• 제목/요약/키워드: transition element

검색결과 347건 처리시간 0.025초

실리카계 유리의 희토류 이온 분광특성 연구 (Spectroscopic Studies of Rare-earth Elements in Silicate Glasses)

  • 윤윤열;김태삼;길대섭;황연;정헌생
    • 한국재료학회지
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    • 제8권3호
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    • pp.219-223
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    • 1998
  • 실리카 유리에 3가 이온 희토류 원소인 $Eu^{3+}$, $Sm^{3+}$, $Tb^{3+}$를 첨가한 경우의 분광특성 변화를 연구하였다. 유리시료의 분광특성은 회토류를 첨가한 경우의 파장영역에 따른 흡수 및 발광파장의 변화를 관찰하였으며, 희토류 함량을 1-10wt%까지 첨가하여 함량변화에 따른 형광세기 변화를 조사하였다. 형광특성 측정 결과 희토류 원소의 함량이 10wt%까지 형광세기는 함량에 비례하여 계속 증가하였으며, 시료의 형광특성을 상온에서 관측한 결과 400-500nm사이에서 가장 많은 빛을 흡수하여 가시광선 영역인 600nm부근에서 방출되는 형광세기가 가장 크게 나타났다. 이때 방출되는 희토류 원소들은 $Eu^{3+}$의 경우 $^{5}D_{o}$ -> ^{7}F$. $Sm^{3+}$$4F_{5/2}$ -> $^{6}H$, $Tb^{3+}$$^{5}D_{4}$ -> ^{7}F$의 전이임일 알 수 있었다.

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Fe-28at.%Al 합금의 미세조직과 기계적 성질에 미치는 Cr, Mo 및 B의 영향 (Effects of Cr, Mo an B additions on the microstructure and mechanical properties of Fe-28at.%Al alloys)

  • 최답천;이연오;김관휴;박은식;이호종
    • 한국주조공학회지
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    • 제15권5호
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    • pp.469-476
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    • 1995
  • The effects of Cr, Mo or B additions were investigated on $B2{\leftrightarrow}DO_3$ structural transition temperature $(T_C)$ and mechanical properties of Fe-28at.%Al. The raw materials were arc-melted in vacuum and then subjected to the following heat-treatments to maximize the $DO_3$ ordered structure : $1000^{\circ}C/7days$, slowly cooled to $500^{\circ}C$ and then held for 5 days. In the effect on the grain refinment, the addition of alloying element B was the most effective. The addition of Cr or Mo had little effect. When 1at.%Mo was added, $T_c$ increase about $30^{\circ}C$, but Cr had a very little effect on $T_c$. On the contrary, when B was added, $T_c$ was apt to come down minutely. In the additional effect of alloying element on the mechanical properties, Cr was apt to decrease the microvickers hardness and yield strength, Mo and B didn't have much effect. In the case of compressure strength test, the effect of the environment on the yield strength was contrary to the result of the tensile strength test.

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증분형(增分形) 유한요소법(有限要素法)에 의한 축대칭(軸對稱) Shell구조(構造)의 좌굴해석(挫屈解析) (Buckling Analysis of Axisymmetric Shells by Incremental Finite Element Mothod)

  • 김재복;김창렬
    • 대한조선학회지
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    • 제22권1호
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    • pp.21-30
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    • 1985
  • This paper deals whth the buckling as well as postbuckling analysis of axisymmertric shells taking the initial deflection effects into account. Incremental equilibrium equations, based on the principle of virtual work, were derived by the finite element method, the successive step-by-step Newton-Raphson iterative technique was adopted. To define the transition pattern of postbuckling behavior from the prebuckling state more accurately, a simple solution method was developed, i.e. the critical load was calculated by the load extrapolation method with the determinant of tangent stiffness matrix and the equilibrium configuration in the immediate postbuckling stage was obtained by perturbation scheme and eigenvalue analysis. Degenerated isoparametric shell elements were used to analyse the axisymmetric shell of revolution. And by the method developed in this paper, the computer program applicable to the nonlinear analysis of both thin and moderately thick shells was constructed. To verify the capabilities and accuracies of the present solution method, the computed results were compared with the results of analytical solutions. These results coincided fairly well in both the small deflection and large deflection ranges. Various numerical analyses were done to show the effect of initial deflection and shape of shells on buckling load and postbuckling behavior. Futhermore, corrected directions of applied loads at every increment steps were used to determine the actual effects of large deflection in non-conservative load systems such as hydrostatic pressure load. The following conclusions can be obtained. (1) The method described in this paper was found to be both economic and effective in calculating buckling load and postbuckling behavior of shell structure. (2) Buckling and postbuckling behavior of spherical caps is critically dependent upon their geometric configuration, i.e. the shape of spherical cap and quantities of the initial deflection. (3) In the analysis of large deflection problems of shells by the incremental method, corrections of the applied load directions are needed at every incremental step to compensate the follower force effects.

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반도체 봉지수지의 파괴 인성치 측정 및 패키지 적용 (Fracture Toughness Measurement of the Semiconductor Encapsulant EMC and It's Application to Package)

  • 김경섭;신영의;장의구
    • E2M - 전기 전자와 첨단 소재
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    • 제10권6호
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    • pp.519-527
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    • 1997
  • The micro crack was occurred where the stress concentrated by the thermal stress which was induced during the cooling period after molding process or by the various reliability tests. In order to estimate the possibility of development from inside micro crack to outside fracture, the fracture toughness of EMC should be measured under the various applicable condition. But study was conducted very rarely for the above area. In order to provide a was to decide the fracture resistance of EMC (Epoxy Molding Compound) of plastic package which is produced by using transfer molding method, measuring fracture is studied. The specimens were made with various EMC material. The diverse combination of test conditions, such as different temperature, temperature /humidity conditions, different filler shapes, and post cure treatment, were tried to examine the effects of environmental condition on the fracture toughness. This study proposed a way which could improve the reliability of LOC(Lead On Chip) type package by comparing the measured $J_{IC}$ of EMC and the calculated J-integral value from FEM(Finite Element Method). The measured $K_{IC}$ value of EMC above glass transition temperature dropped sharply as the temperature increased. The $K_{IC}$ was observed to be higher before the post cure treatment than after the post cure treatment. The change of $J_{IC}$ was significant by time change. J-integral was calculated to have maximum value the angle of the direction of fracture at the lead tip was 0 degree in SOJ package and -30 degree in TSOP package. The results FEM simulation were well agreed with the results of measurement within 5% tolerance. The package crack was proved to be affected more by the structure than by the composing material of package. The structure and the composing material are the variables to reduce the package crack.ack.

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압입축에 발생하는 프레팅 마모가 피로균열 발생 위치에 미치는 영향 (The Effect of Fretting Wear on Fatigue Crack Initiation Site of Press-fitted Shaft)

  • 이동형;권석진;최재붕;김영진
    • 한국철도학회논문집
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    • 제10권5호
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    • pp.546-553
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    • 2007
  • 본 연구는 압입축에 프레팅이 발생할 경우 프레팅 마모에 의한 접촉형상의 변화가 접촉응력의 분포, 균열발생 위치에 미치는 영향을 분석하고자 하였다. 압입축의 프레팅 피로실험시 측정한 접촉면의 프로파일을 이용하여 유한요소 해석을 수행하고 피로 사이클별 마모형상 변화에 따른 접촉면의 응력 변화를 분석하였다. 접촉면의 응력 해석결과를 이용하여 프레팅 피로손상 파라미터와 다축 피로이론를 적용하여 마모에 따른 균열발생위치의 변화를 해석하고 실험과 비교, 분석하였다. 프레팅 마모에 의해 접촉 끝단의 응력집중은 초기에 급격하게 감소하며, 마모가 진행될수록 응력집중의 위치는 접촉끝단에서 안쪽으로 이동한다. 따라서 프레팅 마모에 의한 접촉응력의 변화가 균열발생 위치의 변차와 다중균열발생의 주요원인임을 명확히 하였다.

A comprehensively overall track-bridge interaction study on multi-span simply supported beam bridges with longitudinal continuous ballastless slab track

  • Su, Miao;Yang, Yiyun;Pan, Rensheng
    • Structural Engineering and Mechanics
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    • 제78권2호
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    • pp.163-174
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    • 2021
  • Track-bridge interaction has become an essential part in the design of bridges and rails in terms of modern railways. As a unique ballastless slab track, the longitudinal continuous slab track (LCST) or referred to as the China railway track system Type-II (CRTS II) slab track, demonstrates a complex force mechanism. Therefore, a comprehensive track-bridge interaction study between multi-span simply supported beam bridges and the LCST is presented in this work. In specific, we have developed an integrated finite element model to investigate the overall interaction effects of the LCST-bridge system subjected to the actions of temperature changes, traffic loads, and braking forces. In that place, the deformation patterns of the track and bridge, and the distributions of longitudinal forces and the interfacial shear stress are studied. Our results show that the additional rail stress has been reduced under various loads and the rail's deformation has become much smoother after the transition of the two continuous structural layers of the LCST. However, the influence of the temperature difference of bridges is significant and cannot be ignored as this action can bend the bridge like the traffic load. The uniform temperature change causes the tensile stress of the concrete track structure and further induce cracks in them. Additionally, the influences of the friction coefficient of the sliding layer and the interfacial bond characteristics on the LCST's performance are discussed. The systematic study presented in this work may have some potential impacts on the understanding of the overall mechanical behavior of the LCST-bridge system.

상 변화 메모리 재료 내의 Ga 주입에 미치는 GaGe 스퍼터링 전력의 영향 (Effect of GaGe Sputtering Power on Ga Doping in Phase Change Memory Materials)

  • 정순원;이승윤
    • 한국전기전자재료학회논문지
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    • 제28권5호
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    • pp.285-290
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    • 2015
  • The phase change memory material is an active element in phase change memory and exhibits reversible phase transition behavior by thermal energy input. The doping of the phase change memory material with Ga leads to the increase of its crystallization temperature and the improvement of its amorphous stability. In this study, we investigated the effect of GaGe sputtering power on the formation of the phase change memory material including Ga. The deposition rate linearly increased to a maximum of 127 nm and the surface roughness remained uniform as the GaGe sputtering power increased in the range from 0 to 75 W. The Ga concentration in the thin film material abruptly increased at the critical sputtering power of 60 W. This influence of GaGe sputtering power was confirmed to result from a combined sputtering-evaporation process of Ga occurring due to the low melting point of Ga ($29.77^{\circ}C$).

사탕수수 부산물 펄프의 DEDP 표백 시 킬레이트 전처리가 표백 효율에 미치는 영향 (Effect on Bleaching Efficiency by Chelating Treatment in Sugarcane Bagasse DEDP Bleaching Process)

  • 이재성;송우용;박종문;신수정
    • 펄프종이기술
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    • 제47권4호
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    • pp.81-87
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    • 2015
  • Soda-AQ pulp made from sugarcane bagasse (SCB) were bleached in element chlorine free (ECF) sequence. To reduce chlorine dioxide use, final peroxide bleaching was introduced. Prior to peroxide bleaching, different chelating chemicals were applied for comparative analysis in ISO brightness and viscosity. When using equal total chlorine dioxide usage (4.5%), bleached SCB pulp using chelate and hydrogen peroxide (DEDQP) was reached 86.8% (DTPA), 86.4% (EDTA) ISO brightness, whereas bleached pulp using only hydrogen peroxide (DEDP) reached at 81.2% ISO brightness. Viscosity of DEDQP bleached pulp was 25.6 cPs (DTPA), 25.2 cPs (EDTA), And DEDP bleached pulp was shown 18.0 cPs viscosity. Decreasing of transition metal by chelate process led to improvements in final brightness along with higher viscosity. Due to EDTA is 5-7 times cheaper than DTPA, EDTA is recommended as chelating chemical prior to peroxide bleaching.

수평격판을 갖는 정사각형 밀폐공간내에서 자연대류 유동 및 열전달 (Natural Convective Flow and Heat Transfer in a Square Enclosure with a Horizontal Partition)

  • 정인기;김점수;송동주
    • 대한기계학회논문집
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    • 제17권9호
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    • pp.2304-2314
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    • 1993
  • Natural convective flow and heat transfer in a two-dimensional square enclosure fitted with a horizontal partition are investigated numerically. The enclosure was composed of the lower hot and the upper cold horizontal walls and the adiabatic vertical walls, and a partition was situated perpendicularly at the one vertical insulated wall. The governing equations are solved by using the finite element method with Galerkin method. The computations were carried out with the variations of length, position and thermal conductivity of the partition, and Rayleigh number based on the temperature difference between two horizontal walls and the enclosure height with water(Pr=4.95). As the results, an oscillatory motion of natural convection is resulted in a sudden rise of overall heat transfer, but the increase of length of partition is significantly restrained the increase of Nusselt number. The maximum heat transfer was shown just before the transition of the direction of oscillating flow. An oscillatory motion of flow was perfectly shown the stability with the decrease of the length of partition and Rayleigh number. Also, the heat transfer was raised with the increase of the thermal conductivity in proportion to the increase of the length of partition. The stability and oscillation of flow are affected by the position of partition.

시멘트 분쇄기용 테이블 라이너의 굽힘 피로강도의 실험적 조사 (An Experimental Investigation of Bending Fatigue Strength in Table Liner for Cement Mill)

  • 백석흠;이경영;조석수;장득열;주원식
    • 대한기계학회논문집A
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    • 제31권12호
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    • pp.1214-1220
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    • 2007
  • The vertical roller mill, which performs the grinding and partly blending of raw material, is the one of the important machine to produce ordinary portland cement. It has been reported that an unexpected fatigue failure occurred in a table liner in the course of grinding portland cement. The life of table liner is estimated to $4{\times}10^7$ cycles in the design stage, but at the field, when its operating time reaches to $2{\times}10^6{\sim}8{\times}10^6$ cycles, the fracture of table liner begins to be found. The fracture of table liner is initiated from the outside edge of grinding path contacting with the grinding roller. Its maintenance normally take 30 % of the total maintenance costs of the roller mill. Therefore, this study shows the clarification of the reasons occurring the fatal destruction of the table liner by fatigue fracture analysis utilizing fracture mechanics and by the finite element method. And, the results from Goodman diagram illustrate relationship of including information on the transition between tensile and bending fatigue strength in the fatigue characterization of table liner.