• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.279-279
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• 2010

Smart gels have recently associated with photonic crystals to form photonic gels. Since these photonic gels are capable of reversibly converting the volume change of gels induced in response to external chemical or electric stimuli into characteristic optical signals, they have been considered not only as a good platform for label-free chemical or biological detection, actuators or optical switches but also as a good model system to investigate gel swelling behaviour. Recently, we reported block copolymer photonic gels self-assembled from polystyrene-b-poly(2-vinyl pyridine) (PS-b-P2VP) block copolymers, and demonstrated that selective swelling of lamellar structure allows extremely large tunability of the photonic stop band from UV region to IR region ($\lambda$ peak=350~1,600 nm). Herein we report block copolymer photonic gels which exhibit strong tunable optical hysteresis and their applications. As nonlinear responses in swelling of hydrogels were often observed, photonic gels exhibit optical hysteresis with change of external pH. We demonstrate such optical hysteresis can be precisely programmed by controlling ion-pairing affinity. We anticipate that photonic gels with carefully tunned optical hysteresis are applicable to optical memory devices.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.12 no.7
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• pp.1249-1255
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• 2008

1530nm band has been studied as pump wavelength for long-wavelength-band erbium-doped fiber amplifier (L-band EDFA). The pump source is built using a tunable light source and cascaded conventional-band (C-band) EDFA. The L-band EDFA uses a forward pumping scheme. Within the 1530nm band, 1545nm pump demonstrates 0.45dB/mW gain coefficient, which is twice better than that of conventional 1480nm pumped EDFA. The noise figure of 1530nm pump is at worst 6.36dB, which is 0.75dB higher than that of 1480nm pumped EDFA. Such high gain coefficient indicates that the L-band EDFA consumes low power.

• Current Optics and Photonics
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• v.3 no.5
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• pp.401-407
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• 2019

Polymeric optical waveguide devices with Bragg gratings have been investigated, for implementing tunable lasers and wavelength filters used in wavelength-division-multiplexed optical communication systems. Owing to the excellent thermo-optic effect of these polymers, wavelength tuning is possible over a wide range, which is difficult to achieve using other optical materials. In this study the phase-mask technology, which has advantages over the conventional interferometeric method, was introduced to facilitate the fabrication of Bragg gratings in polymeric optical waveguide devices. An optical setup capable of fabricating multiple Bragg gratings simultaneously on a 4-inch silicon wafer was constructed, using a 442-nm laser and phase mask. During fabrication, some of the diffracted light in the phase mask was totally reflected inside the mask, which affected the quality of the Bragg grating adversely, so experiments were conducted to solve this issue. To verify grating uniformity, two types of wavelength-filtering devices were fabricated using the phase-mask lithography, and their reflection and transmission spectra were measured. From the results, we confirmed that the phase-mask method provides good uniformity, and may be applied for mass production of polymer Bragg-grating waveguide devices.

• Structural Monitoring and Maintenance
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• v.2 no.3
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• pp.181-197
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• 2015

Assessing the condition of paint on civil structures is an important but challenging and costly task, in particular when it comes to large and complex structures. Current practices of visual inspection are labour-intensive and time-consuming to perform. In addition, this task usually relies on the experience and subjective judgment of individual inspectors. In this study, hyperspectral imaging and classification techniques are proposed as a method to objectively assess the state of the paint on a civil or other structure. The ultimate objective of the work is to develop a technology that can provide precise and automatic grading of paint condition and assessment of degradation due to age or environmental factors. Towards this goal, we acquired hyperspectral images of steel surfaces located at long (mid-range) and short distances on the Sydney Harbour Bridge with an Acousto-Optics Tunable filter (AOTF) hyperspectral camera (consisting of 21 bands in the visible spectrum). We trained a multi-class Support Vector Machines (SVM) classifier to automatically assess the grading of the paint from hyperspectral signatures. Our results demonstrate that the classifier generates highly accurate assessment of the paint condition in comparison to the judgement of human experts.

• Smart Structures and Systems
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• v.18 no.3
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• pp.471-484
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• 2016

Optical fiber sensors have been proven that they have the potential to detect high-frequency ultrasonic signals, in structural health monitoring field which generally refers to acoustic emission signals from active structural damages and guided waves excited by ultrasonic actuators and propagating in waveguide. In this work, the sensing properties of optical fiber sensors based on Mach-Zehnder interferometer were investigated in the metal plate. Analytical formulas were conducted first to explore the parameters affecting its sensing performances. Due to the simple and definable frequency component, the Lamb wave excited by the piezoelectric wafer was employed to study the sensitivity of the proposed optical fiber sensors with respect to the frequency, rather than the acoustic emission signals. In the experiments, according to above investigations, spiral shape optical fiber sensors with different size were selected to increase their sensitivity. Lamb waves were excited by a circular piezoelectric wafer, while another piezoelectric wafer was used to compare their voltage responses. Furthermore, by changing the excitation frequency, the tuning frequency characteristic of the proposed optical fiber sensor was also investigated experimentally.

• Macromolecular Research
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• v.17 no.3
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• pp.181-186
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• 2009

We fabricated ordered micro/nano patterns induced by controlled dewetting on the topographically patterned PS/P4VP bilayer thin film. The method is based on utilizing microimprinting lithography to induce a topographically heterogeneous bilayer film that allows the controlled dewetting upon subsequent thermal annealing. The dewetting that was initiated strictly at the boundary of the thicker and thinner regions was guided by the presence of the topographic structure. The dewetting front velocity of the microdomains in the confined regions was linearly proportional to the measurement time, which enabled us to control the size of the dewet domain with annealing time. In particular, the submicron sized dot arrays between lines were generated with ease when the dewetting was confined into geometry with a few microns in size. The kinetically driven, non-lithographical pattern structures accompanied the pattern reduction to 400%. The pattern arrays on a transparent glass substrate were especially useful for non-circular microlens arrays where the focal length of the lens was easily tunable by controlling the thermal annealing.

• Macromolecular Research
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• v.16 no.3
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• pp.200-203
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• 2008

A conducting polymer layer was introduced into the pore surface of mesoporous carbon via vapor infiltration of a monomer and subsequent chemical oxidative polymerization. The polypyrrole, conducting polymer has attracted considerable attention due to the high electrical conductivity and stability under ambient conditions. The mesoporous carbon-polypyrrole nanocomposite exhibited the retained porous structure, such as mesoporous carbon with a three-dimensionally connected pore system after intercalation of the polypyrrole layer. In addition, the controllable addition of pyrrole monomer can provide the mesoporous carbon-polypyrrole nanocomposites with a tunable amount of polypyrrole and texture property. The polypyrrole layer improved the electrode performance in the electrochemical double layer capacitor. This improved electrochemical performance was attributed to the high surface area, open pore system with three-dimensionally interconnected mesopores, and reversible redox behavior of the conducting polypyrrole. Furthermore, the correlation between the amount of polypyrrole and capacitance was investigated to check the effect of the polypyrrole layer on the electrochemical performance.

• Journal of the Optical Society of Korea
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• v.15 no.1
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• pp.82-89
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• 2011

In this paper, we numerically study both band-pass and band-stop plasmonic filters based on Metal-Insulator-Metal (MIM) waveguides and circular ring resonators. The band-pass filter consists of two MIM waveguides coupled to each other by a circular ring resonator. The band-stop filter is made up of an MIM waveguide coupled laterally to a circular ring resonator. The propagating modes of Surface Plasmon Polaritons (SPPs) are studied in these structures. By substituting a portion of the ring core with air, while the outer dimensions of the ring resonator are kept constant, we illustrate the possibility of red-shift in resonant wavelengths in order to tune the resonance modes of the proposed filters. This feature is useful for integrated circuits in which we have limitations on the outer dimensions of the filter structure and it is not possible to enlarge the dimension of the ring resonator to reach to longer resonant wavelengths. The results are obtained by a 2D finite-difference time-domain (FDTD) method. The introduced structures have potential applications in plasmonic integrated circuits and can be simply fabricated.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2018.11a
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• pp.379-379
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• 2018

MXenes are a new family of 2D transition metal carbide nanosheets analogous to graphene (Lv et al., 2017; Sun et al., 2018). Due to the easy availability, hydrophilic behavior, and tunable chemistry of MXenes, their use in applications for environmental pollution remediation such as heavy metal adsorption has recently been explored (Li et al., 2017). In this study, three-dimensional (3D) MXene ($Ti_3C_2T_x$) films with high adsorption capacity, good mechanical strength, and high selectivity for specific radionuclide from aquose solution were successfully fabricated by a polymeric precursor method using vacuum-assisted filtration. The highest removal efficiency on the films was 99.54%, 95.61%, and 82.79% for $Sr^{2+}$, $Co^{2+}$, and $Cs^+$, respectively, using a film dosage of 0.06 g/ L in the initial radionuclide solution (each radionuclide concentration = 1 mg/L and pH = 7.0). Especially, the adsorption process reached an equilibrium within 30 min. The expanded interlayer spacing of $Ti_3C_2T_x$ sheets in MXene films showed excellent radionuclide selectivity ($Cs^+$ and/or $Sr^{2+}/Co^{2+}$) (Simon, 2017). Besides, the MXene films was not only able to be easily retrieved from an aqueous solution by filtration after decontamination processes, but also to selectively separate desired target radionuclides in the solutions. Therefore, the newly developed MXene ($Ti_3C_2T_x$) films has a great potential for radionuclide removal from aqueous solution.

• Current Optics and Photonics
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• v.3 no.1
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• pp.33-39
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• 2019

We report development of a frequency-stabilized mid-infrared continuous-wave (cw) optical parametric oscillator (OPO) based on a fan-out grating MgO:PPLN crystal pumped at 1064 nm. The OPO resonator was designed as a pump-enhanced standing-wave cavity that resonates to the pump and signal beams. To realize stable operation of the OPO, we applied a modified Pound-Drever-Hall technique, which is a well-known method for powerful laser frequency stabilization. Tuning a poling period of the fan-out grating of the crystal allows wavelength-tunable OPO outputs from 1510 nm to 1852 nm and from 2500 nm to 3600 nm for signal and idler beams, respectively. At the idler wavelengths of 2500 nm, 3000 nm and 3500 nm, we achieved more than 50 mW of output powers at a pumping power of 1.1 W. The long-term stability of the OPO was confirmed by recording the power and wavelength variations of the idler for an hour.