• Bulletin of the Korean Chemical Society
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• v.28 no.8
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• pp.1358-1362
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• 2007

The structures, energetics and transfer integrals of the acene tetramers up to pentacene are investigated with the ab initio molecular orbital method at the level of second-order Møller-Plesset perturbation theory (MP2). Calculated geometries for the herringbone-style structures found in the crystal structure were characterized as local minima, however the geometrical discrepancy between crystal and MP2 theoretical structure is reasonably small. The binding energy of pentacene tetramer was calculated up to 40 kcal/mol (MP2/6-31G(d)) and about 90 kcal/mol (MP2/aug-cc-pVDZ), and the latter seems to be too much overestimated. The tendency of the hole transfer integrals computed with ab initio MP2/3-21G(d) geometry is well agreement with those estimated with crystal structure with some discrepancy, and the gradual increment of the transfer integrals at the crystal geometry is attributed to mainly packing structure rather than the intrinsic property of acene such as a size of acene.

• Journal of Power System Engineering
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• v.18 no.6
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• pp.64-69
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• 2014

A circular plate is one of the important structures in many industrial fields. In static analysis of a circular plate, we may obtain an exact solution by analytical method, but it is limited to a simple circular plate. Thus, many researchers and designers have used numerical methods such as the finite element method. The authors of this paper developed the finite element-transfer stiffness coefficient method (FE-TSCM) for static and dynamic analyses of various structures. FE-TSCM is the combination of the modeling technique of the finite element method (FEM) and the transfer technique of the transfer stiffness coefficient method (TSCM). FE-TSCM has the advantages of both FEM and FE-TSCM. In this paper, the authors formulate the computational algorithm for the static analysis of axisymmetric circular plates under lateral loading using FE-TSCM. The computational results for three computational models obtained by FE-TSCM are compared with those obtained by FEM in order to confirm the accuracy of FE-TSCM.

• Korean Journal of Materials Research
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• v.19 no.8
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• pp.437-442
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• 2009

This paper describes an improved strategy for controlling the adhesion force using both the antiadhesion and adhesion layers for a successful large-area transfer process. An MPTMS (3-mercaptopropyltrimethoxysilane) monolayer as an adhesion layer for Au/Pd thin films was deposited on Si substrates by vapor self assembly monolayer (VSAM) method. Contact angle, surface energy, film thickness, friction force, and roughness were considered for finding the optimized conditions. The sputtered Au/Pd ($\sim$17 nm) layer on the PDMS stamp without the anti-adhesion layer showed poor transfer results due to the high adhesion between sputtered Au/Pd and PDMS. In order to reduce the adhesion between Au/Pd and PDMS, an anti-adhesion monolayer was coated on the PDMS stamp using FOTS (perfluorooctyltrichlorosilane) after $O_2$ plasma treatment. The transfer process with the anti-adhesion layer gave good transfer results over a large area (20 mm $\times$ 20 mm) without pattern loss or distortion. To investigate the applied pressure effect, the PDMS stamp was sandwiched after 90$^{\circ}$ rotation on the MPTMS-coated patterned Si substrate with 1-${\mu}m$ depth. The sputtered Au/Pd was transferred onto the contact area, making square metal patterns on the top of the patterned Si structures. Applying low pressure helped to remove voids and to make conformal contact; however, high pressure yielded irregular transfer results due to PDMS stamp deformation. One of key parameters to success of this transfer process is the controllability of the adhesion force between the stamp and the target substrate. This technique offers high reliability during the transfer process, which suggests a potential building method for future functional structures.

• Proceedings of the KSAR Conference
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• 2001.03a
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• pp.18-18
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• 2001

Despite of importance of integrated events of nucleus and microtubule remodeling in nuclear transferred embryos with somatic cells, little information is available on this subject. In this study we configured chromatin and microtubule organization following somatic cell nuclear transfer in pre- and non-activated bovine oocytes in order to clearify nuclear remodeling process and to demonstrate centrosome inheritance during nuclear transfer. The cumulus-oocyte complexes were collected from slaughterhouse and were matured in vitro for 20 h in TCM 199 supplemented hormone. Matured bovine oocytes were enucleated by aspirating the frist polar body and metaphase chromatin using a beveled pipette. Bovine fibroblast cells were fused into enucleated oocyte by electrical stimulation. Reconstructed oocytes were activated with ionomycine and 6-dimethylaminopurin, and then cultured in CRlaa medium. The organization of nuclear and microtubules were observed using laser-scanning confocal microscopy. At 1 hour after fusion, microtubule aster was seen near the transferred nucleus in most oocytes regardless activation condition. While most of fibroblast nuclei remodeled to premature chromosome condensation (PCC) and to the two masses of chromosome in non-activated oocytes, a few number of fibloblasts went to PCC and multiple pronuclear like structures in activated oocytes. Microtubular spindle was seen around condensed chromosome. Gamma-tubulin was detected in the vicinity of condensed chromosome, suggesting this is a transient spindle. The spindle seperated nucleus into two masses of chromatin which developed to the pronuclear like structures. Two pronuclear like structures were than apposed by microtubular aster and formed one syngamy like nuclear structure at 15 h following nuclear transfer. At 17 to 18 h after fusion, two centrosomes were seen near the nucleus, which nucleates micrtubules for two cell cleavage. While 31% of reconstructed oocytes in non-activated condition developed to morulae and blastocysts, a few reconstructed oocytes in pre-activated condition developed to the blastocyst. These results suggested introduction of foreign centrosome during nuclear transfer, which appeared to give an important role for somatic cell nuclear reprogramming.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.223-228
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• 1999

The state of the current design practice in designing the so-called hybrid structures with the upper shear-wall and lower frame systems are reviewed through the investigation of the 43 design examples. In particular, the trend in the design of the transfer system between upper wall and lower frame systems are analyzed with respect to the depth, the length and the number of spans of transfer deep girders and the number of upper stories. Finally the most critical portions in this conventional transfer system, which should be studied in depth in the future, are pointed out to improve the current design and analysis practice.

• Journal of Power System Engineering
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• v.18 no.2
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• pp.19-24
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• 2014

This research conducts CAE analysis of fire damper and design of damper controlling system. The prediction of the design heat transfer was done the answer of fire damper could be obtained by using continuity equation of damper controlling and orthogonal array. Through the design analysis of optimal offshore construction, new fire damper of H-120 class was designed. Accordingly, this equipment will be tested in actual offshore construction. Finally, we could obtain fire damper of optimal design with orthogonal array. With the CAE results of this research, The offshore plant will obtain eco-friendly fire damper with a method to select optimal condition of fire damper with orthogonal array.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.845-850
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• 2000

This paper presents the results of tests performed on the transfer girders which have been generally used between upper walls and lower frames in the hybrid structures. The 8 specimens were designed using (1) ACI method, (2) strut-tie model, and (3) X-type shear reinforcement cage. The capacities of the specimens are in general larger than the design values except the one designed according to strut-tie model. The reason for this difference seems to be due to the arbitrary allocation of transferred shear force to the path of direct compression strut and the path of indirect strut and tie. The failure modes turn out toe be (1) shear failure at critical shear zone, (2) compressive concrete crushing in the diagonal strut in the shear zone of transfer girder, and (3) compressive concrete crushing in the corner of upper wall.

• Journal of Korean Association for Spatial Structures
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• v.17 no.1
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• pp.59-67
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• 2017

In this study, load transfer tests based on KCI-PS101 were conducted to verify the performance of spiral anchorage zone reinforcement for banded post-tensioning (PT) monostrands. With results, the compressive strength of spiral reinforcement was increased by about 20% than that of specimens with two horizontal steel bars and 8% than that of U-shaped bars. Advanced spiral reinforcement for corner increases compressive strength and can resist the spalling forces or fall-out effect at the corner by shear. The ratio of maximum load to amount of steel of the spiral reinforcement is about twice than that of U-shaped reinforcement. With increase of compressive strength capacity and improvement of constructability, the spiral reinforcement is considered to have advantages of promoting the performance of PT anchorage zone compared to conventional methods.

• Progress in Superconductivity and Cryogenics
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• v.25 no.1
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• pp.1-5
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• 2023

The study of two-dimensional electron systems with extraordinarily low levels of disorder was, for a long time, the exclusive privilege of the epitaxial thin film research community. However, the successful isolation of graphene by mechanical exfoliation has truly disrupted this field. Furthermore, the assembly of heterostructures consisting of several layers of different 2D materials in arbitrary order by exploiting van der Waals forces has been a game-changer in the field of low-dimensional physics. This technique can be generalized to the large class of strictly 2D materials and offers unprecedented parameters to play with in order to tune electronic and other properties. It has led to a paradigm shift in the field of 2D condensed matter physics with bright prospects. In this review article, we discuss three device fabrication techniques towards high mobility devices: suspended structures, dry transfer, and pick-up transfer methods. We also address state-of-the-art device structures, which are fabricated by the van der Waals pick-up transfer method. Finally, we briefly introduce correlated ground states in the fractional quantum Hall regime.

• Structural Engineering and Mechanics
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• v.16 no.1
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• pp.17-34
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• 2003

This paper presents a damage assessment procedure applied to periodic spring mass systems using an eigenvalue sensitivity-based method. The damage is directly related to the stiffness reduction of the damage element. The natural frequencies of periodic structures with one single disorder are found by adopting the transfer matrix approach, consequently, the first order approximation of the natural frequencies with respect to the disordered stiffness in different elements is used to form the sensitivity matrix. The analysis shows that the sensitivity of natural frequencies to damage in different locations depends only on the mode number and the location of damage. The stiffness changes due to damage can be identified by solving a set of underdetermined equations based on the sensitivity matrix. The issues associated with many possible damage locations in large structural systems are addressed, and a means of improving the computational efficiency of damage detection while maintaining the accuracy for large periodic structures with limited available measured natural frequencies, is also introduced in this paper. The incomplete measurements and the effect of random error in terms of measurement noise in the natural frequencies are considered. Numerical results of a periodic spring-mass system of 20 degrees of freedom illustrate that the proposed method is simple and robust in locating single or multiple damages in a large periodic structure with a high computational efficiency.