marine Sciences Education
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    • v.25 no.3
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    • pp.625-631
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    • 2013
  • Two-phase pressure drop experiments were performed during flow boiling to deionized water in a microchannel having a hydraulic diameter of $500{\mu}m$. Tests were made in the ranges of heat fluxes from 100 to $400kW/m^2$, vapor qualities from 0 to 0.2 and mass fluxes of 200, 400 and $600kg/m^2s$. The frictional pressure drop during flow boiling is predicted by using two models; the homogeneous model that assumes equal phase velocity and the separate flow model that allows a slip velocity between two phases. From the experimental results, it is found that the two phase multiplier decreases with an increase in mass flux. Measured data of pressure drop are compared to a few available correlations proposed for macroscale and mini/microscale. Among the separated flow models, the correlation model suggested by Lee and Garimella predicted the frictional pressure drop within MAE of 47.2%, which is better than other correlations.