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Relationship between Deodorizing Condition and Production of Trans Fatty Acids in Soybean Oil (대두유의 탈취조건과 trans 지방산 생성의 상관관계)

  • Kim, Duk-Sook;Lee, Keun-Bo
    • Journal of the Korean Society of Food Culture
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    • v.21 no.2
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    • pp.166-170
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    • 2006
  • Soybean oil (SBO) was carried out deodorization at 4 factors as controlled maximum deodorizing temperature (DT), vacuum degree (VD), cycle time (CT) and treating amount of stripping steam (TASS). The results were as follows, acid value (AV), peroxide value (PV) and trans fatty acid content (TFAC) in produced deodorized SBO. Obtained deodorized SBO at high DT had the lower AV, PV, but TFAC was increased relatively. A suitable level of VD and TASS was 4.0 torr and 2.0%(w/w), than the longer CT was appeared a superior quality level. As a result, the best deodorizing conditions in SBO for lower TFAC were maximum DT; $235^{\circ}C$, VD;4.0torr, CT; $14{\sim}15min$ and TASS; 2.0% (w/w). Deodorizing conditions for lower TFAC in deodorizing of SBO was the major factor, more than lower DT was difficult because of the others quality factors.

Analysis of trans-Resveratrol Contents of Grape and Grape Products Consumed in Korea (포도와 포도 가공품에 함유되어 있는 trans-resveratrol의 함량 분석)

  • Kim, Dae-Jung;Kim, Sang-Kyun;Kim, Myung-Hee;Lee, Hee-Bong;Lee, Jun-Soo
    • Korean Journal of Food Science and Technology
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    • v.35 no.5
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    • pp.764-768
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    • 2003
  • Resveratrol is natually occurring phytoalexin compounds produced by grape berries, peanuts, and their products in response to stress such as fungal infection, heavy metal ions or UV irradiation. The objective of this study was to develop a reliable high-performance liquid chromatographic method for the quantitative determination of trans-resveratrol in grape and its products. The trans-resveratrol was separated isocratically on Nucleosil 100-5 C18 column, using a mobile phase containing acetonitrile : water (40 : 60, v/v), detected by UV detector at 306 nm and the flow rate was 0.3 mL/min. Under this analytical condition, the recoveries of trans-resveratrol in grape, wine, and grape juice were 92.35, 104.72, and 91.08, respectively. Limit of detection in grape, wine, and grape juice were 14.5 ng/g, 3.62 ng/mL, and 4.02 ng/mL. Also, limit of quantitation in grape, wine, and grape juice were 14.8 ng/g, 3.69 ng/mL, and 4.10 ng/mL. Assay values of 32 grape varieties, 9 wines, and 9 grape juices were ranged from trace amount to $207.1\;{\mu}g/100\;g$, from 5.4 to $275.7\;{\mu}g/L$, and from 63.3 to $751.6\;{\mu}g/L$, respectively.

Analysis and Comparison of Cerebroside Components from Soybean Fermented Foods (대두발효식품 Cerebroside의 구성성분 분석 및 비교)

  • 이은열;김희숙
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.2
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    • pp.177-183
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    • 2002
  • Cerebroside fatty acids, sugars and long-chain sphingoid bases in raw soybean and soybean fermented foods (chongkukjang and deunjang) were analyzed using gas chromatography-mass spectrometry (GC-MS) and high-pH anion exchange chromatography with pulsed amerometric detection (HPAEC-PAD). Fatty acids of acid-hydrolyzed cerebrosides were derivatized to O-TMS methylester and analysed. The major fatty acids in raw soybean and chongkukjang cerebrosides were identified as 2-hydroxyhexadecanoic acid (16 : 0h), 2-hydroxydocosanoic acid (22 : 0h) and 2-hydroxytetracosanoic acid (24 : 0h). In the case of deunjang cerebroside, 24 : 0h (40.9%) and 22 : 0h (23.4%) were major fatty acids, but 16 : 0h, 23 : 0h, 25 : 0h and 26 : 0h were also detected. Long-chain sphingoid bases of acid-hydrolyzed cerebrosides from raw soybean, chongkukjang and deunjang consisted primarily of 4-tracts, 8-tracts-sphingadienine (dihydroxy base, d18 : 2$\Delta$$^{4trans, 8trans}$) and sis-tracts isomers of 4-hydroxy-sphingenine (trihydroxy base, tl8:1$\Delta$$^{4trans or cis}$) with much less amounts of phytosphingosine (tl8: 0) and isomers of sphingenine (d18 : 1). Although deunjang is a soybean food fermented by fungi and microorganisms for a long period, 2-hydroxyoctadec-3-enoic acid (18 : 1h) and branched 9-methyl-4,8-sphingadienine known as compositional cerebroside fatty acids in Aspergillus species were not detected. Mass spectrum for sugar derivatives in cerebrosides of soybean foods including raw soybean and fermented soybean showed that C-1 of glucose moiety was linked to ceramide backbone as like a monoglucosylceramide.

The Properties & Limits of Trans-media Contents in TRAIN TO BUSAN and SEOUL STATION: Focusing on the Multimedia expansion of 'Possible Worlds' (<부산행>과 <서울역>에 나타난 트랜스미디어 콘텐츠의 속성과 한계: '가능 세계'의 멀티미디어적 확장을 중심으로)

  • Huh, Eunhee
    • Journal of Korea Multimedia Society
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    • v.23 no.8
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    • pp.1118-1127
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    • 2020
  • Train to Busan(2016) and Seoul Station(2016) contain trans-media properties in terms of the expansion of 'possible worlds' from the original story, and show the cultural and economic potential of the domestic trans-media contents with industrial systems added to the artist's competence of Dir. Yeon Shang-ho, an animator and film director. But they also have limits of the lack of continuity in time and characters between each media, various derived contents and suitable marketing strategy. For the development of Korean trans-media contents, it is necessary to extend the range of contents, find changes in production time and style, and improve the distribution environment to encourage a user to integrate contents from each platforms.

Interaction of a 22 kDa Peptidyl Prolyl cis/trans Isomerase with the Heat Shock Protein DnaK in Vibrio anguillarum

  • Kang, Dong Seop;Moon, Soo Young;Cho, Hwa Jin;Lee, Jong Min;Kong, In-Soo
    • Journal of Microbiology and Biotechnology
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    • v.27 no.3
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    • pp.644-647
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    • 2017
  • Peptidyl prolyl cis/trans isomerases (PPIases) catalyze the cis/trans isomerization of peptidyl-prolyl peptide bonds preceding prolines. We investigated the protein-protein interaction between a 22 kDa PPIase (VaFKBP22, an FK506-binding protein) and the molecular chaperone DnaK derived from Vibrio anguillarum O1 (VaDnaK) using GST pull-down assays and a bacterial two-hybrid system for in vivo and in vitro studies, respectively. Furthermore, we analyzed the three-dimensional structure of the protein-protein interaction. Based on our results, VaFKBP22 appears to act as a cochaperone of VaDnaK, and contributes to protein folding and stabilization via its peptidyl-prolyl cis/trans isomerization activity.

Sharp-Line Electronic Spectroscopy and Ligand Field Analysis of [Cr(trans-diammac)](ClO4)3 1

  • Choi, Jong-Ha;Oh, In-Gyung
    • Bulletin of the Korean Chemical Society
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    • v.18 no.1
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    • pp.23-27
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    • 1997
  • The luminescence and excitation spectra of [Cr(trans-diammac)](ClO4)3 (trans-diammac=trans-6, 3-dimethyl-l, 4, 8, 11-tetraazacyclotetradecane-6, 13-diamine) taken at 77 K are reported. The mid and far-infrared spectra at room-temperature are also measured between 4000 cm-1and 50 cm-1. In the excitation spectrum the 2Eg components are splitted by 102 cm-1. Using the observed electronic transitions, a ligand field analysis was performed to determine more detailed bonding properties of the coordinated atoms toward chromium(Ⅲ). According to the results, we can confirm that the six nitrogen atoms have a strong σ-donor character, and the trans-diammac secondary amine has a greater value of eσ than does the primary amine.

η-Ricci Solitons in δ-Lorentzian Trans Sasakian Manifolds with a Semi-symmetric Metric Connection

  • Siddiqi, Mohd Danish
    • Kyungpook Mathematical Journal
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    • v.59 no.3
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    • pp.537-562
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    • 2019
  • The aim of the present paper is to study the ${\delta}$-Lorentzian trans-Sasakian manifold endowed with semi-symmetric metric connections admitting ${\eta}$-Ricci Solitons and Ricci Solitons. We find expressions for the curvature tensor, the Ricci curvature tensor and the scalar curvature tensor of ${\delta}$-Lorentzian trans-Sasakian manifolds with a semisymmetric-metric connection. Also, we discuses some results on quasi-projectively flat and ${\phi}$-projectively flat manifolds endowed with a semi-symmetric-metric connection. It is shown that the manifold satisfying ${\bar{R}}.{\bar{S}}=0$, ${\bar{P}}.{\bar{S}}=0$ is an ${\eta}$-Einstein manifold. Moreover, we obtain the conditions for the ${\delta}$-Lorentzian trans-Sasakian manifolds with a semisymmetric-metric connection to be conformally flat and ${\xi}$-conformally flat.

Homogeneous Catalysis (IV). Hydrogenation of Acrylonitrile with trans-Chlorocarbonylbis(triphenylphosphine)rhodium(I)

  • Woo, Jin-Chun;Chin, Chong-Shik
    • Bulletin of the Korean Chemical Society
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    • v.4 no.4
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    • pp.169-171
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    • 1983
  • It has been found that the acrylonitrile solution of trans-$RhCl(CO)(Ph_3P)_2$ produces propionitrile catalytically at $90^{\circ}C$ under $P_{H_2}$=3 atm. This catalytic hydrogenation proceeds only for a certain period of time producing ca. 50 moles of propionitrile per mole of the rhodium complex. The hydrogenation with trans-$RhCl(CO)(Ph_3P)_2$ in the presence of formaldehyde is much faster than in the absence of formaldehyde, and continues without a decrease in the rate for a prolonged period of time. It is suggested that the hydrogenation with trans-$RhCl(CO)(Ph_3P)_2$ proceeds through the unsaturated route initiated by the dissociation of CO from trans- $RhCl(CO)(Ph_3P)_2$ to give coordinatively unsaturated $RhCl(Ph_3P)_2$.

NON-INVARIANT HYPERSURFACES OF A (𝜖, 𝛿)-TRANS SASAKIAN MANIFOLDS

  • Khan, Toukeer;Rizvi, Sheeba
    • Nonlinear Functional Analysis and Applications
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    • v.26 no.5
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    • pp.985-994
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    • 2021
  • The object of this paper is to study non-invariant hypersurface of a (𝜖, 𝛿)-trans Sasakian manifolds equipped with (f, g, u, v, λ)-structure. Some properties obeyed by this structure are obtained. The necessary and sufficient conditions also have been obtained for totally umbilical non-invariant hypersurface with (f, g, u, v, λ)-structure of a (𝜖, 𝛿)-trans Sasakian manifolds to be totally geodesic. The second fundamental form of a non-invariant hypersurface of a (𝜖, 𝛿)-trans Sasakian manifolds with (f, g, u, v, λ)-structure has been traced under the condition when f is parallel.

Trans Fatty Acid Isomers of Processed Foods Commonly Consumed in Korea (한국인 상용 가공식품의 trans 지방산 이성체)

  • 노경희;원미숙;송영선
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.3
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    • pp.325-337
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    • 2003
  • This study was designed to determine the distribution of trans fatty acids (tFAs) isomers of Processed foods commonly consumed in Korea. The tFAs positional isomers were analyzed using GC/MS spectrometer with HP-23 cis/trans FAME, capillary column (50m $\times$ 0.20 mm, id., 0.2 ${\mu}{\textrm}{m}$ film thickness) for 41 food samples. TFAs isomers were identified by comparing retention time with standards and GC/MS spectrum. In margarines, the content of tFAs ranged from 4.0% to 25.16% and the most abundant positional isomer of tFAs was C18:1 $\Delta$9t. In oils and fats, lards contained higher levels of tFAs (5.70~16.54%) than shortenings (6.77~10.55%). Shortenings contained higher levels of C18:1 $\Delta$9t (3.1~5.1%) than lard (1.6~4.3%), but corn oils had no tFAs. In seasonings, mayonnaise had no C16:1 $\Delta$9t, whereas C18:3t was detected. The content of tFAs in confectioneries was wide (16.20~52.16%). Among them, instant popcorns contained the highest amount of tFAs. Milk and dairy products showed even distribution of tFAS such as C18:1t, C18:2t, and C18:3t. Predominant tFAS isomer of condensed milk and ice cream was C16:1 $\Delta$9t. Frozen french fries and fried chicken contained higher levels of C18:1$\Delta$9t (9.4%), whereas grilled pork (jowl) had no C18:1 $\Delta$9t. The amount of tFAs per serving size was the highest in popcorn, followed by frozen pizza, frozen french fries, fried chicken, and bakeries.