• 제목/요약/키워드: ultraviolet spectra

검색결과 211건 처리시간 0.023초

Study on the realtionship between phthalic and naphthalenic polyimide structures and the photo-induced molecular orientaion of liquid crystals on polyimides

  • Cho, Ki-Yun;Sung, Shi-Joon;Hah, Hyun-Dae;Park, Jung-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.1167-1168
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    • 2004
  • Polarized ultraviolet irradiation techniques have been developed recently to produce alignment of liquid crystals (LC). Because of the excellent thermal stability and the alignment ablility of polyimides, polyimides has attracted considerable research interest for the photoinduced alignment layer. Hasegawa and Taira confirmed homogeneous alignment of LC by the decompostion of a polyimide induced by lineraly ultra-violet polarized light. It was reported that ultraviolet visible absorption spectra of a polyimide alignment film showed a remarkable change upon irradiation. In this study, we synthesized phthalic polyimide and a naphthalenic polyimide in order to investigate the effect of the polyimide structure. Some difference in terms of the photo-induced molecular orientaion of liquid crystals were observed with the polyimide structure.

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초음파분무법으로 제조한 ZnO/MgO막의 특성 (The properties of ZnO/MgO films prepared by ultrasonic spray pyrolysis)

  • 최무희;마대영
    • 센서학회지
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    • 제14권5호
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    • pp.362-367
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    • 2005
  • ZnO films were deposited on MgO substrates (ZnO/MgO) by ultrasonic spray pyrolysis. Substrate temperature varied from $250^{\circ}C$ to $350^{\circ}C$. The crystallographic properties and surface morphologies of the ZnO/MgO films were studied by X-ray diffraction and scanning electron microscopy. The properties of photoluminescence (PL) for the films were investigated by dependence of PL spectra on the substrate temperature and the annealing temperature. The ZnO/MgO films prepared at $350^{\circ}C$ showed the strongest Ultraviolet light emission peak at 18 K and 300 K among the films in this study. The annealing process increases the visible light emission, which is due to the increased oxygen vacancies.

아조벤젠을 함유한 장쇄지방산과 폴리 비닐알코올간의 에스테르화 반응에 의한 폴리머의 광이성화 현상에 관한 연구 (Photoisomerization of Polymer by Esterification Reaction between Poly vinyl alcohol and Azobenzene-containing Long Chain Fatty Acids)

  • 박근호
    • 한국응용과학기술학회지
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    • 제11권1호
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    • pp.53-60
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    • 1994
  • The Synthesis of azobenzene containing long chain fatty acid and poly vinyl alcohol by esterification reaction($C_{n}-Azo-PVA$) was optimized, starting from P-(P'-hydroxy phenyl azo)-benzoic acid and the product of reaction containing azobenzene chromophores was investigated by ultraviolet spectrophotometery in toluene solvent at room temperature. In addition, UV absorption spectra of Langmmuir Blodggett (LB) film deposited on quartz plate have been measured and the structure of these compounds were ascertained by means of Ultraviolet and FT-IR. Recrystallization of reaction product in the solvent results the experimental yield obtained about 22.27% P-(P'-octadecyloxy phenyl azo)-benzoic acid-poly vinyl alcohol. Long chain azobenzene derivative-poly vinyl alcohols are induced phtoisomerization by u, v, and visible light irradiation. The LB film of azobenzene containing long chain fatty acids($C_{18}-Azo-PVA$) are possible of being applied to functional molecular devices such as photomemory and light switching.

ZnO:Er막의 UV 발광에 미치는 열처리 효과 (Annealing effects of ZnO:Er films on UV emission)

  • 최무희;마대영
    • 센서학회지
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    • 제18권4호
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    • pp.316-321
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    • 2009
  • Er-doped ZnO(ZnO:Er) films were deposited onto MgO wafers by ultrasonic spray pyrolysis at 550 $^{\circ}C$ varying the concentration of Er in the deposition source from 0.5 wt% to 3.0 wt%. Annealing of the films in a vacuum was carried out to increase the intensity of ultraviolet(UV) emission from the films. The annealing temperature was between 600$^{\circ}C$ and 800$^{\circ}C$. The crystallographic properties and surface morphology of the films were investigated by X-ray diffraction(XRD)and scanning electron microscope(SEM), respectively. The properties of photoluminescence(PL) for the films were investigated by the dependence of PL spectra on the annealing temperature. X-ray photoelectron spectroscopy(XPS) was conducted to find the composition change in the films by the annealing.

Characterization of Supercontinuum and Ultraviolet Pulses by Using XFROG

  • Tsermaa, Baatarchuluun;Yang, Byung-Kwan;Kim, Myung-Whun;Kim, Jin-Seung
    • Journal of the Optical Society of Korea
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    • 제13권1호
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    • pp.158-165
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    • 2009
  • We present cross-correlation frequency-resolved optical gating (XFROG) measurements of supercontinuum pulses generated by using a photonic crystal fiber (PCF), and ultraviolet (UV) pulses generated by frequency doubling of infrared ultra-short pulses. Since supercontinuum pulses have broad spectra, XFROG measurement typically requires using an extremely thin nonlinear crystal which has a thickness of sub-ten microns. Instead of using such a thin crystal, we employed a relatively thick crystal which was mounted on a galvanometer in order to achieve a phase-matching over the whole spectral bandwidth of the supercontinuum pulses by a crystal-dithering technique. Experimental results of the retrieved phase and intensity were in fair agreement with the independently measured data.

답토양부식물(畓土壤腐植物)에 대(對)한 토양화학적연구(土壞化學的硏究)[I] -Humin 산(酸)과 Hymatomelan 산(酸)의 흡광(吸光) Spectrum- (Soil Chemical Studies on the Humic Substances of Paddy soils(I) -Photoabsorption Spectra of Humic acid and Hymatomelanic acid-)

  • 임선욱;김명종;이춘영
    • Applied Biological Chemistry
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    • 제12권
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    • pp.115-118
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    • 1969
  • 답토양부식물(畓土壤腐植物)에 대(對)한 일련(一連)의 토양화학적연구(土壞化學的硏究)에서 본실험(本實驗)은 수개(數個) 고위(高位)및 저위답토양(低位畓土壞)에서 부식물(腐植物)을 추출(抽出)하고 hymatomelan 산(酸)과 humin 산(酸)으로 분획(分劃)하여 가시(可視), 자외(紫外) 및 적외부(赤外部)에시 흡광(吸光) spectrum을 측정(測定)하여 비교검토(比較檢討)하였다. 토양비옥도(土壞肥沃度)의 차이(差異)에 따라 부식분획물(腐植分劃物)의 흡광(吸光)은 어느 광파역(光波域)에서도 별(別)다른 상이성(相異性)이 존재(存在)하지 않으며 자외광흡수(紫外光吸收) spectrum이 퇴비(堆肥)와 다른 유형(類型)의 토양(土壞)에서 분리(分離)한 부식산(腐植酸)의 spectrum과는 다르게 hymatomelan 산(酸)이 나 humin 산(酸) 모두 $235\;m{\mu}$에서 최고(最高), $395\;m{\mu}$에서 최저(最低)의 만곡접(灣曲點)을 나타내었다. 적외광흡수(赤外光吸收) spectrum은 양(兩) fraction간(間)에 상이점(相異點)을 보여 파수(波數) $1720\;cm^{-1}$에 특징적(特徵的)인 Peak가 존재하(存在)하며 이보다 장파역(長波域)($7.5{\sim}9.5{\mu}$)에서도 상이(相異)한 양상(樣狀)이었다. 또한 이 spectrum 들을 다른 연구자(硏究者)들에 의(依)한것과 대조(對照)하여 상이성(相異成)을 고찰(考察)하였다.

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Preparation of Polyynes by the Laser Ablation of Graphite in Water and Organic Solvents

  • Shin, Seung-Keun;Park, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • 제33권2호
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    • pp.597-600
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    • 2012
  • Polyynes were formed by laser ablation of a graphite target in deionized water ($H_2O$ and $D_2O$) and various organic solvents such as acetonitrile, n-hexane, and c-hexane and were identified by analyzing ultraviolet (UV) absorption and Raman spectra. We assigned the major UV absorption peaks that coincided with the electronic transitions corresponding to linear polyyne chains. The UV absorption peak intensities of a polyyne solution decreased as the holding temperature of the solution increased. Also, the absorption spectra of polyynes obtained by laser ablation of a graphite target at different volume fractions of $H_2O$ and $D_2O$ were examined.

공기 중 대기압 분위기에서 ZnS의 산화에 의해 생성된 벨트형상과 빗 형상의 ZnO 결정 (ZnO Crystals with Belt and Comb Shapes Synthesized by Oxidation of ZnS in Air Atmosphere)

  • 이근형
    • 한국전기전자재료학회논문지
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    • 제24권11호
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    • pp.920-924
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    • 2011
  • ZnO crystals with belt and comb shapes were synthesized without any catalysts through a simple thermal oxidation of ZnS powder in alumina crucible under air atmosphere. X-ray diffraction (XRD) pattern revealed that the ZnO crystals had wurtzite structure of hexagonal phase. Energy dispersive x-ray (EDX) spectra showed that the ZnO was of high purity. In the cathodoluminescece spectra obtained for the ZnO crystals with belt and comb shapes, a strong ultraviolet emission centered at 380nm was observed, which indicates the ZnO crystal has high crystalline quality.

Azoxybenzene 系化合物들의 分光學的硏究 및 그 最大吸收波長의 加成性 (The Absorption Spectra of Substituted Azoxybenzenes and the Additivity of the their Absorption Maxima)

  • 한치선
    • 대한화학회지
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    • 제6권2호
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    • pp.170-175
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    • 1962
  • The ultraviolet and visable absorption spectra of trans, cis-azoxybenzene, substituted azoxybenzenes and their conjugate acids have been studied. The 320-350$m{\mu}$ main bands of free-base of azoxybenzenes are due to ${\pi}{\to}{\pi}^{\ast}$ transition. These bands of their conjugate acids shown bathochromic shift into visible range. The following emperical relationship between absorption maxima of the main bands was found. ${\lambda}_{max}={\lambda}^{\circ}_{max}+{\Delta}{\lambda}_x+{\Delta}{\lambda}_y$ This relationship in terms of wave number is also hold in good agreement. ${\nu}={\nu}_{\circ}-({\Delta}{\nu}_x+{\Delta}{\nu}_y)$

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Structure and Photoluminescence Properties of SnO2/Zn Core-shell Nanowires

  • Kim, Hyoun Woo;Na, Han Gil;Kwon, Yong Jung;Cho, Hong Yeon
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2014년도 추계학술대회 논문집
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    • pp.241-241
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    • 2014
  • $SnO_2-core/Zn-shell$ heteronanowires were fabricated by a two-step process: thermal evaporation of Sn powders and employing a sputtering technique with a Zn target. X-ray diffraction, high-resolution transmission electron microscopy, and EDX spectra coincidentally indicated that the shell layer comprised the Zn phase. From Gaussian deconvolution studies, we observed that photoluminescence (PL) spectra consisted of yellow, green, and ultraviolet (UV) emission bands, regardless of shell-coating. We speculated the possible mechanisms of these emission peaks.

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