• Title/Summary/Keyword: transport property

Search Result 321, Processing Time 0.031 seconds

Fabrication and Mechanical Properties of High-strength Porous Supports for High Temperature Oxygen Transport Membrane (고온 산소분리막용 고강도 다공성 지지체 제조 및 기계적 특성 연구)

  • Park, Geum Sook;Seong, Young-Hoon;Yu, Ji Haeng;Woo, Sang Kuk;Han, Moon Hee
    • Journal of the Korean Ceramic Society
    • /
    • v.50 no.6
    • /
    • pp.423-428
    • /
    • 2013
  • Porous YSZ ceramics are fabricated using 3 mol% yittria-stabilized zirconia (3YSZ) and NiO with different particlesizes (0.6 and 7 ${\mu}m$). Nickel oxide (NiO) is added to the YSZ powder as a pore former with different amounts(40, 50, and 60 vol%) and at different sintering temperatures (1350 and $1400^{\circ}C$) are applied in order to evaluate the temperature effects on the pore and mechanical properties. Heat treatment is conducted after sintering at $700^{\circ}C$ in $H_2$ for the NiO reduction process; then, Ni is removed using a $HNO_3$ etchant solution. According to the NiO contentand sintering temperatures, 41-67% porous YSZ ceramic is obtained and the flexural strength increases, while the porosity decreases with an increasing sintering temperature. The optimum flexural strength ($136.5{\pm}13.4MPa$) and porosity (47%) for oxygen transport porous YSZ membrane can be obtained with 40 vol% of 7 ${\mu}m$ NiO particle at a sintering temperature of $1350^{\circ}C$.

Non-volatile Molecular Memory using Nano-interfaced Organic Molecules in the Organic Field Effect Transistor

  • Lee, Hyo-Young
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.02a
    • /
    • pp.31-32
    • /
    • 2010
  • In our previous reports [1-3], electron transport for the switching and memory devices using alkyl thiol-tethered Ru-terpyridine complex compounds with metal-insulator-metal crossbar structure has been presented. On the other hand, among organic memory devices, a memory based on the OFET is attractive because of its nondestructive readout and single transistor applications. Several attempts at nonvolatile organic memories involve electrets, which are chargeable dielectrics. However, these devices still do not sufficiently satisfy the criteria demanded in order to compete with other types of memory devices, and the electrets are generally limited to polymer materials. Until now, there is no report on nonvolatile organic electrets using nano-interfaced organic monomer layer as a dielectric material even though the use of organic monomer materials become important for the development of molecularly interfaced memory and logic elements. Furthermore, to increase a retention time for the nonvolatile organic memory device as well as to understand an intrinsic memory property, a molecular design of the organic materials is also getting important issue. In this presentation, we report on the OFET memory device built on a silicon wafer and based on films of pentacene and a SiO2 gate insulator that are separated by organic molecules which act as a gate dielectric. We proposed push-pull organic molecules (PPOM) containing triarylamine asan electron donating group (EDG), thiophene as a spacer, and malononitrile as an electron withdrawing group (EWG). The PPOM were designed to control charge transport by differences of the dihedral angles induced by a steric hindrance effect of side chainswithin the molecules. Therefore, we expect that these PPOM with potential energy barrier can save the charges which are transported to the nano-interface between the semiconductor and organic molecules used as the dielectrics. Finally, we also expect that the charges can be contributed to the memory capacity of the memory OFET device.[4]

  • PDF

Active Materials for Energy Conversion and Storage Applications of ALD

  • Sin, Hyeon-Jeong
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.75.2-75.2
    • /
    • 2013
  • Atomic layer deposition (ALD), utilizing self-limiting surface reactions, could offer promising perspectives for future efficient energy conversion devices. The capabilities of ALD for surface/interface modification and construction of novel architectures with sub-nanometer precision and exceptional conformality over high aspect ratio make it more valuable than any other deposition methods in nanoscale science and technology. In the context, a variety of researches on fabrication of active materials for energy conversion applications by ALD are emerging. Among those materials, one-dimensional nanotubular titanium dioxide, providing not only high specific surface area but also efficient carrier transport pathway, is a class of the most intensively explored materials for energy conversion systems, such as photovoltaic cells and photo/electrochemical devices. The monodisperse, stoichiometric, anatase, TiO2 nanotubes with smooth surface morphology and controlled wall thickness were fabricated via low-temperature template-directed ALD followed by subsequent annealing. The ALD-grown, anatase, TiO2 nanotubes in alumina template show unusual crystal growth behavior which allows to form remarkably large grains along axial direction over certain wall thickness. We also fabricated dye-sensitized solar cells (DSCs) introducing our anatase TiO2 nanotubes as photoanodes, and studied the effect of blocking layer, TiO2 thin films formed by ALD, on overall device efficiency. The photon convertsion efficiency ~7% were measured for our TiO2 nanotubebased DSCs with blocking layers, which is ~1% higher than ones without blocking layer. We also performed open circuit voltage decay measurement to estimate recombination rate in our cells, which is 3 times longer than conventional nanoparticulate photoanodes. The high efficiency of our ALD-grown, anatase, TiO2 nanotube-based DSCs may be attributed to both enhanced charge transport property of our TiO2 nanotubes photoanode and the suppression of recombination at the interface between transparent conducting electrode and iodine electrolytes by blocking layer.

  • PDF

Time Synchronization Technique for GNSS Jamming Monitoring Network System (GNSS 재밍 신호 모니터링 네트워크 시스템을 위한 독립된 GNSS 수신기 간 시각 동기화 기법)

  • Jin, Gwon gyu;Song, Young jin;Won, Jong hoon
    • The Journal of The Korea Institute of Intelligent Transport Systems
    • /
    • v.20 no.3
    • /
    • pp.74-85
    • /
    • 2021
  • Global Navigation Satellite System (GNSS) receivers are intrinsically vulnerable to radio frequency jamming signals due to the fundamental property of radio navigation systems. A GNSS jamming monitoring system that is capable of jamming detection, classification and localization is essential for infrastructure for autonomous driving systems. For these 3 functionalities, a GNSS jamming monitoring network consisting of a multiple of low-cost GNSS receivers distributed in a certain area is needed, and the precise time synchronizaion between multiple independent GNSS receivers in the network is an essential element. This paper presents a precise time synchronization method based on the direct use of Time Difference of Arrival (TDOA) technique in signal domain. A block interpolation method is additionally incorporated into the method in order to maintain the precision of time synchronization even with the relatively low sampling rate of the received signals for computational efficiency. The feasibility of the proposed approach is verified in the numerical simualtions.

Crossover from weak anti-localization to weak localization in inkjet-printed Ti3C2Tx MXene thin-film

  • Jin, Mi-Jin;Um, Doo-Seung;Ogbeide, Osarenkhoe;Kim, Chang-Il;Yoo, Jung-Woo;Robinson, J. W. A.
    • Advances in nano research
    • /
    • v.13 no.3
    • /
    • pp.259-267
    • /
    • 2022
  • Two-dimensional (2D) transition metal carbides/nitrides or "MXenes" belong to a diverse-class of layered compounds, which offer composition- and electric-field-tunable electrical and physical properties. Although the majority of the MXenes, including Ti3C2Tx, are metallic, they typically show semiconductor-like behaviour in their percolated thin-film structure; this is also the most common structure used for fundamental studies and prototype device development of MXene. Magnetoconductance studies of thin-film MXenes are central to understanding their electronic transport properties and charge carrier dynamics, and also to evaluate their potential for spin-tronics and magnetoelectronics. Since MXenes are produced through solution processing, it is desirable to develop deposition strategies such as inkjet-printing to enable scale-up production with intricate structures/networks. Here, we systematically investigate the extrinsic negative magnetoconductance of inkjetprinted Ti3C2Tx MXene thin-films and report a crossover from weak anti-localization (WAL) to weak localization (WL) near 2.5K. The crossover from WAL to WL is consistent with strong, extrinsic, spin-orbit coupling, a key property for active control of spin currents in spin-orbitronic devices. From WAL/WL magnetoconductance analysis, we estimate that the printed MXene thin-film has a spin orbit coupling field of up to 0.84 T at 1.9 K. Our results and analyses offer a deeper understanding into microscopic charge carrier transport in Ti3C2Tx, revealing promising properties for printed, flexible, electronic and spinorbitronic device applications.

Improved charge balance in quantum dot light-emitting diodes using self-assembled monolayer (자기조립단분자막을 이용한 양자점 발광다이오드의 전하 균형도 개선)

  • Sangwook Park;Woon Ho Jung;Yeyun Bae;Jaehoon Lim;Jeongkyun Roh
    • Journal of IKEEE
    • /
    • v.27 no.1
    • /
    • pp.30-37
    • /
    • 2023
  • To improve the efficiency and stability of colloidal quantum dot light-emitting diodes (QD-LEDs), it is essential to achieve charge balance within the QD emissive layer. Zinc oxide (ZnO) is widely used for constructing an electron transport layer in the state-of-the-art QD-LEDs, but spontaneous electron injection from ZnO often results in excessive electrons in QDs that significantly deteriorate the performance of QD-LEDs. In this study, we demonstrated the improved performance of QD-LEDs by modifying the electron injection property of ZnO with self-assembled monolayer (SAM)-treatment. As a result of improved charge balance, the external quantum efficiency and maximum luminance of QD-LEDs with SAM-treatment were improved by 25% and 200%, respectively, compared to the devices without SAM-treatment.

Reverse Engineering Procedure of Metal Brake Pad for Part 25 Aircraft (수송류 항공기용 금속계 제동패드의 역설계 절차)

  • Min-ji Kim;Kyung-il Kim;Kyung-taek Kim
    • Journal of Advanced Navigation Technology
    • /
    • v.27 no.5
    • /
    • pp.621-628
    • /
    • 2023
  • This study derived a reverse engineering procedure for verifying the design identity of original parts and developed parts for PMA(Parts Manufacturer Approval) and STC(Supplemental Type Certificate) of metal brake pads for transport aircraft, which are critical parts among aircraft parts and equipment. In Korea, the regulations for reverse engineering procedures are regulated by the Parts Manufacturer Approval Guidelines, and in the United States, AC No. 21. 303-4. In the reverse engineering for the brake pad, the detailed procedures for each component were determined by selecting verification test items to confirm identity based on sample quantity, dimensional tolerance, mechanical property measurement, material, weight and volume characteristics for each component. In addition, as a result of analyzing the regulation of Korea and United States, in the case of Korea, it is necessary to establish technical standards for braking systems for transport aircraft and regulations related to flight tests.

A Comparative Review on Civil Money Penalties in Aviation Law (항공 과징금 제도의 비교법적 검토)

  • Lee, Chang-Jae
    • The Korean Journal of Air & Space Law and Policy
    • /
    • v.34 no.1
    • /
    • pp.3-38
    • /
    • 2019
  • In 1984, Congress enacted a new measure of administrative sanctions which is a civil money penalty program for violations of Aviation Act and its implementing regulations. This civil money penalty system has been in operations in lieu of suspending or revoking certificates issued by Korean government, Ministry of Land, Infrastructure, and Transport. According to the rules of Aviation Business Act or Aviation Safety Act, where the Minister of Land, Infrastructure and Transport should order an air carrier to suspend operation because of her violation under certain rules, in which case the suspension of operation is likely to cause serious inconvenience to consumers of air transport services or to harm public interest, the Minister of the department may impose an administrative monetary penalty in lieu of the suspension of operation. In this regard, airline related civil money penalties are somewhat different from those of fair trade, which is the origin of the money penalties system in Korea. Civil money penalties in the field of fair trade are imposed on executive duty violations that undermine the value of the market economy order, and focus on reimbursement of profits due to violations and compensation for unfair spending by consumers. However, in the aviation sector, breach of duty by a business operator does not simply cause the property loss of the public, but it has a direct impact on life or property of the public. In this respect, aviation penalties are more likely to be administrative sanctions or punitive measures than refunds of unfair benefits, compared to penalties in the field of fair trade. In general, civil money penalties have been highly preferred as administrative sanctions because they are subject to investigations by administrative experts and thus, efficiency can be ensured and execution is quicker than judicial procedures. Moreover, in Korea, because punitive civil damages cannot awarded by the courts, the imposition of civil money penalties is recognized as a means of realizing social justice by recognizing the legal feelings of the people. However, civil money penalties are administrative sanctions, and in terms of effectiveness, they are similar to criminal fines, which are a form of punishment. Inadequate legislation and operation of penalties imposition may cause damage to the value of Constitution. Under the above recognition, this paper has been described for the purpose of identifying the present status of the civil money penalties imposition system and operating status in the area of air transport under the laws and regulations in Korea. Especially, this paper was focused on exploring the problem and improvement direction of Korean system through the comparative study with foreign laws and regulations.

Wearing Performance of Garment for Emotional Knitted Fabrics Made of PTT/Tencel/Cotton MVS Blended Yarns (II) (PTT/Tencel/Cotton 친환경 MVS 혼방사 편성물의 물성에 관한 연구 (II))

  • Kim, Hyun Ah
    • Fashion & Textile Research Journal
    • /
    • v.17 no.6
    • /
    • pp.1020-1029
    • /
    • 2015
  • This paper investigated the wearing performance of knitted fabrics made of air vortex yarns using PTT/tencel/cotton fibres in comparison with ring and compact yarns for emotional garment. Wicking property of knitted fabric made of MVS yarns was worse than those by ring and compact yarns, however, drying property of knitted fabric made of MVS yarns was better than those by ring and compact yarns, which was explained as more water vapor transport due to larger openness between fibres in the MVS yarns than those in the ring and compact yarns. Thermal conductivity of knitted fabric made of MVS was lower than those of ring and compact yarns and maximum heat flow(Qmax) at the transient state of MVS knitted fabric was lower than those of ring and compact yarns, which may be attributed to MVS yarn structure that has parallel fibres in the core part of the yarn and fasciated fibre bundles on the sheath part with roughness on the yarn surface. However, pilling of MVS knitted fabric was better than those by ring and compact yarns, which was caused by less and shorter hairy fibres protruded from MVS yarn surface than those of ring and compact yarns. It was observed that tactile hand of MVS yarn knitted fabrics was stiffer than those of ring and compact yarns knitted fabrics. It was explained by low extensibility and compressibility and high bending and shear rigidities of the MVS yarn knitted fabrics, which resulted in bad wearing performance of MVS knitted fabric.

Bonding Properties of Steel-reinforced Polymer Cement Mortar Evaluated by Pull-off Test and FEM Modeling (폴리머 시멘트 모르타르의 철근부착력 평가를 위한 인발실험과 모델링)

  • Park, Dong-Cheon;Yoneda, Nobutosi;Cho, Bong-Suk
    • Journal of the Korea Institute of Building Construction
    • /
    • v.14 no.3
    • /
    • pp.216-222
    • /
    • 2014
  • Chloride attack to reinforced concrete structures located in seaside can cause a serious problem of durability and maintenance during the service life. Corrosion of reinforced steel bars in concrete decreases the bond strength and finally causes the detachment of concrete cover. Polymer cement mortar is usually adopted to repair the deteriorated RC structures because of its strong bonding property. The recovered load-carrying capacity after the repair was simulated by non-linear FEM analysis. The properties of concrete, repairing materials, bonding materials and reinforced bar were used as input data. Four types of redispersible polymer powders were used as components of polymer cement mortar. Pull-off tests were carried out to examine the bond properties such as rigidity and strength. Effects of a corrosion inhibitor and the loss of reinforced bars due to the corrosion were also considered in this study. FEM modeling and analysis were conducted to propose the universal model. Physical bonding in the relationship between repair materials and steel reinforced bar is more dominant than chemical bonding.