• Title/Summary/Keyword: transfer/concentration coefficient

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Preparation of PVDF Hollow Fiber Membrane and Absorption of SO2 from Flue Gas Using Bench Scale Gas-Liquid Contactor (PVDF 중공사막 제조 및 벤치규모 기-액 접촉기를 이용한 SO2 흡수특성)

  • Park, Hyun-Hee;Jo, Hang-Dae;Kim, In-Won;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.521-528
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    • 2008
  • The micro-porous asymmetric PVDF hollow fiber membranes for gas-liquid contactor were prepared by the dry-jet wet phase inversion process and the characteristics of hollow fiber membranes were evaluated by the gas permeation method and scanning electron microscope. The chemical absorbent for removal of $SO_2$ gas was sodium hydroxide at bench scale hollow fiber membrane contactor. The experiments were performed in a counter-current mode of operation with gas in the shell side and liquid in the fiber lumen of the module to examine the effect of various operating variables such as concentration of absorbent, gas flow rate, L/G ratio and concentration of inlet $SO_2$ gas on the $SO_2$ removal efficiency using PVDF hollow fiber membrane contactor. Membrane mass transfer coefficient($k_m$) was calculated by mathematical modeling. The volumetric overall mass transfer coefficient increased with increasing the concentration of absorbent and L/G ratio. The increase of the absorbent concentration and L/G ratio not only provides more sufficient alkalinity but also decreases liquid phase resistance. The volumetric overall mass transfer coefficient increased with increasing gas flow rate due to decreasing the gas phase resistance.

Prediction of Forced Convective Boiling Heat Transfer Coefficient of Pure Refrigerants and Binary Refrigerant Mixtures Inside a Horizontal Tube

  • Kim, Min-Soo;Hong, Eul-Cheong;Shin, Jee-Young;Kyungdoug Min;Ro, Sung-Tack
    • Journal of Mechanical Science and Technology
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    • v.17 no.6
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    • pp.935-944
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    • 2003
  • Forced convective boiling heat transfer coefficients were predicted for an annular flow inside a horizontal tube for pure refrigerants and nonazeotropic binary refrigerant mixtures. The heat transfer coefficients were calculated based on the turbulent temperature profile in liquid film and vapor core considering the composition difference in vapor and liquid phases, and the nonlinearity in mixing rules for the calculation of mixture properties. The heat transfer coefficients of pure refrigerants were estimated within a standard deviation of 14% compared with available experimental data. For nonazeotropic binary refrigerant mixtures, prediction of the heat transfer coefficients was made with a standard deviation of 18%. The heat transfer coefficients of refrigerant mixtures were lower than linearly interpolated values calculated from the heat transfer coefficients of pure refrigerants. This degradation was represented by several factors such as the difference between the liquid and the overall compositions, the conductivity ratio and the viscosity ratio of both components in refrigerant mixtures. The temperature change due to the concentration gradient was a major factor for the heat transfer degradation and the mass flux itself at the interface had a minor effect.

Effect of the lubrication oil on heat transfer and pressure drop characteristics of supercritical carbon dioxide in a microfin tube (마이크로핀관내 냉동기유가 초임계 이산화탄소의 열전달과 압력강하에 미치는 영향)

  • Ku, Hak-Keun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.4
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    • pp.1440-1446
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    • 2012
  • This paper presents an experimental study of heat transfer and pressure drop characteristics of supercritical carbon dioxide with PAG inside a horizontal microfin tube. Heat transfer coefficient and pressure drop gradients were measured at 10 MPa in pressure and 520 kg/$m^2s$ in mass flux with variation of PAG mass concentration from 0.06% to 2.26%. The tendencies of both heat transfer and frictional pressure drop characteristics show the same as those of pure $CO_2$ up to 0.3% in PAG mass concentration. In case of 2.26% in PAG mass concentration, measured heat transfer coefficients showed 50% lower than those of pure $CO_2$ near the pseudocritical temperature and measured frictional pressure drop gradients show 1.6 times higher in comparison with those of pure $CO_2$ at $60^{\circ}C$ in $CO_2$ bulk temperature.

Effects of Pressure and Dissolved Oxygen Concentration on the Activated Sludge (압력 및 용존산소 농도가 활성슬러지에 미치는 영향)

  • 양병수;신현무
    • Journal of Environmental Science International
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    • v.4 no.3
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    • pp.259-267
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    • 1995
  • This study was conducted to evaluate the effects of pressure and dissolved oxygen concentration on the activated slut비e and to determine the optimum depth of deep shaft process. Some results from this study were summarized as follows. 1. It is considered that low sludge product in the activated sludge system maintaining high dissolved oxygen concentration is attributed to the increase of endogeneous respiration rate caused by the increase of aerobic zone in the sludge floe. 2. The increase of dissolved oxygen concentration does not affect to the increase of organic removal efficiency greatly and therefore the limiting factor is the substrate transfer into the inner part of floe. 3. The yield coefficient, Y is decreased in proportion to the increase of oxygen concentration. In this study, Y values arre ranged from 0.70 to 0.41 according to the variation of dissolved oxygen concentration from 18.0mg/$\ell$ to 258 mg/$\ell$. 4. The optimum depth of deep shaft process should be determined within the limits of non-toxicity to the microorganism and it is about loom in this study.

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Development of Mass Transfer Models for Ammonia Flux Estimation from Sewage Treatment Plants (하수처리장에서의 암모니아 플럭스 산정을 위한 물질전달모형 개발)

  • Sa, Jae-Hwan;Jeon, Eui-Chan;Jeong, Jae-Hak
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.701-711
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    • 2006
  • Sewage treatment plants located near to large cities emit extremely higher concentration of odorous materials. This study evaluated flux profiles of ammonia emitted from the water surface of sewage treatment plants using a dynamic flux chamber. Also, an ammonia overall mass transfer coefficient and a mass transfer model was developed in order to estimate fluxes of ammonia using environment parameters and the flux from the sewage treatment plants. The developed mass transfer model was evaluated through a fitness analysis. Comparison modeled flux applying empirical overall mass transfer coefficients of ammonia and measured ammonia flux show a high linearity with 0.977. The flux ratio of 1.282 demonstrated highly statistical fitness, also. Modeled flux using the mass transfer model was compared with measured flux. In result, it indicated that empirical overall mass transfer coefficients were similar to measured flux. The mass transfer model using the empirical overall mass transfer coefficient developed in this study was proved to be an easy and effective method to make accurate and precise predictions for ammonia flux discharged from sewage treatment plants.

Mass Transfer Effects in Xanthan Gum Fermentation (Xanthan Gum 발효에 있어서 물질전달의 영향)

  • 임병연;유영제
    • Microbiology and Biotechnology Letters
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    • v.17 no.4
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    • pp.277-282
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    • 1989
  • Xanthan gum is a biopolymer produced by Xanthomonas campestris. In xanthan gum fermentation, the fermentation broth changes to highly viscous non-Newtonian fluid as xanthan gum concentration increases. Maximum xanthan gum concentration is limited by high viscosity of the broth since mass transfers of nutrient and oxygen are inhibited. Int this study the mass transfer effects were investigated in batch and fed-batch fermentations at various agitation speeds and by separate oxygen transfer experiments. Xanthan gum production rate was observed to be largely dependent on oxygen transfer coefficient; while cell growth rate was not affected highly by this factor.

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A Study on the Heat Transfer Characteristics of Slurry Ice Generator using Scraper (스크레퍼형 슬러리아이스 제빙기의 열전달 특성 연구)

  • Kim, Joung-Ha;Yun, Jae-Ho;Kim, Min-Jun;Kim, Kyu-Jin;Cho, Hyoug-Seok;An, Seong-Kuk
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.144-149
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    • 2006
  • In this study ice making characteristics are experimentally investigated for the ice slurry generating system which is pneumatically operated. The experimentations are conducted under the various test conditions such as chilled water inlet temperature, aqueous solution concentration, flow rate of cooling water, scraper pitch and frequency of cylinder stroke. For the above experimental conditions, ice making characteristics of the slurry ice generating system are evaluated in terms of the overall heat transfer coefficient, heat transfer rate and the amount of slurry ice generation. And the experimental results show that the heat transfer rate of the system increases as the flow rate of cooling water solution increases and the concentration of ethylene glycol and inlet temperature of chilled water decreases.

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REYNOLDS NUMBER EFFECTS ON MASS TRANSFER IN TURBULENT PIPE FLOW: PART I. MEAN CONCENTRATION FIELD AND LOW-ORDER STATISTICS (난류 파이프 유동 내 물질전달에 대한 레이놀즈 수 영향: Part I. 평균 농도장 및 저차 난류통계치)

  • Kang, Chang-Woo;Yang, Kyung-Soo
    • Journal of computational fluids engineering
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    • v.17 no.3
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    • pp.1-10
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    • 2012
  • Large Eddy Simulation(LES) of turbulent mass transfer in fully developed turbulent pipe flow has been performed to study the effect of Reynolds number on the concentration fields at $Re_{\tau}=180$, 395, 590 based on friction velocity and pipe radius. Dynamic subgrid-scale models for the turbulent subgrid-scale stresses and mass fluxes were employed to close the governing equations. Fully developed turbulent pipe flows with constant mass flux imposed at the wall are studied for Sc=0.71. The mean concentration profiles and turbulent intensities obtained from the present LES are in good agreement with the previous numerical and experimental results currently available. To show the effects of Reynolds number on the turbulent mass transfer, the mean concentration profile, root-mean-square of concentration fluctuations, turbulent mass fluxes, cross-correlation coefficient, turbulent diffusivity and turbulent Schmidt number are presented.

Laminar Convective Heat Transfer from a Horizontal Flat Plate of Phase Change Material Slurry Flow

  • Kim Myoung-Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.7
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    • pp.779-784
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    • 2005
  • This paper presents the theory of similarity transformations applied to the momentum and energy equations for laminar, forced, external boundary layer flow over a horizontal flat plate which leads to a set of non-linear, ordinary differential equations of phase change material slurry(PCM Slurry). The momentum and energy equation set numerically to obtain the non-dimensional velocity and temperature profiles in a laminar boundary layer are solved. The heat transfer characteristics of PCM slurry was numerically investigated with similar method. It is clarified that the similar solution method of Newtonian fluid can be used reasonably this type of PCM slurry which has low concentration. The data of local wall heat flux and convective heat transfer coefficient of PCM slurry are higher than those of water more than 150$\~$200$\%$, approximately.

An Experimental Study on Beat and Mass Transfer Characteristics of Helical Absorber (헬리컬 흡수기의 열ㆍ물질전달 특성에 관한 실험적 연구)

  • Kwon, Oh-Kyung;Yun, Jae-Ho;Yoon, Jung-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.1
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    • pp.81-88
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    • 2004
  • In this study, heat and mass transfer characteristics of five components solution (LiBr+Lil+LiNO$_3$+LiCl+$H_2O$) which could be substituted for commonly used LiBr solution are tested using a helical absorber. The arrangement of helical-typed heat exchangers allows to make the system more compact as compared to conventional one. The effects of experimental parameters, such as the solution flow rate, cooling water, solution temperature, solution concentration and surfactant have been investigated in view of the heat and mass transfer. The results of the experiment of heat and mass transfer performance show that five components solution should have 2% higher concentration fur equal absorption capacity of LiBr solution. But considering that five components solution have higher solubility than LiBr solution about 4% high concentration, five components solution could be applied to a small sized water cooled or air cooled absorption chiller/heater. The increase of heat and mass transfer coefficient by surfactant addition is about 25∼30% and 23∼40% respectively.