• 제목/요약/키워드: urea method

검색결과 360건 처리시간 0.027초

A Method of Measuring Wood Failure Percentage of Wood Specimens Bonded with Melamine-Urea-Formaldehyde Resins Using I mage Analysis

  • KIM, Minseok;PARK, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • 제49권3호
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    • pp.274-282
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    • 2021
  • Transparent and colorless melamine-urea-formaldehyde (MUF) resins make it difficult to identify the area of wood failure percentage (WFP) in the fracture surface of bonded wood specimens. Therefore, in this study, we develop a method of measuring WFP after the adhesion strength measurement of MUF resins under shear stress. The fractured wood surface of b lock shear strength (BSS) specimens bonded with cold-setting MUF resins at three melamine contents (20%, 30%, and 40%) was marked black, and then, WFP was accurately measured via image analysis. WFP values measured using this method consistently increased with BSS as the melamine content increased, showing the reliability of this new method. The results suggested that this new method is useful and reliable for measuring the WFP of the fracture surface of wood specimens bonded with colorless adhesives such as urea-formaldehyde, MUF, and melamine-formaldehyde resins.

Urea 수용액의 배기가스 유동장내 분무 특성과 분무 균일도에 관한 연구 (A Study on the Characteristic and Droplet Uniformity of Spray Injection to Exhaust Gas Flow from Urea Solution Injector)

  • 오정모;차원심;김기범;이진하;이기형
    • 한국자동차공학회논문집
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    • 제19권3호
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    • pp.83-89
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    • 2011
  • Diesel engines can produce higher fuel efficiency and lower $CO_2$ emission, they are subject to ever more stringent emission regulation. However, there are two major emission concerns fo diesel engines like such as particulate matter (PM) and nitrogen oxides (NOx). Moreover, it is not easy to satisfy the regulations on the emission of NOx and PM, which are getting more strengthened. One of the solutions is to apply the new combustion concept using multistage injection such as HCCI and PCCI. The other solution is to apply after-treatment systems. For example, lean NOx trap catalyst, Urea-SCR and others have various advantages and disadvantages Especially, Urea-SCR system have advantages such as a high conversion efficiency and a wide operation conditions. Hence the key factor to implementation of Urea-SCR technology, good mixing of urea(Ammonia) and gas, reducing Ammonia slip. Urea mixer components are required to facilitate evaporation and mixing because the liquid state of urea poses significant barriers for evaporation, and the distance to mixer is the most critical that affect mixer performance. In this study, to find out the distance from injector to mixer and simulation factor, a laser diagnostics and high speed camera are used to analyze urea injector spray characteristics and to present a distribution of urea solution in transparent manifold In addition, Droplet Uniformity Index is calculated from the acquired images by using image processing method to clarify the distribution of spray.

A Simple Method for the Preparation of Highly Pure Conjugated Linoleic Acid(CLA) Synthesized from Safflower Seed Oil

  • Kim, Young R.;Lee, Young H.;Park, Kyung A.;Kim, Jeong O.;Ha, Yeong L.
    • Preventive Nutrition and Food Science
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    • 제5권1호
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    • pp.10-14
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    • 2000
  • A simple and rapid method was developed to prepare a large quantity of highly pure conjugated linoleic acid (CLA) chemically-synthesized from safflower seed oil (SSO). CLA-SSO(74.9% in purity) was synthesized from fresh SSO(79.9% of linoleic acid) by alkaline isomerization at 18$0^{\circ}C$. Urea(50g) and CLA-SSO (25g) were completely dissolved in ethanol (750ml) using a water bath(5$0^{\circ}C$) and followed by refluxing for 60 min. The resultant was cooled to room temperature and stored in a cold room (4$^{\circ}C$) for 24hrs. After removing the urea adduct by filtration, the filtrate was rotoevaporated under 4$0^{\circ}C$ and the residue was dissolved in hexane (200ml). The hexane extract was washed with distilled water (100ml$\times$3) and dried over sodium sulfate anhydrous. This urea treatment procedure was repeated three times. The purity of CLA recovered from the hexane extract was 95.0%. This method can be applied to prepare a large quantity of highly pure chemically-synthesized CLA (>0.5kg/a batch) from any plant oils containing high percentages (>70%) of linoleic acid.

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톱밥 및 요소의 투입이 감자 더뎅이병 병원균(Streptomyces scabiei) 및 감자 더뎅이병 이병도 지수에 미치는 영향 (Effects of Sawdust and Urea Application on Disease Severity and Streptomyces scabiei Pathogen Dynamics)

  • 백계령;이정태;지삼녀
    • 한국환경과학회지
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    • 제32권11호
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    • pp.777-788
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    • 2023
  • Potato common scab disease is caused by pathogens belonging to Streptomyces spp. and results in a serious yield loss worldwide. Despite decades of research aimed at disease management, a definitive control method remains undiscovered. This study aims to explore the correlation between the C/N ratio and urea application with potato common scab pathogen dynamics and disease severity. We applied sawdust with a high C/N ratio and urea into the soil prior to potato cropping, both in pot and field experiments. Disease severity assessments and quantification of the TxtB gene were conducted at the harvest stage. Furthermore, culture experiments were performed to assess the direct impact of urea on the pathogen. Our findings revealed that higher disease severity was correlated with a high C/N ratio application and pathogenic gene quantity. Urea exhibited a direct influence on S. scabiei activity, reducing the disease severity in pot experiments. However, the effects of urea application on disease suppression in the conductive field were inconclusive. Although the results of urea application experiments displayed inconsistencies between pot and field trials, urea worked as the control to suppress S. scabiei activity. Further investigations are needed under various field conditions to confirm these findings.

'Beni Balad' 포도 비가림 재배에서 부숙유기질비료 및 Urea 토양 시용에 의한 암모니아 배출량 및 과실 품질 (Effects of Composted Organic Fertilizer and Urea Application to Soil on the Ammonia Emissions and Fruit Quality of 'Beni Balad' Grapevine in Rain Proof Cultivation)

  • 문영지;문병우;김민욱
    • 한국환경농학회지
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    • 제40권4호
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    • pp.313-321
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    • 2021
  • 비가림 시설에서 'Beni Balad' 포도재배 시 부숙유기질비료 및 Urea를 토양 시용에 의한 암모니아 배출량 산정과 과실품질에 미치는 영향은 다음과 같다. Urea는 처리 1일째부터 암모니아 배출량이 급격히 증가하기 시작하여 15일째에 peak를 이루다가 점차 감소하였으며 그 이후에는 다른 처리와 큰 차이는 없었다. COF2 처리는 처리 후 1일째 peak를 보이다가 점차 감소하였으며, 그 이후는 대조구와 비슷한 발생량을 나타내었다. COF1 처리는 1일째 증가하여 완만한 곡선을 이루다가 15일째에 peak를 이루고 점차 감소하여 그 이후 대조구와 비슷하였다. 140일간 암모니아 누적 배출량은 대조구 2.63, Urea 12.95, COF1 2.05, COF2 3.97 kg NH3-N ha-1 day-1 이었다. 토양내 무기성분 함량이 COF2에서 암모니아태 질소는 유의하게 높았으며 수확시 엽병의 T-N 농도는 COF1 처리보다 COF2 처리가 0.1% 감소하였다. P와 K 농도는 COF1 처리로 인하여 증가하였으나 Ca와 Mg 농도는 차이가 없었다. 과실품질은 Urea 처리는 과피의 경도, 가용성 고형물 및 안토시아닌 함량은 증가하였고, COF1 처리는 가용성고형물 및 안토시아닌 함량은 증가하였으며, 산 함량은 전 처리 모두 증가하였다. 그러나 과중, 과방크기, Hunter L, a, b값에는 차이가 없었다. 이상의 결과는 포도나무 Beni Balad 품종에서 Urea, 부숙유기질비료의 토양 시용 시 암모니아 배출량 산정에 기초자료가 될 것으로 판단되었다.

Urea 혼입 매스콘크리트의 FEM 온도균열 해석을 위한 수화발열특성에 관한 실험적 연구 (An Experimental Study on Hydration Heat Characteristics for Thermal Crack Analysis Based on FEM of Urea Mixed Mass Concrete)

  • 문동환;장현오;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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    • pp.36-37
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    • 2019
  • In domestic construction industry progress, construction and quality control of large structures are considered to be important as the superstructure and mass scale of structures. In the case of mass concrete, high hydration heat caused by cement hydration generates temperature stress by generating internal temperature difference with the concrete surface. These temperature stresses cause cracks to penetrate the concrete structure. A method of lowering the heat generation by incorporating Urea in order to reduce the concrete temperature crack has been proposed. In this study, the heat function coefficient for the FEM temperature crack analysis of the mass concrete containing the element was derived and the adiabatic temperature rise test was carried out according to the incorporation of the element. As a result of this experiment, the maximum temperature of 41 ± 1℃ was obtained irrespective of the amount of urea, and the maximum temperature decreased by 16.9℃ in concrete containing 40kg/㎥ of urea.

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EHC 기반 Urea-SCR 시스템 히터 표면온도 분포의 1-D 모델링 (1-D Modeling of Heater Surface Temperature Distribution in EHC-based Urea-SCR System)

  • 박선홍;손지현;문석수;오광철;장성욱;박성서
    • 한국분무공학회지
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    • 제27권1호
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    • pp.11-17
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    • 2022
  • In upcoming Post Stage-V and Tier 5 regulations of construction machineries, nitrogen oxide (NOx) emissions are strictly limited in cold start conditions. In response to this, a method of improving NOx conversion efficiency has been applied by installing an electric heating catalyst (EHC) in front of conventional urea-SCR systems so that the evaporation and thermal decomposition of urea-water solution can be promoted in cold start conditions. In this strategy, the evaporation and thermal decomposition of urea-water solution and corresponding NOx conversion efficiency are governed by temperature conditions inside the EHC. Therefore, characterizing the temperature distribution in the EHC under various operating conditions is crucial for the optimized operation and control of the EHC in Urea-SCR systems. In this study, a 1-D modeling analysis was performed to predict the heater surface temperature distribution in EHC under various operating conditions. The reliability of prediction results was verified by comparing them with measurement results obtained using an infrared (IR) camera. Based on 1-D analysis results, the effects of various EHC operation parameters on the heater surface temperature distribution were analyzed and discussed.

우레아 첨가량 변화에 따라 수열합성법으로 제조 된 3mol%Y2O3-ZrO2 분말의 합성 및 기계적 특성 평가 (Hydrothermal Synthesis and Mechanical Characterization of 3mol%Y2O3-ZrO2 by Urea Contents)

  • 이학주;고명원;김택남
    • 한국재료학회지
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    • 제21권8호
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    • pp.425-431
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    • 2011
  • The industrial manufacturing of YSZ products can be summarized as a three step process: a) hydrolysis of zirconyl chloride and mixing of other solutions, b) precipitation, and c) calcination. The addition of ammonia or OH- is essential in the precipitation process. However, a strong agglomeration was observed in the results of an ammonia or OH- addition. Thus, it is necessary to disperse the powders smoothly in order to improve the mechanical strength of YSZ. In this study, YSZ was synthesized using the urea stabilizer and hydrothermal method. YSZ powders were synthesized using a hydrothermal method with Teflon Vessels at $180^{\circ}C$ for 24 h. The mole ratio of urea to Zr was 0, 0.5, 1, and 2. The crystal phase, particle size, and morphologies were analyzed. Rectangular specimens ($33\;mm{\times}8\;mm{\times}1{\pm}0.5\;mm$) for three-point bend tests were used in the mechanical properties evaluation. The crystalline of YSZ powders observed a tetragonal phase in the sample with a ratio of Zr:urea = 1:2 addition and a hydrothermal reaction time of 24 h. The average primary particle size of YSZ was measured to be 9 nm to 11 nm. The agglomerated particle size was measured from 15 nm to 30 nm. The three-point bending strength of the YSZ samples was 142.47 MPa, which is the highest value obtained for the Zr:urea = 1:2 ratio addition YSZ sample.

Synthesis and Luminescence Characterization of En3+ Doped Gd2O3 Phosphors by Combustion Method

  • Jeong, Young-Ho;Myung, Kwang-Shik;Kim, Jung-Duk;Han, Sang-Do;Park, Jin-Won;Singh, K.C.
    • Transactions on Electrical and Electronic Materials
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    • 제4권5호
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    • pp.28-32
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    • 2003
  • Europium-doped gadolinium oxide ($Gd_2O_3;Eu^{3+}$) phosphors have been prepared by combustion method using urea[H$_2$NCONH$_2$] or carbohydrazide[H$_2$NNHCONHNH$_2$] as fuel materials in a preheated furnace at 500$^{\circ}C$. The phosphors obtained were fired at 1200$^{\circ}C$ for 3 hours to get better luminescent properties. The combustion method used was found to be a simple and fast method for the preparation of fine-sized particles. The influence of the fuel/oxidant (urea or carbohydrazide/nitrate) mole ratio on the phosphor has been investigated and the optimum values for various parameters have been determined. By this method, phosphor that has better brightness and smaller size particles than that obtained by conventional method has been prepared.d has been prepared.

디젤엔진의 Urea-SCR 시스템에 의한 NH3/NOx 비율 및 촉매 방식이 NOx 저감에 미치는 영향에 관한 융합연구 (A Convergence Study on the Effects of NH3/NOx Ratio and Catalyst Type on the NOx Reduction by Urea-SCR System of Diesel Engine)

  • 윤흥수;류연승
    • 한국융합학회논문지
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    • 제10권4호
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    • pp.131-138
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    • 2019
  • 디젤엔진은 열효율이 높고 연비가 좋으며 CO, HC 및 $CO_2$의 배출량이 낮은 등 가솔린 엔진보다 상당한 장점이 있다. 그러나 디젤엔진은 배기가스 중에 $O_2$ 농도가 높기 때문에 NOx 저감이 어렵고, 삼원촉매를 적용하기 어렵다. Urea-SCR과 LNT는 디젤엔진에서 NOx를 연속적으로 저감하는데 활용 가능한 두 기술이다. 디자인 엔진에 Urea-SCR 시스템을 구현함으로써 2.5l 이상 엔진에서 Euro-6의 강화된 NOx 기준을 충족시킬 수 있게 되었다. 본 연구에서는 엔진 회전속도, 부하, 촉매 방식 및 $NH_3$/NOx 비율에 따른 NOx 저감 특성을 연구하여 NOx 저감을 극대화하는 조건을 제시하고자 한다. 또한 Euro-6 이상의 규제에 대응할 수 있도록 Urea-SCR에 대한 정밀한 실험 데이터를 제공하고자 한다.