• Title/Summary/Keyword: trans-10

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Photoisomerization LB Monolayer Films Mixed with Fatty Acid and Phospholipid at Difference Mixture Ratio (지방산과 인지질의 혼합 단분자 LB막의 혼합비에 따른 광이성질화에 관한 연구)

  • Kang, Dong-Wan;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.3
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    • pp.178-182
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    • 2000
  • We have investgated UV-Vis absorbance to observe the photoisomerization using the mixture solutions in chloroform and LB monolayers mixed with DLPE and 8A5H containing azobenzene which showed reversible cis-trans photoisomerization irradiated by alternate lights. We have found that the absorbance spectrums of the mixture solutions and LB monolayers were reversibly induced to cis-trans photoisomerization irradiated by alternate lights. In addition, the absorbance of both solution and LB monolayer mixed with 8A5H and DLPE were reversibly by alternate temperatures. As a results, the 1:1(by volume) mixture ratio of 8A5H and DLPE was more flexible and reversible cis-trans photoisomerization than the others.

Parallel Operation of Trans-Z-Source Network Full-Bridge DC-DC Converter for Wide Input Voltage Range

  • Lee, Hyeong-Min;Kim, Heung-Geun;Cha, Hon-Nyong
    • Journal of international Conference on Electrical Machines and Systems
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    • v.1 no.2
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    • pp.98-104
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    • 2012
  • This paper presents a novel transformer isolated parallel connected full-bridge dc-dc converter using recently developed trans-Z-source network. Unlike the traditional voltage -fed or current-fed converters, the proposed converter can be open- and short-circuited without damaging switching devices. Therefore, the desired buck and boost function can be achieved and the converter reliability can be greatly improved. A 6 kW prototype dc-dc converter is built and tested to verify performances of the proposed converter.

A 3.3-V Low-Power Compact Driver for Multi-Standard Physical Layer

  • Park, Joon-Young;Lee, Jin-Hee;Jeong, Deog-Kyoon
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.7 no.1
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    • pp.36-42
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    • 2007
  • A low-power compact driver for multistandard physical layer is presented. The proposed driver achieves low power and small area through the voltage-mode driver with trans-impedance configuration and the novel hybrid driver,. In the voltage-mode driver, a trans-impedance configuration alleviates the problem of limited common-mode range of error amplifiers and the area and power overhead due to pre-amplifier. For a standard with extended output swing, only current sources are added in parallel with the voltage-mode driver, which is named a 'hybrid driver'. The hybrid architecture not only increases output swing but reduces overall driver area. The overall driver occupies $0.14mm^2$. Power consumptions under 3.3-V supply are 24.5 mW for the voltage-mode driver and 44.5 mW for the hybrid driver.

Synthesis of the 7,8-Dihydro-7-deazapurine Derivatives and Their Antibiotic Activity

  • Sung, Sun-Young;Sin, Kwan-Seog
    • Archives of Pharmacal Research
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    • v.21 no.2
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    • pp.187-192
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    • 1998
  • The cis- and trans-diastereomers of the 7,8-dihydro-7-deazapurine derivatives were synthesized from the corresponding diastereomers of 4-tran5-cyano-2-methyl-3-phenyl-5-oxopyrrolidine (5), which were reduced from the 2-cis- and 2-tran5-diastereomers of 4-trans-cyano-2-hydroxymethyl-3-phenyl-5-oxopyrrolidine (2) via tosylation, iodination and following elimination respectively. The prepared cis- and ttans-diastereomers of 6-amino-2-mercapto-8-methyl-7-phenyl-7,8-dihydro-7(9H)-deazapurine (8) were transferred to the corresponding 2-methylthio-diastereomers 9 and following desulfurization with Raney-nickel leaded to the cis and trans-diastereomers of 6-amino-8-methyl-7-phenyl-7,8-dihydro-7(9H)-deazapurine (10), respectively. The synthesized 7-deazapurine derivatives were tested for their antibiotic activity by the serial two-fold dilution method.

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Defining 'Islamic' Urbanity Through A Trans-Regional Frame

  • Mukhopadhyay, Urvi
    • Asian review of World Histories
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    • v.3 no.1
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    • pp.113-135
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    • 2015
  • The word 'urbanity' literally means 'quality or state of being urban' where the criterion of urban economic and civic culture is assumed despite the general celebration of cultural uniqueness of urban centers. The narratives celebrating the uniqueness of urban centers since the ancient past till recent times could not get rid of the broad categorization of the urban models depending on their contextual networks of trade, mobility and culture. This paper attempts to explore whether the urban cultures in South Asia even preceding a global phenomenon like colonialism were actually reflecting an idea of urbanity where the urban culture, including planning and architecture reflected a trans-national model. This paper particularly concentrates on the medieval period when a pattern of urbanity took shape in this subcontinent under the influence of Islam, which could be explained by its particular idea of urban model, cultural exchange and vibrant trade networks.

A single-carrier comparison PWM for Voltage Control of Vienna Rectifier (단일 반송파를 이용한 비엔나 정류기의 전압 제어)

  • Yoon, Byung-Chul;Kim, Hag-Wone;Cho, Kwan-Yuhl;Lim, Byung-Kuk
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.2
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    • pp.129-134
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    • 2012
  • In this paper, a new simple PWM method for Vienna rectifier is proposed. The previous SVPWM method for Vienna rectifier is very complex and difficult to implement. To solve these problems, a new single-carrier comparison PWM method for voltage control of Vienna rectifier is proposed. Because of using the only single carrier, implementation of the proposed PWM is very simple. In the proposed PWM method, carrier comparison parts of the PWM block is only changed from the 2 level PWM control block. The usefulness of the proposed PWM method is verified by the simulation and experiment.

DFT Study for Azobenzene Crown Ether p-tert-Butylcalix[4]arene Complexed with Alkali Metal Ion

  • Park, Seong-Jun;Choe, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.541-545
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    • 2008
  • Stable molecular isomers were calculated for the azobenzene crown ether p-tert-butylcalix[4]arene (1) in the host and their alkali-metal-ion complexes. The structures of two distinct isomers (cis and trans) have been optimized using DFT B3LYP/6-31G(d,p) method. Trans isomer of 1 is found to be 11.69 kcal/mol more stable than cis analogue. For two different kinds of complexation mode, the alkali-metal-cation in the crown-ether moiety (exo) has much better complexation efficiency than in the benzene-rings (endo) pocket for both isomers of 1. Sodium ion has much better complexation efficiency than potassium ion in all kinds of complexation mode with host 1. The Na+ complexation efficiency of the trans-complex (1) in the exo-binding mode is 8.24 kcal/mol better than cis-exo analogue.

Cytotoxic Anthraquinones and Stilbenes from Reynoutria sachalinensis (Fr. Schm.) Nakai

  • Jin, Wenyi;Na, Min-Kyun;Song, Gyu-Yong;Lee, Young-Mi;Bae, Ki-Hwan
    • Korean Journal of Medicinal Crop Science
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    • v.13 no.2
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    • pp.80-84
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    • 2005
  • Five known anthraquinones, physcion (1), I-O-methylemodin (2), emodin (3), $physcion-8-O-{\beta},-D-glucopyranoside$ (5), $emodin-8-O-{\beta},-D-glucopyranoside$ (6) and two known stilbenes, trans-resveratrol (4), $trans-resveratrol-3-O-{\beta},-D-glucopyranoside$ (7) were isolated from MeOH extract of Reynoutria sachalinensis (Polygonaceae). All structures were unambiguously established by 1D and 2D NMR and MS data and the compounds were evaluated for their cytotoxicity against L1210, HL-60, BI6F10 tumor cell lines in MTT assay. Among the compounds, trans-resveratrol (4) exhibited significant cytotoxic activity with $IC_{50}$ values of 9.2, 6.7 and $9.8\;{\mu}g/ml$, against the test cell lines respectively, but compounds 1-3 exhibited the moderate cytotoxic activity.

Competitive Advantages and Disadvantages of Trans-Siberian Railway Route -Case study of Korea and Japan-

  • Tsuji, Hisako
    • International Journal of Railway
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    • v.6 no.4
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    • pp.139-147
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    • 2013
  • TSR (Trans-Siberian Railway) route is losing price competitiveness versus Deep Sea route in the transportation from East Asia to Europe, including Moscow. To further attracting the containers to the TSR route, it will be necessary (1) to keep competitive through rate, linked to fluctuating Deep Sea rate; (2) to strengthen speed advantage; (3) to enforce seamless transportation system, including simplified customs clearance procedures. In transportation to Central Asia from East Asia (Korea and Japan), TSR is competitive versus TCR (Trans-China Railway), depending on destinations. Korea has been the leader in revitalizing the TSR route since 2000. Key contributors were affluent export containers to Russia and Central Asia, port of Busan, efficient maritime transport network to Far East Russia, and Korean forwarders' persistent efforts for activating the market. Korea and Japan have a possibility of cooperation in using the TSR route efficiently, such as organizing a joint block train to a same destination.

Corrosolin and Compound-2: Cytotoxic Annonaceous Acetogenins from the Seeds of Annona cherimolia (Corrosolin 및 Compound-2 : Annona cherimolia 씨앗으로부터 분리된 세포독성 Annonaceous acetogenin)

  • 김달환;우미희
    • YAKHAK HOEJI
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    • v.43 no.5
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    • pp.584-590
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    • 1999
  • Bioactivity-directed fractionation from the seeds of Annona cherimolia resulted in the isolation of two known cytotoxic compounds : corrosolin (1) and compound-2 (2). The structures of these compounds were characterized on the basis of chemical and spectral data. Corrosolin has a relative stereochemical relationship of threo/trans/threo for the mono-tetrahydrofuran (THF) ring with two flanking hydroxyls, from C-15 to C-20, which is the annonacin type. Compound-2 has a relative stereochemical relationship of threo/trans/threo/trans/threo for the adjacent bis-THF ring with two flanking hydroxyls, such as in the asimicin type. The absolute configurations of carbinol carbons in corrosolin in corrosolin were determined as 10R, 15R, and 20R by analysis of its Mosher ester derivatives. Corrosolin and compound-2 are known, but are first isolated in this plant.

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