• Title/Summary/Keyword: transport property

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A facile chemical synthesis of a novel photo catalyst: SWCNT/titania nanocomposite

  • Paul, Rima;Kumbhakar, Pathik;Mitra, Apurba K.
    • Advances in nano research
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    • v.1 no.2
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    • pp.71-82
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    • 2013
  • A simple chemical precipitation technique is reported for the synthesis of a hybrid nanostructure of single-wall carbon nanotubes (SWCNT) and titania ($TiO_2$) nanocrystals of average size 5 nm, which may be useful as a prominent photocatalytic material with improved functionality. The synthesized hybrid structure has been characterized by transmission electron microscopy (HRTEM), energy-dispersive X-ray analysis (EDAX), powder X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. It is clearly revealed that nearly monodispersed titania nanocrystals (anatase phase) of average size 5 nm decorate the surfaces of SWCNT bundles. The UV-vis absorption study shows a blue shift of 16 nm in the absorbance peak position of the composite material compared to the unmodified SWCNTs. The photoluminescence study shows a violet-blue emission in the range of 325-500 nm with a peak emission at 400 nm. The low temperature electrical transport property of the synthesized nanomaterial has been studied between 77-300 K. The DC conductivity shows semiconductor-like characteristics with conductivity increasing sharply with temperature in the range of 175-300 K. Such nanocomposites may find wide applications as improved photocatalyst due to transfer of photo-ejected electrons from $TiO_2$ to SWCNT, thus reducing recombination, with the SWCNT scaffold providing a firm and better positioning of the catalytic material.

Role of edge patterning and metal contact for extremely low contact resistance on graphene

  • Jo, Seo-Hyeon;Park, Hyung-Youl;Park, Jin-Hong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.294.2-294.2
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    • 2016
  • Graphene, a sigle atomic layered structure of graphite, has drawn many scientific interests for attractive future electronics and optoelectronics beyond silicon-based technology because of its robust physical, optical, and electrical properties. But high metal-graphene contact resistance prevents the successful integration of high speed graphene devices and circuits, although pristine graphene is known to have a novel carrier transport property. Meanwhile, in the recently reported metal-graphene contact studies, there are many attempts to reduce the metal-graphene contact resistance, such as doping and one-dimensional edge contact. However, there is a lack of quantitative analysis of the edge contact scheme through variously designed patterns with different metal contact. We first investigate the effets of edge contact (metal-graphene interface) on the contact resistance in terms of edge pattern design through patterning (photolithography + plasma etching) and electral measurements. Where the contact resistance is determined using the transfer length method (TLM). Finally, we research the role of metal-kind (Palladium, Copper, and Tianium) on the contact resistance through the edge-contacted devices, eventually minimizing contact resistance down to approximately $23{\Omega}{\cdot}{\mu}m$ at room temperature (approximately $19{\Omega}{\cdot}{\mu}m$ at 100 K).

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Hot carrier induced carrier transport property on InAs nanowires

  • Kim, Taeok;Park, Sungjin;Kang, Hang-Kyu;Bae, Jungmin;Cho, M.H.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.362.1-362.1
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    • 2016
  • InAs nanowires were synthesized by a vapor-liquid-solid method with InAs powder. The composition and crystalline structure of nanowires were confirmed by energy-dispersive spectroscopy (EDS) and high resolution transmission electron microscopy (HRTEM), respectively. The thermal conduction of nanowires was investigated by the optical method using Raman spectroscopy: i.e., the local temperature on nanowire was determined by laser heating. As temperature increased, the Raman peaks are shifted to low frequency and broadened. The temperature dependent Raman scattering experiments was realized on InAs nanowires with different percentages of zinc-blende and wurtzite structure. The temperature dependence on the nanowire structure has been successfully obtained: the phonon scattering was more increased in InAs heretostructure nanowires, compared to the InAs nanowires with homostructure. The result strongly suggests that the thermal conduction can be effectively controlled by ordered interface without any decrease in electrical conduction.

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NMR-based structural characterization of transthyretin in its aggregation-prone state

  • Kim, Bokyung;Kim, Jin Hae
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.3
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    • pp.91-95
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    • 2020
  • Transthyretin (TTR) is an abundant protein in blood plasma and cerebrospinal fluid (CSF), working as a homo-tetrameric complex to transport thyroxine (T4) and a holo-retinol binding protein. TTR is well-known for its amyloidogenic property; several types of systemic amyloidosis diseases are caused by aggregation of either wild-type TTR or its variants, for which more than 100 mutations were reported to increase the amyloidogenicity of TTR. The rate-limiting step of TTR aggregation is the dissociation of a monomeric subunit from a tetrameric complex. A wide range of biochemical and biophysical techniques have been employed to elucidate the TTR aggregation processes, among which nuclear magnetic resonance (NMR) spectroscopy contributed much to characterize the structural and functional features of TTR during its aggregation processes. The present review focuses on discussing the recent advances of our understanding to the amyloidosis mechanism of TTR and to the structural features of its monomeric aggregation-prone state in solution. We expect that the present review provides novel insights to appreciate the molecular basis of TTR amyloidosis and to develop novel therapeutic strategies to treat diverse TTR-related diseases.

The Effect of the Thermal Stress on the Transport Property of Pocheon Granite (열응력이 포천화강암의 투수성에 미치는 영향)

  • Yoon, Yong-Kyun
    • Tunnel and Underground Space
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    • v.7 no.3
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    • pp.238-245
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    • 1997
  • A transient pulse methos has been used to measure the permeability of Pocheon granite pre-heated from $25^{\circ}C$ to $600^{\circ}C$ at effective pressure up to 32MPa. The permeability of whole rock ranged from 0.72 $\mu$d at 10MPa to 0.20 $\mu$d at 32MPa. The permeability of rock heated to $600^{\circ}C$ ranged from 18.07$\mu$d at 10MPa to 6.39$\mu$d at 32MPa. Confining pressure has greater effects on the rocks thermally treated to lower thermal-cycle temperatures than on the higher thermally treated rocks. The increase of permeability is most pronounced between 40$0^{\circ}C$ and $600^{\circ}C$. Below 40$0^{\circ}C$, permeability increase is expected to be associated with the formation of new cracks and widening of preexisting cracks, whereas above 40$0^{\circ}C$, permeability increase is expected to reflect widening of cracks. Using the equivalent channel model, author shows that the exponent n in the relationship relating the permebility(k) to porosity($\phi$) by k∝$$\phi$^n$ falls in the range 2.7$\leq$n$\leq$3.0.

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A STUDY ON THE FATIGUE LIFE PREDICTION OF GUIDEWAY VEHICLE COMPONENTS (안내궤도 차량 부품의 피로 수명 예측에 관한 연구)

  • Lee, Soo-Ho;Park, Tae-Won;Yoon, Ji-Won;Jeon, Yong-Ho;Jung, Sung-Pil;Park, Joong-kyung
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.997-1002
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    • 2007
  • A guideway vehicle is used in automobile, semiconductor and LCD manufacturing industries to transport products efficiently. Since the operating speed of the guideway vehicle should be increased for maximum productivity, the weight of the vehicle has to be reduced. This may cause parts in the system to fail before the life of the system. Therefore estimation of the fatigue life of the parts becomes an important problem. In this study, the fatigue life of the driving wheel in the guideway vehicle is estimated using a S-N curve. To obtain the fatigue life of a part, the S-N curve, load time history applied on a driving wheel and material property are required. The S-N curve of the driving wheel is obtained using the fatigue experiment on wheels. Load time history of the wheel is obtained from multibody dynamics analysis. To obtain the material properties of the driving wheel, which is composed of aluminum with urethane coating, a compression hardware testing has been done with the static analysis of the FE model. The fatigue life prediction using computational analysis model guarantees the safety of the vehicle at the design stage of the product.

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A Comparative Study on the Documentary Conditions of International Trade Transaction (국제무역거래에서의 서류조건에 관한 비교연구 - Incoterms(R) 2010규칙과 UCP 600규칙을 중심으로 -)

  • Sin, Jung-Sik
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
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    • v.54
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    • pp.99-122
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    • 2012
  • According to the United Nations Convention on the International Sale of Goods, the Seller must deliver the goods, hand over any documents relating to the them and transfer the property the to the goods as required by the contract, and buyer must pay the price for the goods and take delivery of them as required by the contract. In particular, the seller provides the documents is important. If the documents are discrepancies in credit, the beneficiary may not receive the payment. So It is important to study on conditions of documents in international trade. Documents provided by the seller shall be determined by express terms. If there is no agreement on the express terms, it shall be determined by the implied terms or governing law terms. In practice Seller shall provide the documents are as follows, For example, transport documents, commercial invoice, certificate of origin, insurance policy, packing list, inspection certificate etc. As stated above if it can not be determined by express terms, it is determined by the implied terms. In international trade, leading to the implied terms is incoterms(R) 2010 and UCP 600. Incoterms(R) 2010 define the seller must provide the goods and the commercial in conformity with the sales contract and any other evidence of conformity that may be required by the contract and UCP 600 are rules that apply to documentary credit. This paper, the practical utility between Incoterms(R) 2010 and UCP 600 is studied.

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A Study on Transport the Hydrological Property of Debris Accumulation at Flood (홍수시 유송잡물 이동에 관한 수리학적 특성연구)

  • Oh, Chae-Yeon;Jun, Kye-Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.1747-1752
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    • 2008
  • 강원도 산간지역에 위치한 소하천의 경우 유송잡물 및 토석류에 의하여 교량이 파괴되거나, 통수능이 작아져 댐의 역할을 하게 됨으로 인해 교량 상류지역이 침수피해를 입는 경우가 많이 발생하고 있으며 강원도 산간지역에 설치된 소규모 수공구조물들은 교량의 경우 교각이 많아 경간장이 짧고, 교량 상판이 제방고 보다 낮게 설치되어 있는 등 하천흐름에 장애를 주는 많은 요인들을 내재하고 있어 홍수시 하천유량의 증가에 따른 하천흐름 해석, 유송잡물의 발생원인 및 수공구조물에 미치는 영향들에 관한 판단기준 마련이 시급한 실정이다. 유송잡물의 발생경로는 대부분 산지계류에서 집중호우시 산사태발생에 따른 유목과 토석류 발생이 주원인이 된다. 또한 유송잡물은 큰 홍수시 고수위가 오랜 시간동안 지속될 경우 가장 많이 발생하는데 이때 발생한 유송잡물은 개별적으로 이송되고 일반적으로 하천의 중앙으로 이동하는 경향이 있으며 수심이 깊고 유속이 빠른 곳에 집중된다. 또한 유송잡물은 큰 홍수시 고수위가 오랜 시간동안 지속될 경우 가장 많이 발생하는데 이때 발생한 유송잡물은 개별적으로 이송되고 일반적으로 하천의 중앙으로 이동하는 경향이 있으며 수심이 깊고 유속이 빠른 곳에 집중된다. 본 연구에서는 홍수시 유송잡물 이동특성에 대한 국내 외 문헌조사, 현장피해사례조사 및 현장모니터링 조사를 실시하고 1차원 모형인 HEC-RAS와 2차원 모형인 RMA-2를 이용하여 수리모델링 분석에 따른 수치모의를 실시하고 분석하였다.

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Hydraulic Property and Solute Breakthrough from Salt Accumulated Soils under Various Head Pressures

  • Lee, Sanghun;Chung, Doug-Young;Hwang, Seon-Woong;Lee, Kyeong-Bo;Yang, Chang-Hyu;Kim, Hong-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.717-724
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    • 2012
  • Salt accumulated soil should be reclaimed to lower salt level for crop production. This study was carried out to investigate the characteristics of water flow and transport of mono and divalent solutes on salt accumulated soils with different head pressures. Saturated hydraulic conductivity was measured by constant and falling head methods with maintaining different head pressures. Saturated hydraulic conductivity was influenced by bulk density and organic matter contents in soils, but it had different elusion patterns between saline and sodic soil. While the quantity of water necessary for reclamation could be varies with soil type, it was considered that the supply of one pore volume of water was affordable and economic. Additional head pressure significantly increased the volume of leachate at a given time and it was more effective at low organic matter soils. The results indicate that additional head pressure would be one of the best irrigation practices on desalination method for salt accumulated soils.

Growth of superconducting $MgB_2$ fibers for wire applications

  • Kim J. H.;Yoon H. R.;Jo W.
    • Progress in Superconductivity and Cryogenics
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    • v.7 no.4
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    • pp.1-3
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    • 2005
  • Superconducting $MgB_2$ fibers are in-situ grown by a diffusion method. The fibers are prepared by exposing B filaments to Mg vapor inside a folded Ta foil over a wide range of temperature and growth time. The materials are sealed inside a quartz tube by gas welding. The as - grown fibers are characterized by scanning electron microscopy and energy dispersive x - ray analysis. The fibers have a diameter of about $110{\mu}m$. Surface morphology of the fibers looks dependent on growth temperature and mixing ratio of Mg and B. Radial distribution of Mg ions into B is observed and analyzed over the cross - sectional area. Transport properties of the $MgB_2$ fibers are examined by a physical property measurement system. The $MgB_2$ fibers grown at $900^{\circ}C$ for 2 hours show a superconducting transition at 39.8K with ${\Delta}T_c<$ 2.0 K. Resistance at room temperature $MgB_2$ is 3.745 $\Omega$ and residual resistivity ratio (RRR) is estimated as 4.723.