• Nuclear Engineering and Technology
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• v.54 no.6
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• pp.2230-2243
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• 2022

The tin tailing processing industry in Malaysia has operated with minimal regard and awareness for material management and working environment safety, impacting the environment and workers in aspects of radiation and heavy metal exposure. RIA was conducted where environmental samples were analyzed, revealing concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K between the range of 0.1-10.0, 0.0-25.7, and 0.1-5.8 Bq/g respectively, resulting in the AED exceeding UNCEAR recommended value and regulation limit enforced by AELB (1 mSv/y). Ra_eq calculated indicates that samples collected pose a significant threat to human health from gamma-ray exposure. Assessment of heavy metal content via pollution indices of soil and sediment showed significant contamination and enrichment from processing activities conducted. As and Fe were two of the highest metals exposed both via soil ingestion with an average of 4.6 × 10^-3 mg/kg-day and 1.4 × 10^-4 mg/kg-day, and dermal contact with an average of 5.6 × 10^-4 mg/kg-day and 6.0 × 10^-4. mg/kg-day respectively. Exposure via accidental ingestion of soil and sediment could potentially cause adverse non-carcinogenic and carcinogenic health effect towards workers in the industry. Correlation analysis indicates the presence of a relationship between the concentration of NORM and trace elements.

• Journal of Soil and Groundwater Environment
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• v.27 no.1
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• pp.39-49
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• 2022

Bottom ash generated from thermal power plants is mainly disposed in landfills, from which metals may be leached by infiltrating water. To evaluate the effect of metals in leachate on soil and groundwater, we characterized bottom ash generated from burning cokes, bituminous coal, the mixture of bituminous coal and wood pellets, and charcoal powder. The bottom ash of charcoal powder had a relatively large particle size, and its wood texture was well-preserved from SEM observation. The bottom ash of charcoal powder and wood pellets had relatively high K concentration from total element analysis. The eluates of the bottom ash samples had appreciable concentrations of Ca, Al, Fe, SO₄, and NO₃, but they were not a significant throughout the batch test. Therefore, it is considered that there is low possibility of soil and groundwater contamination due to leaching of metal ions and anions from these bottom ash in landfills. To estimate the trend of various trace elements, long-term monitoring and additional analysis need to be performed while considering the site conditions, because they readily adsorb on soil and aquifer substances.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.3
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• pp.148-154
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• 1998

Gubong gold-mine, previously one of the largest gold mines in Korea, is located at the mid-west of the South Korea. In the areas nearby the mine, the shallow groundwater was the major source for domestic and farming water-supply. Soil contamination by Cd, Cu, Pb and Zn was previously known in this area. This study is objected to identify quality of the shallow groundwater, possibly affected by the mine tailings. Samples were collected from a nearby stream, shallow groundwater and seepage from the tailings. Chemical analysis for the water quality includes major cations such as Na, K, Ca, and Mg, anions as F, Cl, NO$_3$, SO$_4$, HCO$_3$, and trace elements as Al, Cr, Mn, Fe, Ni, Cu, Zn, Cd, Pb, Se, As, Hg. Water types could be drawn into four groups from the plots of Piper, Stiff diagrams and cluster analysis. SAR-Conductivity plot indicates the water does not pose either alkalinity or salinity hazards for irrigation. Major contaminant in groundwater appeared to be arsenic, released from arsenopyrites in tailings by oxidation. Dredging of buried railing materials could stimulate the release of arsenic from the sediments to the groundwater.

• Steel and Composite Structures
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• v.52 no.2
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• pp.199-215
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• 2024

The Caynarachi Bridge is a 130 m long posttensioned steel-concrete composite bridge built in Peru. The structural performance of this bridge under construction loads is reviewed in this paper using numerical simulation. Hence, a numerical model using shell finite elements to trace its deformational behavior at service conditions is proposed. The geometry and boundary conditions of the superstructure are updated according to the construction schedule. Firstly, the adequacy of the proposed model is validated with the field measurements obtained from the static truck load test. Secondly, the study of other scenarios less explored in research are performed to investigate the effect of some variables on bridge performance such as time effects, sequence of execution of concrete slabs and type of supports conditions at the abutments. The obtained results show that the original sequence of execution of the superstructure better behaves mechanically in relation to the other studied scenarios, yielding smaller stresses at critical cross sections with staging. It is also demonstrated that an improper slab staging may lead to more critical stresses at the studied cross sections and that casting the concrete slab at the negative moment regions first can lead to an optimal design. Also, the long-term displacements can be accurately predicted using an equivalent composite resistance cross section defined by a steel to concrete modulus ratio equal to three. This article gives some insights into the potential shortcomings or advantages of the original design through high-fidelity finite element simulations and reinforces the understating of posttensioned composite bridges with staging.

• Journal of Conservation Science
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• v.30 no.3
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• pp.249-261
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• 2014

This study aims to examine production technique of white wares from the Guyre-2ri 1st and 2nd kiln sites, Wonju, Gangwon Province and characteristics of the used materials, and to find a correlation among materials of the excavated white wares. X-ray fluorescence sequential spectroscopy(XRF), X-ray diffraction(XRD), Dilatometer and Inductively coupled plasma mass spectrometry(ICP-MS), Inductively coupled plasma automic emission spectrometer(ICP-AES) were applied to determine the chemical composition, crystalline phase of samples, firing temperatures, trace elements and rare earth elements. White wares from the Guyre-2ri kiln sites contained high contents of coloring oxides and fluxes. Though firing temperature of each sample was different, they were mostly fired at a temperature below $1200^{\circ}C$ and some of them experienced a low temperature of $1000^{\circ}C{\pm}20^{\circ}C$ and a high temperature above $1200^{\circ}C$. When analyzing body crystalline phases of the white wares using the XRD method, quartz and mullite were extracted from all the samples, and the proportions were similar to each other. When analyzing the excavated white wares using the Seger formula, also, all the samples showed similar clay sources and production techniques. Moreover, the white wares were made of host rocks of the same geological origin, according to the result of rare earth elements analysis.

• Analytical Science and Technology
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• v.11 no.4
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• pp.271-280
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• 1998

Rice flour reference materials were prepared from the unpolished rice grown in Korea and certified for elemental composition. The reference materials consist of two samples containing normal and high level. The reference material at elevated level was prepared by spiking to the normal rice flour six toxic elements of As, Cd, Cu, Cr, Hg, Pb with $1.0{\mu}g/g$ on a dry weight basis. Homogeneity of the prepared materials was evaluated through the determination of Ca, Cu, Fe, Mn, Zn by instrumental neutron activation analysis (INAA) and atomic absorption spectrometry (AAS). Small variance of elemental composition among interbottled samples assured homogeneity of the prepared materials. The materials were decomposed by high pressure digestion and microwave digestion method. INAA, AAS, inductively coupled plasma-atomic absorption spectrometry (ICP-AES), ICP-mass spectrometry (MS) and vapour generation techniques were employed to analyze the reference materials. From this independent analytical results, the certified or reference values are determined for As, Ca, Cd, Cr, Cu, Fe, Hg, K, Mg, Mn, Mo, Na, P, Pb, Se, Zn.

• Journal of Conservation Science
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• v.29 no.3
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• pp.261-277
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• 2013

This study aims to research the relationship between whitewares and their rare materials from the site of Yanggu and Bunwon through the componential characteristic of the excavated whitewares from the 1st and the 2nd kilns of Chiljeon-ri in Bangsan-myeon, Yanggu-gun. As a result, the sherds were devided according to the chemical compositions of the body and the glaze via their respective production era. However, it considered that the whitewares from Chiljeon-ri had been manufactured with geochemically similar materials and the production process, such as refining and combining materials, had been different. It assumed that the firing temperatures of the whitewares from Chiljeon-ri were around $1,100-1,200^{\circ}C$ and substantially lower than for general whitewares. In the componential analysis, there were disparate properties in the cobalt pigment, which contained trace elements and rare earth elements. A review of the literature revealed a correlation between the whitewares from the late Chosun kiln site in Bunwon-ri and the raw materials from Yanggu-gun, but this was there were various techniques for refining and combining materials in Bunwon-ri.

• Korean Journal of Heritage: History & Science
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• v.51 no.4
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• pp.224-233
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• 2018

Thirty-three Early Iron Age bronzes at the sites of Hoam-dong in Chungju and Cheongsong-ri in Buyeo were investigated in order to study the manufacturing technique and the provenance of lead. Chemical analysis using X-ray fluorescence showed that 33 bronzes consist of copper(Cu), tin(Sn) and lead(Pb) served as major elements. Major and minor elemental analyses by EPMA were performed on two mirrors and 2 weapons of the bronzes investigated. The results shows that bronze mirrors from Chungju and Buyeo were high-tin bronzes(> 30 wt%). And 20% of tin and 5% of lead were founded in bronze weapons. Iron, zinc, arsenic, silver, nickel, sulfur and cobalt detected in four bronzes as minor and trace elements. The four bronzes were alloyed considering their function and were not heat treated after casting due to their high tin content. Lead isotope analysis using TIMS indicates that thirty-three bronzes were distributed southern Korea peninsula except Zone 1. As a result, lead raw materials came from various regions in Korean Peninsula not from Gyeongsang-do regions. The manufacturing techniques of bronze ware generalized at this age, and bronze was produced in various sites using raw materials from various sources.

• Journal of the Korean Wood Science and Technology
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• v.34 no.4
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• pp.37-45
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• 2006

Recently, wood-framed houses has been built in the Korea for pension. Wood is good material for human healthy, while the construction lumbers are treated with preservative such as CCA (chromated copper arsenate), which contain some toxic elements for human body. However, if the waste woody biomass treated with various heavy metals, which has been collected from house construction or demolition, was fired in the field, and incinerated or landfilled after mass collection, such components will result in the toxic air pollutants in the burning or land fills, and spreaded into other areas. So the careful selection of wood and chemicals are required in advance for house construction, in particular, for environment-friendly housings. Therefore, this study was carried out to determine the content of toxic heavy metals in woody materials such as domestic hinoki and imported hemlock treated with CCA for housing materials, and the post-treated wood components such as organic fertilizer, sludge, dry-distilled charcoal and carbonized charcoal, to be returned finally into soil. The results are as follows. 1) The chemical analysis of toxic trace elements in various solid biomass required accurate control and management of laboratory environment, and reagents and water used, because of the error of data due to various foreign substances added in various processing and transporting steps. So a systematic analyzers was necessary to monitor the toxic pollutants of construction materials. 2) In particular, the biomass treated with industrial biological or thermal conditions such as sludge or charcoals was not fully dissolvable after third addition of $HNO_3$ and HF. 3) The natural woody materials such as organic fertilizer, sludge. and charcoals without any treatment of preservatives or heavy metal components were nontoxic in landfill because of the standard of organic fertilizers, even after thermal or biological treatments. 4) The CC A-treated wood for making the construction wood durable should not be landfilled, because of its higher contents of toxic metals than the criterion of organic fertilizer for agriculture or of natural environment. So the demolished waste should be treated separately from municipal wastes.

• The korean journal of orthodontics
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• v.22 no.3 s.38
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• pp.557-578
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• 1992

Heat treatment which removes internal stress enhances the mechanical properties of the orthodontic arch wire. The main purpose of this experiment was to investigate the effects of the heat treatment on the mechanical properties of the Elgiloy wire. The Elfiloy wire, 0.016' X 0.022' and 0.018' X 0.025', were heat treated in an electric oven for 5, 10 and 15 minutes at selected temperatures between 300 and $900^{\circ}C$. Tensile strength and load deflection rate were measured to reveal the changes of mechanical property at various conditions, and each specimen was observed under metallurgic microscope. Also to trace the precipitation material due to overheat treatment, a qualitative analysis was carried out with EDS system. It was found that heat treatment at a low temperature caused an increase in the tensile strength and bending resistance, and a maintenance in the fibrous in the tensile strength and bending resistance, and a maintenance in the fibrous structure of both sizes of wire. The changes observed in properties and appearance were probably due to the relief of internal stresses incurred in the metal during cold working. In both sizes of wire the tensile strength and the bending resistance continued to decrease at high temperature, and the fibrous structure continued to disappear then was not observed at $900^{\circ}C$. The carbide precipitation founded in grain boundary at $750^{\circ}C$ probably was other elements carbide (Ni, Co) except Cr. The grain growth was observed at $1100^{\circ}C$. Optimum heat treatment for the 0.016' X 0.022' Elgiloy wire was 10 minutes at $500^{\circ}C$, and for the 0.018' X 0.025' Elgiloy wire it was 5 to 15 minutes at $500^{\circ}C$.