• Title/Summary/Keyword: transport property

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An Effect of Ethanol on Polypyrrole-Glucose Oxidase Enzyme Electrode (Polypyrrole-Glucose oxidase 효소전극의 Ethanol 첨가효과)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.147-150
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    • 1999
  • In the case of immobilizing of glucose oxidase in organic polymer using electrosynthesis, the glucose oxidase obstructs charge transfer and mass transport during the film growth. This may lead to short chained polymer and/or make charge-coupling weak between the glucose oxidase and the backbone of the polymer. That is mainly due to insulating property and net chain of the glucose oxidase. Since being the case, it is useless to increase in amount of glucose oxidase more than reasonable in the synthetic solution. We establish qualitatively that amount of immobilization can be improved by adding a little ethanol in the synthetic solution. As ethanol was added by 0.1 rnol dm" in the synthetic solution, Michaelis-Menten constants of the resulting enzyme electrode decreased from 30.7 mmol $dm^{-3}$ to about 2 mmol $dm^{-3}$. That suggests increase in affinity of the enzyme electrode for glucose and in amount of the immobilized enzyme.zyme.

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Pervaporation Separation Properties of Chlorinated Hydrocarbons through Poly(1-trimethylsilyl-1-propyne) Modified Memebrane (Poly(1-trimethylsilyl-1-propyne) Modified Memebrane을 통한 유기염소계화합물의 투과증발 분리 특성)

  • 백귀찬;변인섭;이용희;이용택
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.66-69
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    • 1998
  • 1. 서론 : 본 연구는 시간이 경과함에 따라 free volume감소로 나타나는 PTMSP[Poly(1-trimethylsilyl-1-propyne)] memebrane의 pysical aging을 늦추거나 방지할 목적으로 PTMSP polymer를 합성하여 여기에 hydroxy-terminated PDMS를 graft시켜 PTMSP/PDMS graft copolymer를 제조하였다. 용매증발법에 의해 PTMSP memebrane 및 PTMSP/PDMS graft copolymer memebrane을 제막한 후 PTMSP막의 물리적 노화를 관찰하기 위한 시점에서 조업시간에 따른 이들 막의 transport property을 살펴 보았다. 또한 이들 polymer을 사용하여 0.5 wt%의 희박 dope solution을 제조한 후 여기에 상전환법에 의해 제조된 비대칭 PEI(polyetherimide)지지막을 dip-doping시켜 PTMSP-PEI, PTMSP/PDMS-PEI 복합막을 제조하여 상기의 두 막과 투과증발 특성을 상호 비교하여 보았다. 그리고 객관적 비교 자료를 얻을 목적으로 PDMS막과 PDMS-PEI 복합막을 각각 제막하여 동일조건에서 실험을 수행하였다. 따라서 본 연구는 수중에 미량 용해된 chloroform, trichloroethylene, perchlororthylene, 1,1,1-trichloroethane 등의 유기염소계화합물 제거 실험을 통해 PTMSP, PTMSP/PDMS 등의 dense membrane과 asymmetric composite membrane 사이의 상관관계 및 이들 막들의 투과특성을 서로 비교, 분석하는데 목적을 두었다.

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Prediction of Outflow Hydrograph caused by Landslide Dam Failure by Overtopping

  • Do, XuanKhanh;Kim, Minseok;Nguyen, H.P.T;Jung, Kwansue
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.196-196
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    • 2016
  • Landslide dam failure presents as a severe natural disaster due to its adverse impact to people and property. If the landslide dams failed, the discharge of a huge volume of both water and sediment could result in a catastrophic flood in the downstream area. In most of previous studies, breaching process used to be considered as a constructed dam, rather than as a landslide dam. Their erosion rate was assumed to relate to discharge by a sediment transport equation. However, during surface erosion of landslide dam, the sediment transportation regime is greatly dependent on the slope surface and the sediment concentration in the flow. This study aims to accurately simulate the outflow hydrograph caused by landslide dam by overtopping through a 2D surface flow erosion/deposition model. The lateral erosion velocity in this model was presented as a function of the shear stress on the side wall. The simulated results were then compared and it was coherent with the results obtained from the experiments.

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Hazard Prevention using Multi-Level Debris Flow Barriers (다단식(다단식) 토석류 방호책을 이용한 재해방지 시스템)

  • Lee, Sung-Uk;Choi, Seung-Il;Choi, Yu-Kyung
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.815-829
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    • 2008
  • Debris flows are a natural hazard which looks like a combination of flood, land and rock slide. Large rainfall in July 2006 produced several large scale debris flows and many small debris flows that resulted in loss of life and considerable property and railway damage, as was widely reported in the national media. The hazard "debris flow" is still insufficiently researched. Furthermore debris flows are very hard to predict. Flexible Ring net barriers are multi-functional mitigation devices commonly applied to rock fall or floating wood protection in floods, snow avalanches and also mud flows or granular debris flows, if properly dimensioned for the process or processes for which they are intended. Overtopping of the barriers by debris flows and sediment transport is possible, supporting the design concept that a series of barriers may be used to stop volumes of debris larger than are possible using only one barrier. The future for these barrier concepts looks promising because these barriers represent the state of art for such applications and are superior to many other available options.

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Spin-Motive Force Caused by Vortex Gyration in a Circular Nanodisk with Holes

  • Moon, Jung-Hwan;Lee, Kyung-Jin
    • Journal of Magnetics
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    • v.16 no.1
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    • pp.6-9
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    • 2011
  • Spin-motive force has drawn attention because it contains a fundamental physical property. Spin-motive force creates effective electric and magnetic fields in moving magnetization; a vortex is a plausible system for observing the spin-motive force because of the abrupt profile of magnetization. However, the time-averaged value of a spin-motive force becomes zero when a vortex core undergoes gyroscopic motion. By means of micromagnetic simulation, we demonstrates that a non-zero time-averaged electric field induced by spin-motive force under certain conditions. We propose an experimental method of detecting spin-motive force that provides a better understanding of spin transport in ferromagnetic system.

In-situ XPS Study of Core-levels of ZnO Thin Films at the Interface with Graphene/Cu

  • Choi, Jinsung;Jung, Ranju
    • Journal of the Korean Physical Society
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    • v.73 no.10
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    • pp.1546-1549
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    • 2018
  • We have investigated core-levels of ZnO thin films at the interface with the graphene on Cu foil using in-situ X-ray Photoelectron Spectroscopy (XPS). Spectral evolution of C 1s, Zn 2p, and O 1s are observed in real time during RF sputtering deposition. We found binding energy (BE) shifts of Zn 2p and 'Zn-O' state of O 1s depending on ZnO film thickness. Core-levels BE shifts of ZnO will be discussed on the basis of electron transfer at the interface and it may have an important role in the electronic transport property of the ZnO/graphene-based electronic device.

P-EXTREMAL FUNCTIONS AND BERNSTEIN-MARKOV PROPERTIES ASSOCIATED TO COMPACT SETS IN ℝd

  • Anh, Hoang Thieu;Chi, Kieu Phuong;Dieu, Nguyen Quang;Long, Tang Van
    • Bulletin of the Korean Mathematical Society
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    • v.59 no.4
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    • pp.811-825
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    • 2022
  • Given a compact subset P ⊂ (ℝ+)d and a compact set K in ℂd. We concern with the Bernstein-Markov properties of the triple (P, K, 𝜇) where 𝜇 is a finite positive Borel measure with compact support K. Our approach uses (global) P-extremal functions which is inspired by the classical case (when P = Σ the unit simplex) in [7].

Variation of the Transport Property in Lap-Jointed YBCO Coated Conductor Tapes with Tension and Bending Deformation

  • Dizon, John Ryan C.;Bonifacio, Rolly;Park, Sung-Taek;Shin, Hyung-Seop
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.4
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    • pp.11-15
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    • 2007
  • In practical applications of HTS tapes for electric devices such as coils and power cables, the jointing of HTS tapes is inevitable even though long length tapes have recently been achieved. The critical current, $I_c$, degradation behaviors with tensile and bending deformations were investigated in commercially available YBCO coated conductor tapes. When the V-I relationship was measured at the jointed section of the lap-jointed YBCO CC tapes, the resistance at the joint decreased with increasing joint length. The critical load for 95% $I_c$ retention were determined for the IBAD and RABiTS YBCO tapes and they were 175 and 355N, respectively. Fracture occurred at the unjointed part which represents strong copper lamination and solder jointing. The electro-mechanical properties of lap-jointed CC tapes depended on the properties of single tapes. The V-I behavior under bending strain was similar with the tensile case.

Passivation effect on large volume CdZnTe crystals

  • B. Park;Y. Kim;J. Seo;J. Byun;K. Kim
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4620-4624
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    • 2022
  • Several cadmium zinc telluride (CZT) crystals were fabricated into radiation detectors using methods that included slicing, dicing, lapping, polishing, and chemical etching. A wet passivation with sodium hypochlorite (NaOCl) was then carried out on the Br-etched detectors. The Te-rich layer on the CZT surface was successfully compensated to the Te oxide layer, which was analyzed with X-ray photoelectron spectroscopy data of both a Br-etched crystal and a passivated CZT crystals. We confirmed that passivation with NaOCl improved the transport property by analyzing the mobility-lifetime product and surface recombination velocity. The electrical and spectroscopic properties of large volume detectors were compared before and after passivation, and then the detectors were observed for a month. Both bar and quasi-hemispherical detectors show an enhancement in performance after passivation. Thus, we could identify the effect of NaOCl passivation on large volume CZT detectors.

Conductance of ultrathin Pt films

  • Chang-Jin Yun;Jiho Kim;Mingu Kim;Dongseuk Kim;Chanyong Hwang;B. C. Lee;Kungwon Rhie
    • Journal of the Korean Physical Society
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    • v.80
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    • pp.415-419
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    • 2022
  • Ultrathin Pt less than 10 nm thick is widely used in spintronic devices including spin Hall current. The transport property and underlying physics however have not been much studied for ultrathin films. Classical theories are analyzed to find that they cannot be applied to ultrathin films. Quantum mechanical size effect theory was applied to analyze Pt and Pt/CoFeB film sets. The quantum mechanical theory explained the conductance variation for both films along with roughness remarkably well.