• Journal of Korean Society of Environmental Engineers
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• v.33 no.2
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• pp.137-142
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• 2011

This study was conducted to establish the optimal electrolyte and bismuth concentrations using bismuth film electrode in laboratory and to confirm the possibilities of using this operational condition for heavy metals monitoring in field. In lab test, heavy metal measurement was not accurate more than 600 ppb when heavy metal (Pb, Cd, Zn) range 100~1,000 ppb was measured with bismuth 2,000 ppb. So, bismuth and heavy metal was reacted about 1:1 with ASV method. In electrolyte test, 0.1 M acetate buffer (pH 4.5), 0.1 M chloroacetate buffer (pH 2.0), 0.1 M HCl (pH 2.0), 0.1 M $HNO_3$ (pH 2.0) was tested. As a results, 0.1 M acetate buffer was most suitable in ASV measurement with bismuth film electrode. In field application, Pb, Cd and Zn was measured respectively 36~45 ppb, 84~91 ppb, 90~98 ppb when heavy metal (Pb, Cd, Zn) 100 ppb was spiked in field sample. These results were identified of matrix effect in field sample, So relationship between heavy metal measurement and matrix effects will be studied.

• The Journal of Engineering Geology
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• v.23 no.3
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• pp.283-292
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• 2013

A calcareous rock slope failed during excavation of the slope for construction of a tunnel entrance. The slope is located at the construction site for widening highway in Yeongwol, Korea. Field surveys, laboratory tests, and numerical analyses were performed to determine the reason for the slope failure. The numerical analysis revealed that the safety factor of the slope before construction of the entrance was less than 1, and that this decreased after construction. After construction of the entrance, the sliding zone of the slope increased and slope stability decreased because the shear strain and plastic zone in the slope over the tunnel entrance showed an increase relative to the lower part of the slope. To enhance the stability of the slope for construction of the tunnel entrance, countermeasures such as rock bolts, rock anchors, and FRP (Fiber glass Reinforced Plastic) grouting were adopted in light of the field conditions. Serial field monitoring performed to confirm the reinforcing effects of the adopted countermeasures revealed a small amount of horizontal deformation of the slope soils, most of the elastic deformation that can regain its former value. In addition, the axial forces of the rock bolt and anchor were more strongly affected by slope excavation during construction of the tunnel entrance than by tunnel excavation or the rainy season, and the axial forces tended to converge after excavation of the tunnel. Therefore, we can confirm that the slope is currently safe.

• Fire Science and Engineering
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• v.31 no.2
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• pp.29-36
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• 2017

The design fire based on the heat release rate (HRR) of combustibles can significantly affect the assessment of fire safety in the performance-based design (PBD). In the present PBD, however, limited information in the foreign literature has been used without further verification due to the lack of fire information in domestic combustibles. The objective of this study is to provide information on the HRR and fire growth rate for various combustibles in residential and office spaces. To end this, the fire experiments were carried out with single and multiple combustibles. The peak HRR of combustibles used in the present study had a range of 36 kW~1,092 kW. The fire growth rates were also $0.003kW/s^2{\sim}0.0287kW/s^2$ and $0.003kW/s^2{\sim}0.0838kW/s^2$ for the residential and office spaces, respectively. In particular, a sofa had the highest fire risk in terms of the peak HRR and fire growth rate. Finally, a methodology for calculating the peak HRR in a space was proposed through correlation analysis between the peak HRR and exposed surface of various combustibles.

• Tunnel and Underground Space
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• v.30 no.4
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• pp.271-305
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• 2020

An effect of coupled thermo-hydro-mechanical and chemical (THMC) behavior is an essential part of the performance and safety assessment of geological disposal systems for high-level radioactive waste and spent nuclear fuel. Furthermore, numerical models and modeling techniques are necessary to analyze and predict the coupled THMC behavior in the disposal systems. However, phenomena associated with the coupled THMC behavior are nonlinear, and the constitutive relationships between them are not well known. Therefore, it is challenging to develop numerical models and modeling techniques to analyze and predict the coupled THMC behavior in the geological disposal systems. It is also difficult to verify and validate the development of the models and techniques because it requires expensive laboratory tests and in-situ experiments that need to be performed for a long time. DECOVALEX was initiated in 1992 to efficiently develop numerical models and modeling techniques and validate the developed models and techniques against the lab and in-situ experiments. In Korea, Korea Atomic Energy Research Institute has participated in DECOVALEX-2011, DECOVALEX-2015, and DECOVALEX-2019 since 2008. In this study, all tasks in the three DECOVALEX projects were introduced to the researcher in the field of rock mechanics and geotechnical engineering in Korea.

• Journal of Korea Water Resources Association
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• v.51 no.9
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• pp.795-802
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• 2018

This study investigates the hydraulic characteristics and the delta development processes in the improved-pneumatic-movable weir by considering the standing angle of the weir through laboratory experiments. The delta migration speed decreases rapidly with time. As the ratio of delta height to water depth increases, the dimensionless delta migration speed decreases at the delta point. Therefore, the water depth decreases as the delta height increases. Although the delta volume is large due to the effective height of the delta, the delta migration speed and sediment deposition decreases because of the backwater effect on the delta. On the same bed slope condition, the larger the weir height, the larger the delta volume and the ratio of delta height to delta front length is close to 1.0. The delta development could be suppressed when the weir is high. Therefore, the condition that the weir is high has the suppressing effect on the delta developments.

• Journal of Korea Water Resources Association
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• v.53 no.11
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• pp.951-960
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• 2020

This study investigates the adjustment processes of the rivers after weir removal through laboratory experiments. Delta upstream eroded rapidly by flow at the initial stage of the experiments and the knickpoint migrates upward. Moreover, the knickpoint moves fast upward on the condition of alternate bars. The head cutting in the bed is developed fast at the initial stage. However, the erosion speed in the bed decreases with time. The well developed alternate bars migrates with keeping their shape downstream, and the bars affect the channel downstream to adjust new environments after weir removal. Maximum scouring depth downstream and the migration speed decrease over time after removing the weir. The scouring depth in the channel without alternate bars migrates with speed. However, the depth in the channel with alternate bars migrates slow downstream. The channel with alternate bars, in turn, is adjusted well to the new equilibrium states. The maximum scouring depth migrates downstream with time, and the scouring depth and its migration speed decreases with time. The dimensionless maximum scouring depth decreases with the migration speed of dimensionless maximum scouring depth because the deeply scoured places capture the sediments from upstream and the migration speed is slow as the places are filled with them. The dimensionless maximum scouring depth is shallow as the dimensionless backfilling speed is high. The dimensionless maximum scouring depth decreases rapidly less than 5 of dimensionless backfilling speed. However, the depth decreases slow more than 5 of it.

• The Korean Journal of Pesticide Science
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• v.7 no.3
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• pp.182-187
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• 2003

In order to elucidate a degradation characteristics of herbicide mefenacet in soil, the persistence in soils was studied under laboratory conditions for $90\sim120$ days at $28^{\circ}C$. Mefenacet residues were determined from the two soils which pre-treated by sterilization and flooding, respectively. Non-sterilized upland soil was used as a control. When 70 days elapsed from application time, $55\sim63%$ of mefenacet applied were dissipated in control soils. However, $32\sim33%$ of mefenacet applied were dissipated in the sterilized soils and $33\sim35%$ was dissipated in the flooded soils. 까 lese results indicated that the degradation of mefenacet was assumed to be due to microorganism, especially aerobic microbes. In order to elucidate the influence of water content on the persistence of mefenacet in soil, water content in soils was adjusted to 20, 50, and 80% of the water-holding capacity(Field capacity, WHC). The half-life of mefenacet in soil containing 20% and 50% of WHC were 82 and 73 days, respectively, after incubation for 90 days. However, the half-life in soil containing 80% of WHC was shortened to 61 days. These results indicated that degradation of mefenacet in soil was influenced by the activity of soil microorganism, organic matter content and water content.

• Journal of Life Science
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• v.28 no.11
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• pp.1379-1385
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• 2018

Glycans are attached to proteins as in glycoproteins and proteoglycans. They are found on the exterior surface of cells. O- and N-linked glycans are very common in eukaryotic cells but may also be found in prokaryotes. The interaction of cell surface glycans with complementary glycan binding proteins located on neighboring cells, other cell types, pathogens like virus, or bacteria is crucial in biologically and biomedically important processes like pathogen recognition, cell migration, cell-cell adhesion, development, and infection. Their implication in pathological condition, suggests an important role for glycans as disease markers. In addition, a great amount of research has been shown that appropriate glycosylation of a recombinant therapeutic protein is critical for product solubility, stability, pharmacokinetics and pharmacodynamics, bioactivity, and safety. Besides, cancer-associated glycosylation changes often involve sialic acid in glycan branch which play important roles in cell-cell interaction, recognition and immunological response. This review aims at giving a comprehensive overview of the glycan's biological function and describing the relevance among the glycosylation, disease diagnosis and treatment methods. Furthermore, the high-throughput analytic methods available to measure the profile changing patterns of glycan in the blood serum as well as possible underlying biochemical mechanisms.

• Journal of Korean Tunnelling and Underground Space Association
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• v.26 no.3
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• pp.191-208
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• 2024

In this study, a hydro-mechanical-damage coupled analysis model was developed to evaluate the structural safety of radioactive waste disposal structures. The Mazars damage model, widely used to model the fracture behavior of brittle materials such as rocks or concrete, was coupled with conventional hydro-mechanical analysis and the developed model was verified via theoretical solutions from literature. To derive the numerical input values for damage-coupled analysis, uniaxial compressive strength and Brazilian tensile strength tests were performed on concrete samples made using the mix ratio of the disposal concrete silo cured under dry and saturated conditions. The input factors derived from the laboratory-scale experiments were applied to a two-dimensional finite element model of the concrete silos at the Wolseong Nuclear Environmental Management Center in Gyeongju and numerical analysis was conducted to analyze the effects of damage consideration, analysis technique, and waste loading conditions. The hydro-mechanical-damage coupled model developed in this study will be applied to the long-term behavior and stability analysis of deep geological repositories for high-level radioactive waste disposal.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.4
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• pp.377-392
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• 2017

A set of BFM (Brute Force Method) simulations with the CMAQ (Community Multiscale Air Quality) model were conducted in order to estimate self-contributions and conversion rates of PPM (Primary $PM_{2.5}$), $NO_x$, $SO_2$, $NH_3$, and VOC emissions to $PM_{2.5}$ concentrations over the SMA (Seoul Metropolitan Area). CAPSS (Clean Air Policy Support System) 2013 EI (emissions inventory) from the NIER (National Institute of Environmental Research) was used for the base and sensitivity simulations. SCCs (Source Classification Codes) in the EI were utilized to group the emissions into area, mobile, and point source categories. PPM and $PM_{2.5}$ precursor emissions from each source category were reduced by 50%. In turn, air quality was simulated with CMAQ during January, April, July, and October in 2014 for the BFM runs. In this study, seasonal variations of SMA $PM_{2.5}$ self-sensitivities to PPM, $SO_2$, and $NH_3$ emissions can be observed even when the seasonal emission rates are almost identical. For example, when the mobile PPM emissions from the SMA were 634 TPM (Tons Per Month) and 603 TPM in January and July, self-contributions of the emissions to monthly mean $PM_{2.5}$ were $2.7{\mu}g/m^3$ and $1.3{\mu}g/m^3$ for the months, respectively. Similarly, while $NH_3$ emissions from area sources were 4,169 TPM and 3,951 TPM in January and July, the self-contributions to monthly mean $PM_{2.5}$ for the months were $2.0{\mu}g/m^3$ and $4.4{\mu}g/m^3$, respectively. Meanwhile, emission-to-$PM_{2.5}$ conversion rates of precursors vary among source categories. For instance, the annual mean conversion rates of the SMA mobile, area, and point sources were 19.3, 10.8, and $6.6{\mu}g/m^3/10^6TPY$ for $SO_2$ emissions while those rates for PPM emissions were 268.6, 207.7, and 181.5 (${\mu}g/m^3/10^6TPY$), respectively, over the region. The results demonstrate that SMA $PM_{2.5}$ responses to the same amount of reduction in precursor emissions differ for source categories and in time (e.g. seasons), which is important when the cost-benefit analysis is conducted during air quality improvement planning. On the other hand, annual mean $PM_{2.5}$ sensitivities to the SMA $NO_x$ emissions remains still negative even after a 50% reduction in emission category which implies that more aggressive $NO_x$ reductions are required for the SMA to overcome '$NO_x$ disbenefit' under the base condition.