• 제목/요약/키워드: trapping mechanism

검색결과 71건 처리시간 0.031초

An Overview on Hydrogen Uptake, Diffusion and Transport Behavior of Ferritic Steel, and Its Susceptibility to Hydrogen Degradation

  • Kim, Sung Jin;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • 제16권4호
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    • pp.209-225
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    • 2017
  • Development of high strength steel requires proper understanding of hydrogen behavior since the higher the steel strength the greater the susceptibility of hydrogen assisted cracking. This paper provides a brief but broad overview on hydrogen entry and transport behavior of high-strength ferritic steels. First of all, hydrogen absorption, diffusion and trapping mechanism of the steels are briefly introduced. Secondly, several experimental methods for analyzing the physical/chemical nature of hydrogen uptake and transport in the steels are reviewed. Among the methods, electrochemical permeation technique utilized widely for evaluating the hydrogen diffusion and trapping behavior in metals and alloys is mainly discussed. Moreover, a modified permeation technique accommodating the externally applied load and its application to a variety of steels are intensively explored. Indeed, successful utilization of the modified permeation technique equipped with a constant load testing device leads to significant academic progress on the hydrogen assisted cracking (HAC) phenomenon of the steels. In order to show how the external and/or residual stress affects mechanical instability of steel due to hydrogen ingress, the relationship among the microstructure, hydrogen permeation, and HAC susceptibility is briefly introduced.

Lu3Al5-xGaxO12:Ce3+,Cr3+ 형광체의 결정구조 분석 및 잔광성 발광 특성 (Crystal Structure Refinement and Persistent Luminescence Properties of Lu3Al5-xGaxO12:Ce3+,Cr3+ Phosphors)

  • 김지원;김영진
    • 한국재료학회지
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    • 제30권8호
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    • pp.413-420
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    • 2020
  • Lu3Al5-xGaxO12:Ce3+,Cr3+ powders are prepared using a solid-state reaction method. To determine the crystal structure, Rietveld refinement is performed. The results indicate that Ga3+ ions preferentially occupied tetrahedral rather than octahedral sites. The lattice constant linearly increases, obeying Vegard's law, despite the strong preference of Ga3+ for the tetrahedral sites. Increasing x led to a blue-shift of the Ce3+ emission band in the green region and a change in the emission intensity. Persistent luminescence is observed from the powders prepared with x = 2-3, occurring through a trapping and detrapping process between Ce3+ and Cr3+ ions. The longest persistent luminescence is achieved for x = 2; its lifetime is at least 30 min. The findings are explained using crystal structure refinement, crystal field splitting, optical band gap, and electron trapping mechanism.

유한차분 시간영역 방법을 이용한 Ag 나노링 구조의 산란효과 (Finite-Difference Time-Domain Calculation of Light Scattering Efficiency for Ag Nanorings)

  • 이태수;정종율
    • 한국재료학회지
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    • 제22권10호
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    • pp.519-525
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    • 2012
  • Enhancement of light trapping in solar cells is becoming increasingly urgent for the development of next generation thin film solar cells. One of the possible candidates for increasing light trapping in thin film solar cells that has emerged recently is the use of scattering from metallic nanostructures. In this study, we have investigated the effects of the geometric parameters of Ag nanorings on the light scattering efficiency by using three dimensional Finite Different Time Domain (FDTD) calculations. We have found that the forward scattering of incident radiation from Ag nanorings strongly depends on the geometric parameters of the nanostructures such as diameter, height, etc. The forward scattering to substrate direction is increased as the outer diameter and height of the nanorings decrease. In particular, for nanorings larger than 200 nm, the inner diameter of Ag nanorings should be optimized to enhance the forward scattering efficiency. Light absorption and scattering efficiency calculations for the various nanoring arrays revealed that the periodicity of nanorings arrays also plays an important role in the absorption and the scattering efficiency enhancement. Light scattering efficiency calculations for nanoring arrays also revealed that enhancement of scattering efficiency could be utilized to enhance the light absorption through the forward scattering mechanism.

Observation of nano powders and fly ash usage effects on the fluidity features of grouts

  • Celik, Fatih;Yildiz, Oguzhan;Bozkir, Samet M.
    • Advances in nano research
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    • 제13권1호
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    • pp.13-28
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    • 2022
  • The pumpability of the grouts is significant issue in concept of the rheological and workability properties during penetrating to voids and cracks. To improve the fluidity features of the grout mixes, the usage of Colloidal Nano Particular Powders (CNPPs) with mineral additives such as fly ash (FA) can contribute. Therefore, the main purpose of this study can be explained as investigating the usage effects of four types of Colloidal Nano Particular Powders (n-TiO2, n-ZnO, n-Al2O3 and n-SiO2) as nano additives on the rheological, workability and bleeding properties of cement-based grout incorporated with fly as. Test results showed that the usage of FA in the grout samples positively contribute to increase on the fluidity of the grout samples as expected. The dilatant behavior was observed from the results for all mixes. Observing the effect of nano-sized additives in such cement-based grout mixtures with high fluidity has presented remarkable effects in this study.

광 포획 향상을 위한 다중 아키텍처 식각 기술을 적용한 박막 실리콘 태양전지에 관한 연구 (A Study on Thin-Film Silicon Solar Cells with Multi-Architecture Etching Technique to Improve Light Trapping)

  • 박형기;이준신
    • 한국전기전자재료학회논문지
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    • 제37권3호
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    • pp.337-344
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    • 2024
  • This work focuses on improving the light-harvesting efficiency of thin-film silicon solar cells through innovative multi-architecture surface modifications. To create a regular optical structure, a lithographic process was performed to form it on a glass substrate through various etching processes, from Etch-1 to Etch-3. AZO was deposited on top of the structures and re-etched to create a multi-architectural surface. These surface-modified structures improved the light absorption and overall performance of the solar cell through changes in optical and physical properties, which we will analyze. In addition, we investigated the effect of post-cleaning on the etched glass structures through EDX analysis to understand the mechanism of the etching action. The results of this study are expected to provide important guidelines for the design and fabrication of solar cells and other photovoltaic devices.

금속 섬유 필터층을 이용한 미세 분진 집진 성능 관찰 (Examination of Dust Trapping Mechanism in a Metal Fiber Filter-bed)

  • 이경미;조영민
    • 한국대기환경학회지
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    • 제20권3호
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    • pp.361-369
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    • 2004
  • A metal fiber bed has seldom been applied to the practical filtration process despite its excellent mechanical and chemical stability. The filter-bed used in this work was highly porous with open structure, of which apparent porosity was 80 ∼ 90%. Although pressure loss across the filter-bed was very low, separation efficiency was found to be quite high. This paper focuses on the basic filtration mechanisms of a metal filter-bed and a thin ceramic filter from fly ash for reference. The experimental parameters were face velocity, dust loading and porosity of filter-bed. Pressure drop increased with increasing face velocity and dust feeding load for both filters. It also showed that dust particles deposited in the deep flow path, finally resulting in clogging the pore channels. It thereby indicates that the dominating mechanism of the metal filter-bed would be depth filtration. Meanwhile, the thin fly ash composite filters trapped the aerated dust mainly on the surface of the filter medium, so that the instantaneously formed dust layer might cause a steep increase of pressure drop across the filtration system.

이미징기술을 활용한 코어규모의 다상유체 유동 특성화: 이산화탄소 지중저장 연구에의 적용 (Use of an Imaging Technology for Characterizing Core-scale Multiphase Flow: Application to CO2 Geological Storage)

  • 김구영
    • 지질공학
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    • 제28권1호
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    • pp.35-45
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    • 2018
  • 이미징 기술은 매질 자체의 구조특성 뿐만 아니라 유체의 유동특성을 분석하기 위해 공극규모, 코어규모, 그리고 중급규모에서 다양하게 활용되고 있다. 본 기술보고에서는 코어규모에서 유동실험과 이미징기술을 연계하여 균질매질, 균열매질, 그리고 불균질매질에서의 이산화탄소($CO_2$) 유동 특성과 함께 $CO_2$ 주입시 주입관정 주변에서 발생할 수 있는 염침전 현상, 균질매질과 균열매질에서의 모세관압 평가, 그리고 $CO_2$ 주입이 완료된 이후 나타나는 포획메커니즘 평가 등에 대해 살펴보았다. 이미징기술을 통해 코어내에서 시간에 따른 $CO_2$ 플룸을 이미지화 함으로써 유동특성을 분석할 수 있으며, 특히 균열이 포함된 매질과 불균질한 매질에서의 유동 및 저장특성을 평가할 수 있다.

Progress of High-k Dielectrics Applicable to SONOS-Type Nonvolatile Semiconductor Memories

  • Tang, Zhenjie;Liu, Zhiguo;Zhu, Xinhua
    • Transactions on Electrical and Electronic Materials
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    • 제11권4호
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    • pp.155-165
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    • 2010
  • As a promising candidate to replace the conventional floating gate flash memories, polysilicon-oxide-nitride-oxidesilicon (SONOS)-type nonvolatile semiconductor memories have been investigated widely in the past several years. SONOS-type memories have some advantages over the conventional floating gate flash memories, such as lower operating voltage, excellent endurance and compatibility with standard complementary metal-oxide-semiconductor (CMOS) technology. However, their operating speed and date retention characteristics are still the bottlenecks to limit the applications of SONOS-type memories. Recently, various approaches have been used to make a trade-off between the operating speed and the date retention characteristics. Application of high-k dielectrics to SONOS-type memories is a predominant route. This article provides the state-of-the-art research progress of high-k dielectrics applicable to SONOS-type nonvolatile semiconductor memories. It begins with a short description of working mechanism of SONOS-type memories, and then deals with the materials' requirements of high-k dielectrics used for SONOS-type memories. In the following section, the microstructures of high-k dielectrics used as tunneling layers, charge trapping layers and blocking layers in SONOS-type memories, and their impacts on the memory behaviors are critically reviewed. The improvement of the memory characteristics by using multilayered structures, including multilayered tunneling layer or multilayered charge trapping layer are also discussed. Finally, this review is concluded with our perspectives towards the future researches on the high-k dielectrics applicable to SONOS-type nonvolatile semiconductor memories.

BiPbSrCaCuO 초전도체의 전자기특성 (Electromagnetic Properties of BiPbSrCaCuO Superconductor)

  • 이상헌;남성필;이성갑;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 하계학술대회 논문집 C
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    • pp.1549-1551
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    • 2004
  • The Electromagnetic properties in BiPbSrCaCuO superconductor was studied. In the measurement of current-voltage characteristics, a voltage across the superconducting sample was observed on applying an external magnetic field. The voltage continues to appear the removal of the magnetic field. The appearance of the voltage is ascribed to the trapping of magnetic flux. Depanding on the direction of applied magnetic flux less than 2.5${\times}$10-5 T, the voltage in the magnetized sample increases or decreases. It is considered that mechanism of voltage occurrence can be explained by applying filament model.

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나노급 소자의 핫캐리어 특성 분석 (Characterization of Hot Carrier Mechanism of Nano-Scale CMOSFETs)

  • 나준희;최서윤;김용구;이희덕
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2004년도 하계종합학술대회 논문집(2)
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    • pp.327-330
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    • 2004
  • It is shown that the hot carrier degradation due to enhanced hot holes trapping dominates PMOSFETs lifetime both in thin and thick devices. Moreover, it is found that in 0.13 ${\mu}m$ CMOSFET the PMOS lifetime under CHC (Channel Hot Carrier) stress is lower than the NMOSFET lifetime under DAHC (Drain Avalanche Hot Carrier) stress. Therefore. the interface trap generation due to enhanced hot hole injection will become a dominant degradation factor. In case of thick MOSFET, the degradation by hot carrier is confirmed using charge pumping current method and highly necessary to enhance overall device lifetime or circuit lifetime in upcoming nano-scale CMOS technology.

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