DOI QR코드

DOI QR Code

Relationship between Deodorizing Condition and Production of Trans Fatty Acids in Soybean Oil

대두유의 탈취조건과 trans 지방산 생성의 상관관계

  • Kim, Duk-Sook (Dept. of Food Science and Technology, Seoil College) ;
  • Lee, Keun-Bo (Dept. of Food Science and Technology, Seoil College)
  • Published : 2006.04.30

Abstract

Soybean oil (SBO) was carried out deodorization at 4 factors as controlled maximum deodorizing temperature (DT), vacuum degree (VD), cycle time (CT) and treating amount of stripping steam (TASS). The results were as follows, acid value (AV), peroxide value (PV) and trans fatty acid content (TFAC) in produced deodorized SBO. Obtained deodorized SBO at high DT had the lower AV, PV, but TFAC was increased relatively. A suitable level of VD and TASS was 4.0 torr and 2.0%(w/w), than the longer CT was appeared a superior quality level. As a result, the best deodorizing conditions in SBO for lower TFAC were maximum DT; $235^{\circ}C$, VD;4.0torr, CT; $14{\sim}15min$ and TASS; 2.0% (w/w). Deodorizing conditions for lower TFAC in deodorizing of SBO was the major factor, more than lower DT was difficult because of the others quality factors.

대두유의 탈취과정에서 탈취온도, 진공도, cycle time 및 stripping steam 주입량의 4대 요소를 조정하여 탈취를 행한 후 탈취유의 산가, 과산화물가 및 trans 지방산 함량을 측정한 결과는 다음과 같았다. 즉, 탈취온도가 높을수록 AV, POV는 하락하였으나 trans 지방산 함량이 비례적으로 증가하였다. 진공도는 4torr 수준이 적정하였으며, CT는 길어질수록 효과가 우수하였다. SS주입량은 2.0%(w/w) 수준이 가장 적절한 조건이었다. 이러한 결과를 종합적으로 볼 때, 대두유에서 trans 지방산 함량을 상대적으로 낮게 할 수 있는 탈취조건은 최고 탈취온도 $235^{\circ}C$, 진공도 4torr, CT $14{\sim}15$분 및 SS주입량 2.0%(w/w)내외의 조건에서 trans 지방산 함량 0.31% 내외의 우수한 탈취유의 생산이 가능하였다. 결과적으로 탈취과정에서 trans 지방산 생성량을 극소화하기 위하여는 탈취온도가 가장 중요하였는데, AV, POV 등 다른 품질 요인들을 동시에 고려할 때, 더 이상의 탈취온도 하락은 어려운 것으로 판단된다.

Keywords

References

  1. American Oil Chemists Society. 1989. Official Method and Recommended Practice of AOCS, 4th. Ed
  2. Athanassiadis, A. 1991 Emerging technology in deodorization: Lecture presented at the AOCS meeting in Chicago, Illinois, the 15th May. 115
  3. Cheon, JH. 1986. Manufacturing principle and practice of soybean oil, Korea Advanced Institute and Science Technol. & Korean Society of Food Science and Technol
  4. David, RE, Everette, HP, Ordean, LB, Timothy, LM, Richard, AF. 1980. Handbook of soy oil processing and utilization, Am. Soybean Association and the Am. Oil Chem. Soc, Illinois, p. 155-188
  5. De Greyt, WF, Kellens, MJ, Huyghebaert, AD. 1999. Effect of physical refining on selected minor components in vegetable oils, Lipid/Fett, 101(3): 428-432 https://doi.org/10.1002/(SICI)1521-4133(199911)101:11<428::AID-LIPI428>3.0.CO;2-T
  6. Emken, EA. 1984. Nutrition and biochemistry of trans and positional fatty acid isomers in hydrogenated oils, Annu. Rev. Nutr, 4(2): 339-343 https://doi.org/10.1146/annurev.nu.04.070184.002011
  7. Ernesto B. 1983. Vegetable oils and fats processing (Vol. II) Oilseed, oils and fats, Interstampa, Rome, p.221-252
  8. Jandacek, R. 1994. Structured lipids : An overview and comments on performance enhancement potential. Food components to enhance performance, National Academy Press, p.351-379
  9. Kim, DS. 1994. Effects of deodorizing conditions on the color of final products in evening primrose oil, Collection of learned papers of Seoiljunior college, 12: 363-368
  10. Kim, DS. 2004. Risk and minimization project of trans fatty acids in edible fats & oils and its products, J. Food Industry, 182: 24-43
  11. Kim, DS, Lee, KB. 2005. Effect of deodorizing conditions on color in soybean oil, Korean J. Dietary Culture, 20(5), 627-635
  12. Kim, JI. 2003. Effects of deodorization step on formation of trans fatty acids and contents of tocopherol during industrial refining process of soybean oil, Thesis of master degree of Graduate School in Yonsei University
  13. Lee, KB, Han, MK, Lee, MS. 1998. Effect of deodorizing temperature on physicochemical characterisitcs in corn oil. 3. Effect of deodorizing temperature on trans fatty acid formation in corn oil, Korean J. Food Nutr., 11(1): 26-30
  14. Lee, KB, Hong, M, Han, MK, Lee, MS. 1997. Effect of deodorizing temperature on physicochemical characterisitcs in corn oil. 1. Effect of deodorizing temperature on fatty acid and triglyceride composition in corn oil, Korean J. Dietary Culture, 12(2): 189-193
  15. Lee, KB, Han, MK, Lee, MS. 1998. Effect of deodorizing temperature on physicochemical characterisitcs in corn oil. 2. Effect of deodorizing temperature on cold test and smoke point in corn oil, Korean J. Food Nutr., 11(1): 6-10
  16. Lee, KB, Han, MK, Lee, MS. 1998. Effect of deodorizing temperature on physicochemical characterisitcs in corn oil. 4. Effect of deodorizing temperature on volatile flavor component corn oil, Korean J. Food Nutr., 11(3): 272-277
  17. Matthias, S. 1983. Trans unsaturated fatty acids in natural products and processed Foods, Prog. Lipid Res., 21(2): 221-226
  18. Moore, EA. 1984. Effects of trans fatty acids on tissue lipids and lecithin: Cholesterol acyltransferase, Health Sci. Nutr, Dissertation Abstracts International, 40(2): 215-220
  19. Privett, OO, Phillips, F, Shimasaski M, Nazawa T, Nickell EC. 1977. Studies of effects of trans fatty acids in the diet on lipid metabolism in essential fatty acid deficient rats, Am. J. Clin., 30(1): 100-104
  20. Robert, LA. 1967. Oxidation of the geometric isomer of A9-octadecanoic acid be rat-liver mitochondria, Biochem. Biophys. Acta, 144(1): 68-72
  21. Shimp JL. 1981. The effects of trans fatty acids on essential fatty acid metabolism, Food Sci. Technol, 42(2): 261-266
  22. Quinlan. P. 1998. Modification of triglycerides by lipases: process technology and its application to the production of nutritionally improved fats, INFORM, 4(2): 271-276