• Title/Summary/Keyword: tunability

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Review of interface engineering for high-performance all-solid-state batteries (계면 제어를 기반으로 한 고성능 전고체 전지 연구)

  • Insu, Hwang;Hyeon Jeong, Lee
    • Journal of Industrial Technology
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    • v.42 no.1
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    • pp.19-27
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    • 2022
  • This review will discuss the effort to understand the interfacial reactions at the anode and cathode sides of all-solid-state batteries. Antiperovskite solid electrolytes have received increasing attention due to their low melting points and anion tunability which allow controlling microstructure and crystallographic structures of this material system. Antiperovskite solid electrolytes pave the way for the understanding relationship between critical current density and mechanical properties of solid electrolytes. Microstructure engineering of cathode materials has been introduced to mitigate the volume change of cathode materials in solid-state batteries. The hollow microstructure coupled with a robust outer oxide layer effectively mitigates both volume change and stress level of cathode materials induced by lithium insertion and extraction, thus improving the structural stability of the cathode and outer oxide layer, which results in stable cycling performance of all-solid-state batteries.

A design of tuning band and structure to generate diverse properties by stretching

  • Ruqi Wang;Ruoyun Li
    • Advances in nano research
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    • v.14 no.5
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    • pp.451-461
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    • 2023
  • Two-dimensional (2D) materials have been attracting attention since graphene monolayer was firstly separated. However, after an explosive boom, there is always quandary and stagnancy following and soon will come the refractory period of capital market. To avoid that undesired future, a paradigm of quasi 2D monolayer has been contemplated and devised in this article, with examples studied theoretically. The results show the general dynamic nonlinearity, and the expected tunability of bandgap without extra doping or substitution. These together suggest its intriguing both electronical and mechanical properties, which will enrich the arsenal of potential 2D materials.

Study on the Fabrication and Characterization of Hydrophobic Surface with Hierarchical Microstructure using Spray Coating Deposition Method (스프레이 코팅 증착 방식을 이용한 계층적 미세 구조의 발수표면 제작 및 특성 분석에 대한 연구)

  • Jongyun Choi;Kiwoong Kim
    • Journal of the Korean Society of Visualization
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    • v.21 no.3
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    • pp.15-22
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    • 2023
  • This research introduces an innovative approach for fabricating microstructure surfaces using spray-coating deposition. The resulting surface, referred to as Magnetically Responsive Microstructures (MRM), exhibits hierarchically structured micro-pillar arrays with remarkably high aspect ratios. The fabrication process involves precisely mixing PDMS and hexane with Carbonyl iron powders, followed by ultrasonication and spray-coating on the top of a PDMS substrate placed on the neodymium magnet. The MRM surface shows hydrophobic properties, characterized by a contact angle surpassing 150° and an aspect ratio exceeding 10. Through a comprehensive exploration of critical parameters, including spray amount, magnet-substrate distance, and solution ratio enhanced dynamic tunability and exceptional hydrophobic characteristics are attained. This novel approach holds significant potential for diverse applications in the realm of dynamically tunable microstructures and magnetically responsive surfaces.

A Micromachined Tunable Bandpass Filter Using Tunable Series Inductors For WLAN Applications (가변 직렬 인덕터를 이용한 무선랜 응용 MEMS 가변 대역 통과 필터)

  • Kim, Jong-Man;Park, Jae-Hyoung;Kim, Jung-Mu;Lee, Sang-Hyoung;Baek, Chang-Wook;Kwon, Young-Woo;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.2108-2110
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    • 2004
  • In this paper, a novel tunable bandpass filter using tunable series inductors and MEMS switches for wireless LAN applications was proposed. The proposed tunable filter was fabricated using a micromachining technology and performances of the fabricated filter were estimated. The filter consists of spiral inductors, MIM capacitors and direct-contact type MEMS switches, and its frequency tunability is achieved by changing the inductance that is induced by ON/OFF actuations of the MEMS switches. The actuation voltage of the MEMS switches was 58 V, and the measured center frequencies were 2.55 GHz and 5.1 GHz, respectively. The passband insertion loss and 3-dB bandwidth were 4.2 dB and 22.5 % at 2.55 GHz, and 5.2 dB and 23.5 % at 5.1 GHz, respectively.

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Optimization of Emulsion Polymerization for Submicron-Sized Polymer Colloids towards Tunable Synthetic Opals

  • Kim, Seul-Gi;Seo, Young-Gon;Cho, Young-Jin;Shin, Jin-Sub;Gil, Seung-Chul;Lee, Won-Mok
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1891-1896
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    • 2010
  • Submicron-sized polymeric colloidal particles can self assemble into 3-dimensional (3D) opal structure which is a useful template for photonic crystal. Narrowly dispersed polymer microspheres can be synthesized by emulsion polymerization in water using water-soluble radical initiator. In this report, we demonstrate a facile and reproducible emulsion polymerization method to prepare various polymeric microspheres within 200 - 400 nm size ranges which can be utilized as colloidal photonic crystal template. By controlling the amount of monomer and surfactant, monodisperse polymer colloids of polystyrene (PS) and acrylates with various sizes were successfully prepared without complicated synthetic procedures. Such polymer colloids self-assembled into 3D opal structure exhibiting bright colors by reflection of visible light. The colloidal particles and the resulting opal structures were rigorously characterized, and the wavelength of the structural color from the colloidal crystal was confirmed to have quantitative relationship with the size of constituting colloidal particles as predicted by Bragg equation. The tunability of the structural color was achieved not only by varying the particle size but also by infiltration of the colloidal crystal with liquids having different refractive indices.

Fabrication of Patchable Organic Lasing Sheets via Soft Lithography

  • Kim, Ju-Hyung
    • Clean Technology
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    • v.22 no.3
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    • pp.203-207
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    • 2016
  • Here, we report a novel fabrication technique for patchable organic lasing sheet based on non-volatile liquid organic semiconductors and freestanding polymeric film with high flexibility and patchability. For this work, we have fabricated the second-order DFB grating structure, which leads to surface emission, embedded in the freestanding polymeric film. Using an ultra-violet (UV) curable polyurethaneacrylate (PUA) mixture, the periodic DFB grating structure can be easily prepared on the freestanding polymeric film via a simple UV curing process. Due to unsaturated acrylate remained in the PUA mixture after UV curing, the freestanding PUA film provides adhesive properties, which enable mounting of the patchable organic lasing sheet onto non-flat surfaces with conformal contact. To achieve laser actions in the freestanding resonator structure, a composite material of liquid 9-(2-ethylhexyl)carbazole (EHCz) and organic laser dyes was used as the laser medium. Since the degraded active materials can be easily refreshed by a simple injection of the liquid composite, such a non-volatile liquid organic semiconducting medium has degradation-free and recyclable characteristics in addition to other strong advantages including tunable optoelectronic responses, solvent-free processing, and ultimate mechanical flexibility and uniformity. Lasing properties of the patchable organic lasing sheet were also investigated after mounting onto non-flat surfaces, showing a mechanical tunability of laser emission under variable surface curvature. It is anticipated that these results will be applied to the development of various patchable optoelectronic applications for light-emitting displays, sensors and data communications.

Characterization of BST films for high tunable thin film capacitor

  • No, Ji-Hyeong;Song, Sang-U;Kim, Ji-Hong;Go, Jung-Hyeok;Mun, Byeong-Mu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.179-179
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    • 2009
  • This is for the electrical characterization by IDC pattern using BST$(Ba_{0.5}Sr_{0.5}TiO_3)$ thin film. BST materials had been chosen for high frequency applications due to it's high permitivity and tunability. The BST thin films have been deposited on $Al_2O_3$ Substrates by Nd-YAG pulsed laser deposition with a 355nm wavelength at $700\;^{\circ}C$. The post deposition annealing at $750^{\circ}C$ in flowing $O_2$ atmosphere for 1 hours. The capacitance of IDC patterns have been measured from 1 to 10 GHz as a function of electric field ($\pm40$ KV/cm) at room temperature using inter-digital Au electrodes deposited on top of BST. The IDC patterns have three type of fingers number. For the 10 pairs finger was the best capacitance onto $Al_2O_3$ substrate. The capacitance was 0.9pF. Also Dielectric constant was been 351 at 100 mTorr and annealing temperature $750^{\circ}C$ for 1 hour. The loss tangent was been 0.00531.

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Electrical and Magnetical Characteristics for PZT/Ferrite Ceramics (PZT/Ferrite 합성 세라믹의 특성에 관한 기초연구)

  • 김장용;이상현;이승봉;안형호;현충일;이명세;문병무
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.4
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    • pp.153-158
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    • 2003
  • This thesis deal with ferroelectric and ferromagnetic materials. PZT/Ferrite ceramics were made by the making process using PZT powder and garnet ferrite powder. PZT and ferrite are mixed as much 90%-10%, 50%-50%, and so on. After making samples, we are polishing samples until thickness is 0.1~0.2mm. We measured all kinds of samples in room temperature and applied magnetic field from -4500 to 4500 Oersted and conducted test of magnetical and electrical measurement using VSM and lpC resolution electrometer calibrated with RT66A pulsed tester. From this measurement, we can calculate tunability of these samples using C value obtained from P-E loop. As a result, it was able to measure magnetic characteristic when two matter had each other component ratio, and it was compound. However, it confirmed the possibility that was able to have ferroelectric characteristic with you in PZT 90% and ferrite 10%. Therefore, If this thing comes for PZT 50% and ferrite 50% have ferroelectric characteristic as him in a compound sample ore, can use this in an oscillator, supersonic waves detector in addition to a piezoelectric element. It may contribute to multipurpose of an element and demands such as a miniaturization of equipment, efficiency, reduce of a price which can use a characteristic of two components.

Design and Simulation of Tunable Dielectric Multilayer (TDM) Filters for RF and MMIC Applications (MMIC화를 위한 RF용 튜닝가능한 다층 박막 유전체 필터 설계 및 시뮬레이션)

  • 윤기완;채동규;임문혁;김동현
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.4
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    • pp.730-735
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    • 2003
  • In this paper, four different types of BSTO tunable bandpass filters with ferroelectrics are proposed. The achievement of the tunability is based on the fact that the increase in the bias voltage leads to the reduction of the effective dielectric constant. Therefore, the center frequency shifts to the higher value with the higher bias voltage. The most frequently used and well-known ferroelectrics are STO and BSTO materials where the STO is mainly used below 100K while the BSTO is used at room temperature. The proposed technology seems very useful and promising for the development of the next-generation wireless communications.

High-temperature superconducting band-pass filters for digital cellular communication system (고온 초전도체를 이용한 이동통신 기지국용 영역통과 필터에 관한 연구)

  • J. H. Lee;Y. H. Do;J. S. Kwak;C. O. Kim;J. P. Hong;K. L. Lee;S. K. Han;K. Char
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.132-136
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    • 2003
  • Extremely selective high temperature superconducting (HTS) band -pass filters were developed for the base transceiver station applications of Digital Cellular communication Service (DCS). The filters have a bandwidth of 25 MHz at a center frequency of 834 MHz. There are 12 resonators which have spiral-meander microstrip-line structures in order to reduce far-field radiations with a reasonable tunability. As a result, the size of filters is 5 mm $\times$ 17 mm $\times$ 41 mm. Device characteristics exhibited a low insertion loss of -0.4 dB with a -0.2 dB ripple and a return loss better than -10 dB in the pass-band at 65 K. The out-of-band signals were attenuated better than 60 dB about 3.5 MHz from the lower band edge, and 3.8 MHz from the higher band edge.

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