• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.447-452
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• 2013

In this study we report a new method for the synthesis of a silica monolithic column bed with bimodal pores (throughpores and mesopores). The template induced synthesis method was used to direct bimodal pores simultaneously instead of the usual post base-treating method. Block polymer Pluronic F127 was chosen as a dual-function template to form hierarchically porous silica monolith with both macropores and mesopores. This is a simplification of the method of monolithic column preparation. Poly(ethylene glycol) was used as a partial substitute for F127 can effectively prevent shrinkage during the monolith aging process without losing much surface area (944 $m^2/g$ to 807 $m^2/g$). More importantly, the resultant material showed a much narrower mesopore size (centered at 6 nm) distribution than that made using only F127 as the template reagent, which helps the mass transfer process. The solvent washing method was used to remove the remaining organic template, and it was proved to be effective enough. The new synthesis method makes the fabrication of the silica monolithic column (especially capillary column) much easier. All the structure parameters indicate that monolith PFA05 prepared by the above method is a good material for separation, with the merits of much higher surface area than usual commercial HPLC silica particles, suitable mesopore volume, narrow mesopore size distribution, low shrinkage and it is easily prepared.

• The Journal of the Acoustical Society of Korea
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• v.28 no.2
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• pp.85-95
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• 2009

In the binaural synthesis environments, wide varieties of the head-related transfer functions (HRTFs) that have measured with a various direction would be desirable to obtain the accurate and various spatial sound images. To reduce the size' of HRTFs, interpolation has been often employed, where the HRTF for any direction is obtained by a limited number of the representative HRTFs. In this paper, we study on the distortion measures for interpolation, which has an important role in interpolation. With lhe various objective distortion metrics, the differences between the interpolated and the measured HRTFs were computed. These were then compared and analyzed with the results from the listening tests. From the results, the objective distortion measures were selected, that reflected the perceptual differences in spatial sound image. This measure was employed in a practical interpolation technique. We applied the proposed method to four kinds of an HRTF set, measured from three human heads and one mannequin. As a result, the Mel-frequency cepstral distortion was shown to be a good predictor for the differences in spatial sound location, when three HRTF measured from human, and the time-domain signal to distortion ratio revealed good prediction results for the entire four HRTF sets.

• 제어로봇시스템학회:학술대회논문집
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• 2003.10a
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• pp.433-437
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• 2003

Quantitative Feedback Theory (QFT) is one of effective methods of robust controller design. In QFT design we can considers the phase information of the perturbed plant so it is less conservative than $H_{\infty}$ and ${\mu}$-synthesis methods and as be shown, it is more transparent than the sensitivity reduction methods mentioned . In this paper we want to overcome the major drawback of QFT method which is lack of an automatic method for loop-shaping step of the method so we focus on the following problem: Given a nominal plant and QFT bounds, synthesize a controller that achieves closed-loop stability and satisfies the QFT boundaries. The usual approach to this problem involves loop-shaping in the frequency domain by manipulating the poles and zeros of the nominal loop transfer function. This process now aided by recently developed computer aided design tools proceeds by trial and error and its success often depends heavily on the experience of the loop-shaper. Thus for the novice and First time QFT user, there is a genuine need for an automatic loop-shaping tool to generate a first-cut solution. Clearly such an automatic process must involve some sort of optimization, and while recent results on convex optimization have found fruitful applications in other areas of control theory we have tried to use LMI theory for automating the loop-shaping step of QFT design.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.94.2-94.2
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• 2011

In this work, multi-functional groups, i.e., nitrogen and oxygen, contained microporous carbons (MF-MCs) were prepared by the one step carbonization of the poly(vinylidene chloride-co-acrylonitrile-co-methyl methacryalte) (PVDC-AN-MMA) without activation. The electrochemical performance of MF-MCs was investigated as a function of carbonization temperature. It was found that MF-MCs had a high specific surface area over $800m^2/g$ without additional activation, resulting from the micropore's formation by the release of chlorine groups. In addition, although functional groups decreased, specific surface area was increased with increasing carbonization temperature, leading to the enhanced electrochemical performance. The pore size of the carbon distributed mainly in small micropore of 1.5 to 2 nm, which was idal for aqueous electrolyte. Indeed, the unique microstructure features, i.e. high specific surface area and optimized pore size provided high energy storage capability of MF-MCs. These results indicated that the microporous features of MF-MCs lead to feasible electron transfer during charge/discharge duration and the presence of nitrogen and oxygen groups on the MF-MCs electrode led to a pseudocapacitive reaction.

• The Transactions of the Korea Information Processing Society
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• v.7 no.5
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• pp.1361-1369
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• 2000

For the implementation of 3D Sound Localization system, the binaural filtering by HRTFs is generally employed. But the HRTF filter is of high order and its coefficients for all directions have to be stored, which imposes a rather large memory requirement. To cope with this, research works have centered on obtaining low dimensional HRTF representations without significant loss of information and synthesizing the original HRTF efficiently, by means of feature extraction methods for multivariate dat including PCA. In these researches, conventional linear PCA was applied to the frequency domain HRTF data and using relatively small number of principal components the original HRTFs could be synthesized in approximation. In this paper we applied neural network based nonlinear PCA model (NLPCA) and the nonlinear PLS repression model (NLPLS) for this low dimensional HRTF modeling and analyze the results in comparison with the PCA. The NLPCA that performs projection of data onto the nonlinear surfaces showed the capability of more efficient HRTF feature extraction than linear PCA and the NLPLS regression model that incorporates the direction information in feature extraction yielded more stable results in synthesizing general HRTFs not included in the model training.

• ETRI Journal
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• v.27 no.6
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• pp.691-696
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• 2005

In asynchronous transfer mode (ATM) networks, fixed length cells of 53 bytes are transmitted. A cell may be discarded during transmission due to buffer overflow or a detection of errors. Cell discarding seriously degrades transmission quality. The quality degradation can be reduced by employing efficient forward error control (FEC) to recover discarded cells. In this paper, we present the design and implementation of decoding equipment for FEC in ATM networks based on a single parity check (SPC) product code using very-large-scale integration (VLSI) technology. FEC allows the destination to reconstruct missing data cells by using redundant parity cells that the source adds to each block of data cells. The functionality of the design has been tested using the Model Sim 5.7cXE Simulation Package. The design has been implemented for a $5{\times}5$ matrix of data cells in a Virtex-E XCV 3200E FG1156 device. The simulation and synthesis results show that the decoding function can be completed in 81 clock cycles with an optimum clock of 56.8 MHz. A test bench was written to study the performance of the decoder, and the results are presented.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.3 no.3
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• pp.541-546
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• 1999

The head-related transfer function (HRTF), which expresses the acoustic process from the sound source to the human ears in the free field, contains critical informations which the location of the source can be traced. It also makes it possible to realize multi-dimensional acoustic system that can approximately generate non-existing sound source. The use of non-individual, common HRTF brings performance degradation in localization ability such as front-back judgment error, elevation judgment error. In this paper, we have reduced the error on vertical plane by increasing the spectral notch level. The performance of the proposed method was Proved through subjective test that it is Possible to improve the ability to locate stationary/moving source.

• Journal of the Korean Magnetic Resonance Society
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• v.12 no.1
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• pp.1-13
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• 2008

Acetyl-CoA carboxylase (ACC) catalyzes the first step in fatty acid biosynthesis: the synthesis of malonyl-CoA from acetyl-CoA. As essential regulators of fatty acid biosynthesis and metabolism, ACCs are regarded as therapeutic targets for the treatment of metabolic diseases such as obesity, In ACC, the biotinoyl domain performs a critical function by transferring an activated carboxyl group from the biotin carboxylase domain to the carboxyl transferase domain, followed by carboxyl transfer to malonyl-CoA. Despite the intensive research on this enzyme, only the bacterial and yeast ACC structures are currently available, To explore the mechanism of ACC holoenzyme function, we determined the structure of the biotinoyl domain of human ACC2 and analyze its characteristics using NMR spectroscopy. The 3D structure of the hACC2 biotinoyl domain has a similar folding topology to the previously determined domains from E. coli and P. Shermanii, however, the 'thumb' structure is absent in the hACC2 biotinoyl domain. Observations of the NMR signals upon the biotinylation indicate that the biotin group of hACC2 does not affect the structure of the biotinoyl domain, while the biotin group for E. coli ACC interacts directly with the thumb residues that are not present in the hACC2 structure. These results imply that, in the E. coli ACC reaction, the biotin moiety carrying the carboxyl group from BC to CT can pause at the thumb of the BCCP domain. The human biotinoyl domain, however, lacks the thumb structure and does not have additional non-covalent interactions with the biotin moiety; thus, the flexible motion of the biotinylated lysine residue must underlie the "swinging arm" motion. This study provides insight into the mechanism of ACC holoenzyme function and supports the "swinging arm" model in human ACCs.

• Journal of the Korean Chemical Society
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• v.17 no.1
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• pp.1-9
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• 1973

The purpose of this paper is to investigate the mechanism of Diels-Alder reaction by assuming pseudo molecular complex (PMC) which has characters both of ionic and radical bonds. We treated this complex quantum-chemically as an intermediate between the configuration without charge transfer (radical bond character) and the configuration corresponding to the charge transfer from Diene (R) to Dienophile (S) (ionic bond character). The wave function for the complex could be expressed as: ${\psi}_{complex} = {\psi}(R,S) +{ \rho}{\psi}(R^+,S^-)$ where ${\rho}$ is the extent of charge transfer which is a constant to measure the ionic character of PMC. It has been noticed that${\rho}$is related to the difference between Fr + Fr' and Fs + Fs' in free valence (F) when R is united to S through atom r in R to atom s in S and atom r' in R to atom s' in S, That is, ${\rho}{\alpha}$ ${\Delta}F = (Fr + Fr') - (Fs + Fs')$. We have calculated ${\Delta}F$values for more than forty Diels-Alder reactions. The calculated values of ${\Delta}F$ is reversely proportional to the values of Brown's paralocalization energy (Lp) as well as Dewar's differences of delocalization energy$({\Delta}Edeloc.)$ with good linearity. This approach also presents a way of predicting the possibility and the easiness of diene synthesis between any two conjugate compounds. According to the considerations, it could be concluded that Diels-Alder reaction takes place through the united ionic-radical mechanism rather than the separated ionic or radical mechanism.

• Broadcasting and Media Magazine
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• v.16 no.4
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• pp.31-45
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• 2011

사용자가 원하는 3D 사운드 혹은 소리의 공간감을 원하는 대로 재현할 수 있는 오디오 시스템은 오랜 기간 동안 인류가 가지고 싶었던 꿈의 기계였다. 그러나 과연 개인 혹은 사용자가 원하는 3D 사운드라는 것이 무엇이며 어떻게 정의하여야 하는지는 명확하지 않다. 이것은 매우 주관적인 개념일 뿐만 아니라 개인에 따라 다를 수 있으며, 그 평가에 대한 객관적인 방법 또한 존재하지 않는다. 관련된 연구를 살펴보면, 원하는 소리의 파동 전파 자체를 시공간 상에서 물리적으로 재현하는 WFS(Wave Field Synthesis)나 Ambisonics, 또는 머리전달함수(HRTF: Head Related Transfer Function)를 기반으로 한 많은 연구들이 있다. 이렇게 재현된 음장(sound field)을 보면 이들이 인지되고 평가되는 등의 객관화를 위하여는 청취 환경에 따라 그 특성이 바뀌고 동일한 환경에서도 청취자에 따라 다르게 인지되는 근본적인 문제점을 가지고 있다. 음장 재현 방법의 이러한 근본적인 문제는 놀랍게도 과거의 스테레오 시스템에서 볼 수 있는 밸런스 노브(balance knob)로부터 그 해결의 실마리를 찾을 수 있다. 밸런스 노브는 보편적인 최적의 소리를 찾는 대신에 청취자가 원하는 음향 효과를 얻을 때까지 직접적으로 소리를 청취하고, 스스로 조절하여 평가할 수 있는 매개체의 역할을 수행한다. 만일 밸런스 노브와 같이 청취자가 원하는 3D 사운드를 스스로 평가하고 조절하기 위한 방법을 마련할 수 있다면? 즉, 청취자가 시공간적으로 원하는 3D 사운드를 실시간으로 청취하고 변화시킬 수 있는 인터페이스를 구현할 수 있다면? 과연 그러한 것이 어떻게 가능할 수 있는지 체계적인 검토가 이루어질 수 있다면 매우 좋을 것이다. 본 고는 이러한 것을 가능케 할 수 있는 즉, 청취자가 자유 자재로 원하는 음장을 형성할 수 있는 렌더링 기법 및 즉각적인 피드백이 가능한 인터페이스를 소개하고 있다. 인터페이스는 현재까지 오디오 시스템에서 주로 사용되는 주파수 이퀄라이져(frequency equalizer)와 매우 유사한 특징이 있다. 이러한 점을 감안하여 "Spatial Equalizer$^{(R)}$"라는 이름을 붙여 보았다. Spatial Equalizer$^{(R)}$는 공간 상에 하나의 점 또는 다수의 점으로 표시되는 가상 음원을 사용자가 조종하여 원 소리의 공간감을 제어할 수 있도록 구성되어 있다. 공간 상에 다수의 점 음원들의 위치를 변화시키거나 크기를 변화시킴으로써 청취자가 원하는 공간감을 구현할 수 있도록 하고 있다. 중요한 것은 종전의 이퀄라이져와 같이 Spatial Equalizer$^{(R)}$에 의해 형성되는 음장이 어떤 객관적인 척도에 의해서 평가되는 대신 사용자에 의해 직접 주관적으로 평가되고, 선택된다는 점이다.