• Bulletin of the Korean Chemical Society
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• v.15 no.10
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• pp.845-849
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• 1994

Tetracarbonylhydridoferrate, $HFe(CO)^-_4$, generated by the reaction of $Fe(CO)_5$ with alkaline solution, is a good reducing agent for mono-dehalogenation of gem-dihalocyclopropanes. It also acts as a good reducing catalyst under phase transfer reaction conditions. 1,1-Dibromo-2-phenylcyclopropane and 1,1-dichloro-2-phenylcyclopropane were reduced to the corresponding mono-dehalogenated products in excellent yields. Thermodynamically stable trans-l-bromo-2-phenyl cyclopropane was formed as the major product over the cis-isomer, trans/cis=3/2. The 1-bromo-2-phenyl cyclopropane radical intermediate was formed by single electron transfer from $HFe(CO)^-_4$. Dissociation of bromide anion, followed abstraction of hydrogen radical from alcoholic solvent would lead to the formation of the stable trans-isomer. The further mechanistic aspects were discussed.

• Bulletin of the Korean Chemical Society
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• v.19 no.10
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• pp.1084-1090
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• 1998

The oxidation of triphenylphosphine by [(tpy)(phen)RuⅣ(O)]2+ and [(bpy)(p-tert-butylpy)RuⅣ(0)]2+ (tpy is 2,2': 6',2"-terpyridine, phen is 1,10-phenanthroline, bpy is 2,2'-bipyridine, and p-tert-butylpy is para-tertbutylpyridine) in CH3CN has been studied. Experiments using 18O-labeled complex show the oxyl group transfer from [RuⅣ=O]2+ to triphenylphosphine occured quantitatively within experimental error. Kinetic data were fit to a second-order for [RuⅣ=O]2+ and [PPh3]. The initial product, [RuⅡ-OPPh3]2+, was formed as an observable intermediate and then underwent slow solvolysis. The reaction proceeded as endothermic in activation enthalpy and a decrease in activation entropy. The oxidative reactivity of four representative ruthenium mono-oxo oxidants against triphenylphosphine was compared. These systems have been utilized as electrochemical oxidative catalysts.

• Journal of the Korean Society of Industry Convergence
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• v.21 no.5
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• pp.191-195
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• 2018

By using an ANSYS product suite (CFX, Ansys Multiphysics), which is a powerful tool for multiphysics analysis of complicated physical phenomena, we performed a structural stress analysis based on fluid flow and heat transfer phenomena within a quick connect/disconnect (QC/DC) bellows system. Considering the extremely low temperatures in the QC/DC environment, an approach to the problem based on complex multi-physics phenomena, where different phenomena interact with each other, is crucial. Therefore, we use a numerical analysis technique where fluid-thermal-structural interactions are combined. In conclusion, when low temperature fluids flow inside bellows, the expected service life is conspicuously reduced due to the thermal stress caused by heat transfer. Therefore, in future research, a structure with considerably reduced thermal stress by robust design optimization will be derived.

• Journal of Ocean Engineering and Technology
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• v.33 no.3
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• pp.229-235
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• 2019

In this study, a two-dimensional oscillating foil with forward speed in a propagating wave flow field was considered. The time-mean power to maintain the heaving and pitching motions of the foil was analyzed using the perturbation theory in an ideal fluid. The power, which was a non-linear quantity of the second-order, was expressed in terms of the quadratic transfer functions related to the mutual product of the heaving and pitching motions and incoming vertical flow. The effects of the pivot point and phase difference among the disturbances were studied. The negative power, which indicates energy extraction from the fluid, is shown as an example calculation.

• Korea Trade Review
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• v.44 no.2
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• pp.159-172
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• 2019

An important issue in trade transactions is risk management. Trading partners focus on how to recognize risks and how to address these areas. This article discusses whether the quality of a substantial period of time remains appropriate to the contract even after the risk has been transferred. If the contracted product is not delivered, then the risk is not transferred because it does not fulfill the obligations of delivery. In order to prevent such risks, the Seller must regard the quality of the goods of their fulfillment and provide them to the Buyer in detail. In addition, it is necessary to carry out several times of transportation or insurances of insurance according to the transaction conditions. Commercial practice comes from repetitive trading activities over many years. I think it is constantly changing as the transaction continues. Changes in the way of international commerce always create new orders and regulations. We need to keep a close eye on them.

• Design & Manufacturing
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• v.17 no.3
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• pp.61-66
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• 2023

In this study, we developed a simulation methodology for a technology that rapidly cools molds by directly spraying them with CO₂ in its liquefied gaseous state. Initially, a simulation verification process was conducted using ANSYS Fluent's heat transfer analysis based on temperature values measured in prior research experiments, ensuring a comparable temperature could be calculated. Subsequently, the validated analysis method was employed to evaluate design factors that exert the most significant influence on cooling. An evaluation was conducted based on three factors: part thickness, mold thickness, and the melting temperature of material. Using a full factorial design approach, a total of 27 analyses were completed and subsequently calculated through analysis of means. The impact assessment was carried out based on the temperature values at the product's core. The results indicated that the thickness of the mold had the highest influence, while the melting temperature of material had the least.

• Journal of Embryo Transfer
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• v.27 no.2
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• pp.71-80
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• 2012

Biotechnologies for cloning animals and in vitro embryo production have the potential to produce biomedical models for various researches. Especially, pigs are a suitable model for xenotransplantation, transgenic production and various areas of reproductive research due to its physiological similarities to human. However, utilization of in vitro-produced embryos for transfer remains limited. Despite improvement over past few decades, obstacles associated with the production of good quality embryos in vitro still exist which limit the efficiency of cloning. One of major problems includes improper in vitro maturation (IVM) and culture (IVC). Oxidative stress caused from in vitro culture conditions contributes to inadequate IVM and IVC which leads to poor developmental competence of oocytes, failure of fertilization and embryo development. To reduce the oxidative stress, various antioxidants have been used to IVM and IVC system. However, limited information is available on the effects of resveratrol on livestock reproductions. Resveratrol is a polyphenolic natural product and well known as an antioxidant in foods and beverages (e.g. in grapes and red wine). Resveratrol is known to be cardioprotective, anticarcinogenic, anti-inflammatory, antioxidant and antiapoptotic. This paper will review the effects of resveratrol on in vitro maturation of oocytes and embryo development.

• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.365-371
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• 2010

The multiconfiguration molecular mechanics (MCMM) algorithm was used to generate potential and vibrationally adiabatic energy surfaces for excited-state tautomerization in the 1:1 7-azaindole:$H_2O$ complex. Electronic structures and energies for reactant, product, transition state were computed at the CIS/6-31G(d,p) level of theory. The potential and vibrationally adiabatic energies along the reaction coordinate were generated step by step by using 16 high-level Shepard points, which were computed at the CIS/6-31G(d,p) level. This study shows that the MCMM method was applied successfully to make quite reasonable potential and adiabatic energy curves for the excited-state double proton transfer reaction. No stable intermediates are present in the potential energy curve along the reaction coordinate of the excited-state double proton transfer in the 1:1 7-azaindole:$H_2O$ complex, indicating that these two protons are transferred concertedly. The change in the bond distances along the reaction coordinate shows that two protons move very asynchronously to make an $H_3O^+$-like moiety at the transition state.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.4
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• pp.460-469
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• 2010

In spite of the global-class aquaculture and fishing technology of our country, the processing technologies are lags behind the other nations relatively. The processed marine products are mainly frozen foods, canned goods, salty food (fermented fish products), fish paste products (boiled fish paste), and we can see that the high-value dehydrated foods by drying are very few. These problems are considered to be caused directly by the lack of drying technologies. This paper is concerned to the experimental results of drying heat transfer characteristics for the green energy type vacuum dryer for the high quality sea foods production.

• 한국지구물리탐사학회:학술대회논문집
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• 2003.11a
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• pp.238-243
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• 2003

As there are many advantages on underground caverns, such as safety and operation, they can also be used for gas storage purpose. When liquefied gas is stored underground, the cryogenic temperature of the gas will affect the stability of the storage cavern. In order to store the liquefied gas successfully, it is essential to estimate the exact temperature distribution of the rock mass around the cavern. In this study, an analytic solution and a conceptual model that can estimate three-dimensional temperature distribution around the storage cavern are suggested. When calculating the heat transfer within a solid, it is likely to consider the solid as the intersection of two or more infinite or semi-infinite geometries. Therefore heat transfer solution for the solid is expressed by the product of the dimensionless temperatures of the geometries, which are used to form the combined solid. Based on the multi-dimensional transient heat transfer theory, the analytic solution is successfully derived by assuming the cavern shape to be of simplified geometry. Also, a conceptual model is developed by using the analytic solution of this study. By performing numerical experiments of this multi-dimensional model, the temperature distribution of the analytic solution is compared with that of numerical analysis and theoretical solutions.