• Title/Summary/Keyword: unique solution

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Characteristics of PEGylated Polydiacetylene Liposome and its Inclusion Complex Formation with α-Cyclodextrin

  • Choi, Hye;Choi, Joon Sig
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3083-3087
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    • 2013
  • Diacetylene lipid monomers possess the capability to self-assemble into vesicles via polymerization under ultraviolet irradiation, resulting in the formation of polydiacetylene (PDA) liposomes. Exposure of the polymerized vesicles to external stimuli is known to induce a unique blue-to-red color transition. The cyclic oligosaccharide ${\alpha}$-cyclodextrin known for its use in many applications, such as drug delivery, purification, and stimulus sensing, is able to form an inclusion complex with poly(ethylene glycol) (PEG) in aqueous solution. In this study, we prepared polymeric liposomes with PEG (PEG-PDA) with the aim of improving the stability of the vesicles and colorimetric response toward ${\alpha}$-cyclodextrin. We demonstrated that PEG-PDA liposome displays unique characteristics compared with native PDA liposome and it also shows apparent chromic properties of the inclusion complex formation with ${\alpha}$-cyclodextrin.

On Routing Protocol and Metric for Multiradio Multichannel WMNs: Survey and Design Considerations (Multiradio Multichannel WMNs의 라우팅 프로토콜 및 메트릭: 연구 및 설계 고려 사항)

  • Gao, Hui;Lee, Hyung-Ok;Nam, Ji-Seung
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2012.01a
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    • pp.105-108
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    • 2012
  • Wireless mesh networks are considered a promising solution to last mile broadband. The unique characteristics of WMN impose unique requirements on designing routing protocols and metrics for WMN. However, existing routing schemes that are designed for single-channel multi-hop wireless networks may lead to inefficient routing paths in multichannel. This paper focuses on the routing problem for multi-radio multichannel WMNs. We list the challenges in designing routing algorithms for multi-radio multichannel WMNs. Then we examine the requirements and considerations for designing routing metrics according to the characteristics of multi-radio multichannel WMNs. Finally we survey and investigate the existing routing metrics in terms of their ability to satisfy these requirements.

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A Study on Formation Characteristics of Townscape in Korean Slow City (국내 슬로시티의 경관 형성 특성에 관한 연구)

  • Moon, Sun-Wook
    • Journal of the Korean Institute of Rural Architecture
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    • v.13 no.3
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    • pp.11-20
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    • 2011
  • The present age demands a change in attitude based on a differentiated life value from city. It will provide to a fundamental solution for the gap of living level in the farming and fishing communities and recreate distinguishing comfortable communities. The purpose of this study was to deduct the formation characteristics of the townscape of Korean slow city according to analyze resources and structure of landscape. Planning of slow city's townscape is a process of imagification of filtrate unique meaning. The glob share synchronic unique values by slow city's network. Therefore instead of putting emphasis on promoting tourist business for short-term revenue, it will be under control to raise the standard of living and to be not forfeited and diluted the rights for sustainable slow city's status. Participation of resident needs in this process. Accordingly it need a strategy of landscape formation design and a interdepartmental practice system for a continuous slow city's image by renewal of disharmonious townscape in the built-up area.

Adsorption Properties of Keggin-type Polyoxometalates on Carbon Based Electrode Surfaces and Their Electrocatalytic Activities

  • Choi, Su-Hee;Kim, Jong-Won
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.810-816
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    • 2009
  • The interactions between four Keggin-type POMs (${SiW_{12}O_{40}}^{4-},\;{PW_{12}O_{40}}^{3-},\;{SiMo_{12}O_{40}}^{4-},\;and\;{PMo_{12}O_{40}}^{3-}$) and glassy carbon (GC) and highly oriented pyrolytic graphite (HOPG) surfaces are investigated in a systematic way. Electrochemical results show that molibdate series POMs adsorb relatively stronger than tungstate POMs on GC and HOPG surfaces. Adsorption of POMs on HOPG electrode surfaces is relatively stronger than on GC surfaces. ${SiMo_{12}O_{40}}^{4-}$ species exhibits unique adsorption behaviors on HOPG surfaces. Surface-confined ${SiMo_{12}O_{40}}^{4-}$ species on HOPG surfaces exhibit unique adsorption behaviors and inhibit the electron transfer from the solution phase species. The catalytic activity of the surface-confined POMs for hydrogen peroxide electroreduction is also examined, where ${PW_{12}O_{40}}^{3-}$ species adsorbed on GC surfaces exhibits the highest catalytic efficiency among the investigated POM modified electrode systems.

Privacy Inferences and Performance Analysis of Open Source IPS/IDS to Secure IoT-Based WBAN

  • Amjad, Ali;Maruf, Pasha;Rabbiah, Zaheer;Faiz, Jillani;Urooj, Pasha
    • International Journal of Computer Science & Network Security
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    • v.22 no.12
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    • pp.1-12
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    • 2022
  • Besides unexpected growth perceived by IoT's, the variety and volume of threats have increased tremendously, making it a necessity to introduce intrusion detections systems for prevention and detection of such threats. But Intrusion Detection and Prevention System (IDPS) inside the IoT network yet introduces some unique challenges due to their unique characteristics, such as privacy inference, performance, and detection rate and their frequency in the dynamic networks. Our research is focused on the privacy inferences of existing intrusion prevention and detection system approaches. We also tackle the problem of providing unified a solution to implement the open-source IDPS in the IoT architecture for assessing the performance of IDS by calculating; usage consumption and detection rate. The proposed scheme is considered to help implement the human health monitoring system in IoT networks

APPLICATION OF NEW CONTRACTIVE CONDITION IN INTEGRAL EQUATION

  • Amrish Handa;Dinesh Verma
    • The Pure and Applied Mathematics
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    • v.31 no.1
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    • pp.83-102
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    • 2024
  • In this paper, first we establish a unique common fixed point theorem satisfying new contractive condition on partially ordered non-Archimedean fuzzy metric spaces and give an example to support our result. By using the result established in the first section of the manuscript, we formulate a unique common coupled fixed point theorem and also give an example to validate our result. In the end, we study the existence of solution of integral equation to verify our hypothesis. These results generalize, improve and fuzzify several well-known results in the existing literature.

Non-blinking dendritic crystals from C-dot solution

  • Mewada, Ashmi;Vishwakarma, Ritesh;Patil, Bhushan;Phadke, Chinmay;Kalita, Golap;Sharon, Maheshwar;Sharon, Madhuri
    • Carbon letters
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    • v.16 no.3
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    • pp.211-214
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    • 2015
  • Bio-imaging and drug carriers for delivery have created a huge demand for crystals. Crystals are fascinating materials that have been grown for a long time but obtaining biocompatible fluorescent crystals is a challenging task. We report on the growth of fluorescent crystals using a carbon dot (C-dot) solution by a hydrothermal process. The crystallization pattern of these C-dots exhibited a unique dendritic structure having a feather-like morphology. The growth temperature and pressure were maintained at 60℃ and 200 mmHg, respectively, for crystal growth. A green fluorescence (under UV light) that was observed in the C-dot solution was retained in the crystals formed from the solution. Cytotoxicity studies on Vero cells revealed the crystals to be extremely biocompatible. These fluorescent crystals are extremely well suited for biomedical and optoelectronic applications.

Determination of the Frumkin and Temkin Adsorption Isotherms of Hydrogen at Nickel/Acidic and Alkaline Aqueous Solution Interfaces Using the Phase-Shift Method and Correlation Constants

  • Chun, Jang-H.
    • Journal of the Korean Electrochemical Society
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    • v.15 no.1
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    • pp.54-66
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    • 2012
  • The phase-shift method and correlation constants, which are unique electrochemical impedance spectroscopy techniques for studying the linear relationship between the phase shift ($90^{\circ}{\geq}-{\varphi}{\geq}0^{\circ}$) vs. potential (E) behavior for the optimum intermediate frequency ($f_o$) and the fractional surface coverage ($0{\leq}{\theta}{\leq}1$) vs. E behavior, are proposed and verified to determine the Frumkin, Langmuir, and Temkin adsorption isotherms and the related electrode kinetic and thermodynamic parameters. At Ni/0.5 M $H_2SO_4$ and 0.1M LiOH aqueous solution interfaces, the Frumkin and Temkin adsorption isotherms (${\theta}$ vs. E) of H for the cathodic hydrogen ($H_2$) evolution, interaction parameters (g), equilibrium constants (K), standard Gibbs energies (${\Delta}G^0_{\theta}$) of H adsorption, and rates of change (r) of ${\Delta}G^0_{\theta}$ with ${\theta}$ have been determined using the phase-shift method and correlation constants. A lateral repulsive interaction (g>0) between the adsorbed H species appears. The value of K in the alkaline aqueous solution is much greater than that in the acidic aqueous solution.

A Study on the Molecular Changes of Tungstophosphate Species at Different pH Values using Spectroscopy (pH 변화에 따른 Tungstophosphates 화합물의 분자형태 변화에 대한 분광학적 연구)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.284-289
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    • 2011
  • All spectroscopic methods used in this work indicate the instability of tungstophosphates in aqueous solutions and considerable dependence on pH with regard to the dominant species present in the solution. UV spectroscopy indicates that some changes occur in the system but they cannot be specified. IR spectroscopy gives more information on the identification of the dominant species as a function the pH of the solution. NMR spectroscopy provides unique data, which can be used for more accurate interpretation of changes in the solution of various pH values. In the case of aqueous solutions of tungstophosphates, the parent anion was present only in a very acidic solution of ca. pH 1. Some differences in interpretation of the molecular species present under various experimental conditions can be ascribed to some extent to the diversity of chemical shifts of NMR. Under physiological conditions attained with the addition of NaOH, tungstophosphates was dominantly present in the form of the lacunary monovacant anion.

On the Design of Novel Hybrid Wave Generator (신형식 다기능 조파기 설계)

  • Kim, Hyochul;Oh, Jungkeun
    • Journal of the Society of Naval Architects of Korea
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    • v.58 no.2
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    • pp.112-120
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    • 2021
  • The novel wave generating system of a wave flume has been devised by utilizing the analytic solution of wave board motion in idealized two dimensional space. The arbitrary oscillation motion of submerged wave board segment has been defined by sinusoidal motion of upper and lower end of the wave board. The analytic solution of the wave board motion has been represented by the solution of board motion due to flap motion and swing motion. Arbitrary oscillation of the board could be specified by determining amplitude, frequency, and the phase lag. A novel hybrid wave generator could be operated not only in piston motion but also in flap or swing motion by selection of control parameter. The wave generator has unique motion enhancing ability by appending flap motion or swing motion to piston motion in wave generation. In addition the hybrid wave generator has advantages in generating high quality wave spectrum of irregular wave in simulating real sea condition.