• 공업화학
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• 제25권4호
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• pp.425-429
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• 2014

호기성 벤질 알코올 산화반응용 상용촉매 개발을 위하여 팔라듐이 담지된 차콜 입자를 제조하였다. 특히 촉매의 팔라듐 분산도를 높이기 위해서 상온 이온성액체 중 하나인 [Hmim][$PF_6$]을 기능성 용매로 사용하여 입자를 합성하였다. 다양한 농도의 팔라듐을 함침하여 제조된 입자의 반응성을 측정한 결과 7.5 wt%의 촉매가 가장 우수한 반응 활성과 안정성을 나타내었다. 또한 조촉매로서 다양한 농도의 은입자를 합침하여 촉매를 제조하였다. 동일한 반응조건에서 팔라듐과 은의 질량 비율이 9 : 1인 촉매가 높은 금속 분산도로 인하여 가장 반응성이 우수하였다.

• 한국주조공학회지
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• 제13권6호
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• pp.524-531
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• 1993

Dispersion behaviors of SiC particles and microstructures in Al-2%Si/SiCp composite prepared by Rheo-compocasting were studied with change of fabrication conditions(slurry temperature, agitation time) and additions of Mg($0{\sim}3wt.%$). Also, the microhardness change of matrix, interface and total in composites were examined with additions of Mg($0{\sim}3wt.%$). The dispersion of particles in the composites became relatively homogeneous with increase of Mg additions, agitation time and decrease of slurry temperature. Rate of occupied area by particle in matrix was increased as increase of Mg additions due to improvement of wettability between SiC particle and matrix. A favorable composites were obtained by melting under Ar atmospheric SiCp injection and bottom pouring system. According to the analysis of X-ray diffraction, $Mg_2Si$, $Al_4C_3$, $SiO_2$ and MgO, etc, intermetallic compounds were formed by chemical interreaction at interface of matrix and particles. The microhardness of interface is higher than that of matrix due to more strengthening of above intermetallic compounds. It was considered that the total hardness of the composites is improved by dispersing of SiCp and addition of Mg.

• 한국해양공학회지
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• 제7권1호
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• pp.13-24
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• 1993

해양오염은 환경파괴의 주요 인자이다. 해양바닥에 가라않은 오염물질을 근본적으로 제거하는 문제와는 별도로, 파동(wave)에 의해 그것이 자동적으로확산될 수가 있다. 파문(ripple)으로 덮혀진 해저(sea bottom)에서 표면의 중력파에 의한 물의 수평방향 요동운동은 와류(vrotices)를 발생시칸다. 이런한 유동장은 해저 침전물을 부유시켜 멀리까지 화가신시키는 작용을 한다.파문주위의 유동장을 살펴보면 모서리(crest)에서 발생된 와류로 인해 정상유동성분이 존재하며 이런한 정상유동은 파문의 주기적 형상으로인해 다분히 순환적이다. 이ㅔ 파동에 의한 요동운동이 가세하면 Taylor 와류와 같은 효과를 보여 줄 것이다. 해저부근에서의 이러한 확산효과를 보기 위하여, 해양유동을 단순화하여 최근 널리 이용되고 있는 혼돈이론을 가미시켰다. 아주 단순한 유동이라도 복잡한 입자의 궤적을 나타내며 입자의 확산과 연관됨을 수치해석을 이용하여 보여준다.

• Steel and Composite Structures
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• 제28권1호
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• pp.99-110
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• 2018

In this paper, a new size-dependent quasi-3D plate theory is presented for wave dispersion analysis of functionally graded nanoplates while resting on an elastic foundation and under the hygrothermaal environment. This quasi-3D plate theory considers both thickness stretching influences and shear deformation with the variations of displacements in the thickness direction as a parabolic function. Moreover, the stress-free boundary conditions on both sides of the plate are satisfied without using a shear correction factor. This theory includes five independent unknowns with results in only five governing equations. Size effects are obtained via a higher-order nonlocal strain gradient theory of elasticity. A variational approach is adopted to owning the governing equations employing Hamilton's principle. Solving analytically via Fourier series, these equations gives wave frequencies and phase velocities as a function of wave numbers. The validity of the present results is examined by comparing them with those of the known data in the literature. Parametric studies are conducted for material composition, size dependency, two parametric elastic foundation, temperature and moisture differences, and wave number. Some conclusions are drawn from the parametric studies with respect to the wave characteristics.

• Structural Engineering and Mechanics
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• 제74권1호
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• pp.91-104
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• 2020

A mathematical analysis has been carried out for understanding the traversal attributes of torsional waves in a Voigt-type viscoelastic porous layer bounded with corrugated surfaces resting over a heterogeneous transversely isotropic gravitating semi-infinite medium. Both the media are assumed to be under the effect of initial stresses acting along horizontal directions. In the presumed geometry, continuous and periodic type of corrugation has been considered. The condensed form of dispersion relation has been obtained analytically with the aid of the Whittaker's function and suitable boundary conditions. The influence of viscoelasticity, porosity, initial stresses, heterogeneity, gravity, undulation and position parameters on the phase and damped velocities has been illustrated graphically. In addition, relative examination investigating the impact of corrugated and planar bounded surfaces on the dispersion and damping characteristics is one of the important highlights of this study.

• 조명전기설비학회논문지
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• 제28권6호
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• pp.52-59
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• 2014

This paper deals with the effect of decomposition products which occur in breakdown of mineral oil, on the insulation characteristics of its oil. Breakdown tests in the oil were conducted by the proposed experimental methods under a quasi-uniform field and AC HV (60Hz). The breakdown voltage in the oil shows characteristics of dispersion from successive breakdowns and, it is found that there are three patterns of the decomposition products behavior at the process of breakdown progress in the oil. Finally, the breakdown voltage dispersion in the oil can be described in detail based on the behavior patterns of the decomposition products and its diffusion time.

• 한국식품과학회지
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• 제28권1호
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• pp.197-202
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• 1996

콜레스테롤을 함유하는 수용성 모형계에서 erythrosine의 첨가농도, 광도, tocopherol과 ${\beta}-carotene$의 첨가에 따른 headspace내의 산소량의 변화와 콜레스테롤 산화물의 생성량의 변화를 연구하였다. Erythrosine의 첨가량이 증가할수록 headspace내 산소량의 감소가 컸고, 각종 COP 생성량은 증가하였다. 형광등의 조도가 증가할수록 headspace내 산소량의 감소가 컸고, 이에 비례하여 콜레스테롤은 감소하였고 총 COP의 생성량은 증가하였다. 일중항 산소 소거제로 tocopherol과 ${\beta}-carotene$을 첨가하였을 때 headspace내의 산소량은 완만하게 감소하였으며, 이에 비례하여 콜레스테롤의 감소가 완만하였고 총 COP의 생성량 또한 감소하였다.

• Composites Research
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• 제32권3호
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• pp.141-147
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• 2019

In this study, micro-sized and nano-sized pure aluminum (Al) powders were compressed by unidirectional pressure at room temperature. Although neither type of Al bulk was heated, they had a high relative density and improved mechanical properties. The microstructural analysis showed a difference in the process of densification according to particle size, and the mechanical properties were measured by the Vickers hardness test and the nano indentation test. The Vickers hardness of micro Al and nano Al fabricated in this study was five to eight times that of ordinary Al. The grain refinement effect was considered to be one of the strengthening factors, and the Hall-Petch equation was introduced to analyze the improved hardness caused by grain size reduction. In addition, the effect of particle size and dispersion of aluminum oxide in the bulk were additionally considered. Based on these results, the present study facilitates the examination of the effect of particle size on the mechanical properties of compacted bulk fabricated by the powder metallurgy method and suggests the possible way to improve the mechanical properties of nano-crystalline powders.

• Communications for Statistical Applications and Methods
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• 제26권3호
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• pp.325-336
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• 2019

In this article we extend the discrete Weibull regression model in the presence of missing data. Discrete Weibull regression models can be adapted to various type of dispersion data however, it is not widely used. Recently Yoo (Journal of the Korean Data and Information Science Society, 30, 11-22, 2019) adapted the discrete Weibull regression model using single imputation. We extend their studies by using multiple imputation also with several various settings and compare the results. The purpose of this study is to address the merit of using multiple imputation in the presence of missing data in discrete count data. We analyzed the seventh Korean National Health and Nutrition Examination Survey (KNHANES VII), from 2016 to assess the factors influencing the variable, 1 month hospital stay, and we compared the results using discrete Weibull regression model with those of Poisson, negative Binomial and zero-inflated Poisson regression models, which are widely used in count data analyses. The results showed that the discrete Weibull regression model using multiple imputation provided the best fit. We also performed simulation studies to show the accuracy of the discrete Weibull regression using multiple imputation given both under- and over-dispersed distribution, as well as varying missing rates and sample size. Sensitivity analysis showed the influence of mis-specification and the robustness of the discrete Weibull model. Using imputation with discrete Weibull regression to analyze discrete data will increase explanatory power and is widely applicable to various types of dispersion data with a unified model.

• 대한원격탐사학회지
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• 제38권1호
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• pp.1-20
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• 2022

As unmanned aerial vehicle (UAV) technology grew in popularity over the years, it was introduced for air quality monitoring. This can easily be used to estimate the sidewalk emission concentration by calculating road traffic emission factors of different vehicle types. These calculations require a simulation of the spread of pollutants from one or more sources given for estimation. For this purpose, a Gaussian plume dispersion model was developed based on the US EPA Motor Vehicle Emissions Simulator (MOVES), which provides an accurate estimate of fuel consumption and pollutant emissions from vehicles under a wide range of user-defined conditions. This paper describes a methodology for estimating emission concentration on the sidewalk emitted by different types of vehicles. This line source considers vehicle parameters, wind speed and direction, and pollutant concentration using a UAV equipped with a monocular camera. All were sampled over an hourly interval. In this article, the YOLOv5 deep learning model is developed, vehicle tracking is used through Deep SORT (Simple Online and Realtime Tracking), vehicle localization using a homography transformation matrix to locate each vehicle and calculate the parameters of speed and acceleration, and ultimately a Gaussian plume dispersion model was developed to estimate the CO, NOx concentrations at a sidewalk point. The results demonstrate that these estimated pollutants values are good to give a fast and reasonable indication for any near road receptor point using a cheap UAV without installing air monitoring stations along the road.