• Title/Summary/Keyword: time dependent behavior

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Breakthrough Behavior of Benzene and Toluene in Adsorption Bed (흡착탑에서 벤젠과 톨루엔의 파괴거동)

  • Kang, Sung-Won;Min, Byong-Hoon;Suh, Sung-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.2
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    • pp.83-88
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    • 2000
  • The VOCs(Volatile Organic Compounds) is one of the major cause for the atmosphere pollution. Breakthrough behavior of benzene and toluene in adsorption bed packed with activated carbon was experimentally studied. Composition and temperature of the gas flowing in the bed was measured and breakthrough curves for each component was obtained. Breakthrough time of benzene was earlier than that of toluene due to relatively weak adsorptivity. The relationship between breakthrough time and flow rate was obtained. The shape of temperature change with time was dependent on the position in the bed. Temperature changed faster and sharper in the inlet than in the outlet. It was noted that breakthrough behavior could be affected by the heat transfer properties.

Gender Differences in Problematic Online Behavior of Adolescent Users over Time (남녀 청소년 소비자의 온라인 문제행동 차이에 대한 종단 분석)

  • Kim, Jung Eun
    • Human Ecology Research
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    • v.53 no.6
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    • pp.641-654
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    • 2015
  • This study identifies and tracks changes gender differences in adolescent users' problematic online behavior. This study used Korea Youth Panel Survey (KYPS), which has tracked respondents over 7 years, with self-control theory and social learning theory applied as a theoretical framework. The model included individual-level variables such as self-control and respondent's experience of problematic behavior (offline), as well as socialization variables such as the number close friends who engaged in problematic offline behavior, parent-child relationships, and parental monitoring. Dependent variables included problematic online behavior, unauthorized ID use (ID theft) and cyberbullying (cursing/insulting someone in a chat room or on a bulletin board). Control variables consisted of academic performance, time spent on a computer, monthly household income, and father's educational attainment. Random and fixed effects models were performed by gender. Results supported self-control theory even for the within-level analysis (fixed effects models) regardless of gender, while social learning theory was partially supported. Only peer effects were found significant (except for unauthorized ID use) among girls. Year dummy variables showed significant negative associations; however, academic performance and time spent using computers were significant in some models. Father's educational attainment and monthly household income were found insignificant, even in the random effects models. We also discuss implications and suggestions for future research and policy makers.

Dissolution Characteristics of ph-Dependent Antacid Granules Agglomerated in High Speed Agitation Type Speed Agitation Type Granulator

  • Choi, Woo-Sik;Lee, Jung-Sun
    • Archives of Pharmacal Research
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    • v.18 no.5
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    • pp.314-319
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    • 1995
  • Antacid granules were prepared by agglomeration and powder method in high speed agitation type granulator. The copmositions of the test antacids were sodium bicarbonate nad magnesium carbonate nad a coating material was powder of polyvinylacetal diethyl-aminocacetate (AEA) and an additive material was talc powder. The dissolution characteristics of base from the antacid granules were investigated to evaluate neutralization capacity of hydrochloric profile of base and neutralization behavior, the following results were obtained : The prepared granules showed a pH-dependent dissolution pattern of a base. The dissolution profile of a base was varied with addition of talc powder as well as coating amount of AEA. The relationship between the ratio of dissolution retarded time for 20% and 10% AEA. The relationship between the ratio of dissolution retarded time for 20% AEA coated granules $\theta_{20}/\theta_{10}$ and the diameter reduction of the granules was explained by the rate process of neutralization of hydrochloric acid.

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The Effects of Grain Size on the Degradation Phenomena of PZT Ceramics (입자의 크기가 PZT 세라믹스의 열화현상에 미치는 영향)

  • 정우환;김진호;조상희
    • Journal of the Korean Ceramic Society
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    • v.29 no.1
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    • pp.65-73
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    • 1992
  • The effect of grain size on the time-dependent piezoelectrice degradation of a poled PZT of MPB composition Pb0.988Sr0.012 (Zr0.52Ti0.48)O3 with 2.4 mol% of Nb2O5 was studied, and the degradation mechanism was discussed. Changes in the internal bias field and the internal stress both responsible for the time-dependent degradation of poled PZT were examined by the polarization reveral technique, XRD and Vickers indentation, respectively. The piezoelectric degradation increased with increasing time and grain size, and the internal bias field due to space charge diffusion decreased with increasing grain size of poled PZT. The internal bias field, however, was almost insensitive to the degradation time regardless of the grain size. On the other hand, both the x-ray diffraction peak intensity ratio of (002) to (200) and the fracture behavior including the crack propagation support that the ferroelectric domain rearrangement of larger grain size showed rapid relaxation of the internal stress compared with smaller one, which is thought the origin of the larger piezoelectric degradation in the former. In conclusion, the contribution of space charge diffusion on the piezoelectric degradation of PZT is strongly dependent on both the grain size and the composition. Thus, the relaxation of internal stress due to the ferroelectric domain rearrangement as well as the amount and time-dependence of the internal bias field due to space charge diffusion should be considered simultaneously in the degradation mechanism of PZT.

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TIME-DEPENDENT FRACTURE OF ARTICULAR CARTILAGE: PART 1 - THEORY & VALIDATION

  • Mun, M.S.;Lewis, J.L.
    • Proceedings of the KOSOMBE Conference
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    • v.1995 no.05
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    • pp.27-33
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    • 1995
  • A time-dependent large deformation fracture theory is developed for application to soft biological tissues. The theory uses the quasilinear viscoelastic theory of Fung, and particularizes it to constitutive assumptions on polyvinyl-chloride (PVC) (Part I) and cartilage (Part II). This constitutive theory is used in a general viscoelastic theory by Christensen and Naghdi and an energy balance to develop an expression for the fracture toughness of the materials. Experimental methods are developed for measuring the required constitutive parameters and fracture data for the materials. Elastic stress and reduced relaxation functions were determined using tensile and shear tests at high loading rates with rise times of 25-30 msec, and test times of 150 sec. The developed method was validated, using an engineering material, PVC to separate the error in the testing method from the inherent variation of the biological tissues. It was found that the the proposed constitutive modeling can predict the nonlinear stress-strain and the time-dependent behavior of the material. As an approximation method, a pseudo-elastic theory using the J-integral concept, assuming that the material is a time-independent large deformation elastic material, was also developed and compared with the time-dependent fracture theory. For PVC. the predicted fracture toughness is $1.2{\pm}0.41$ and $1.5{\pm}0.23\;kN/m$ for the time-dependent theory and the pseudo-elastic theory, respectively. The methods should be of value in quantifying fracture properties of soft biological tissues. In Part II, an application of the developed method to a biological soft tissue was made by using bovine humeral articular cartilage.

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Numerical analysis of pre-reinforced zones in tunnel considering the time-dependent grouting performance (터널 사전보강영역의 경시효과를 고려한 수치해석 기법에 관한 연구)

  • Song, Ki-Il;Kim, Joo-Won;Cho, Gye-Chun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.9 no.2
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    • pp.109-120
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    • 2007
  • Auxiliary support systems such as the reinforced protective umbrella method have been applied before tunnel excavation to increase ground stiffness and to prevent the large deformation. However, determination procedure of geotechnical parameters along the construction sequence contains various errors. This study suggests a method to characterize the time-dependent behavior of pre-reinforced zones around the tunnel using elastic waves. Experimental results show that shear strength as well as elastic wave velocities increase with the curing time. Shear strength and strength parameters can be uniquely correlated to elastic wave velocities. Obtained results from the laboratory tests are applied to numerical simulation of tunnel considering its construction sequences. Based on numerical analysis, initial installation part of pre-reinforcement and portal of tunnel are critical for tunnel stability. Result of the time-dependent condition is similar to the results of for $1{\sim}2$ days of the constant time conditions. Finally, suggested simple analysis method combining experimental and numerical procedure which considering time-dependent behavior of pre-reinforced zone on tunnel would provide reliable and reasonable design and analysis for tunnel.

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Short- and long-term analyses of shear lag in RC box girders considering axial equilibrium

  • Xiang, Yiqiang;He, Xiaoyang
    • Structural Engineering and Mechanics
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    • v.62 no.6
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    • pp.725-737
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    • 2017
  • An analytical method considering axial equilibrium is proposed for the short- and long-term analyses of shear lag effect in reinforced concrete (RC) box girders. The axial equilibrium of box girders is taken into account by using an additional generalized displacement, referred to as the longitudinal displacement of the web. Three independent shear lag functions are introduced to describe different shear lag intensities of the top, bottom, and cantilever plates. The time-dependent material properties of the concrete are simulated by the age-adjusted effective modulus method (AEMM), while the reinforcement is assumed to behave in a linear-elastic fashion. The differential equations are derived based on the longitudinal displacement of the web, the vertical displacement of the cross section, and the shear lag functions of the flanges. The time-dependent expressions of the generalized displacements are then deduced for box girders subjected to uniformly distributed loads. The accuracy of the proposed method is validated against the finite element results regarding the short- and long-term responses of a simply-supported RC box girder. Furthermore, creep analyses considering and neglecting shrinkage are performed to quantify the time effects on the long-term behavior of a continuous RC box girder. The results show that the proposed method can well evaluate both the short- and long-term behavior of box girders, and that concrete shrinkage has a considerable impact on the concrete stresses and internal forces, while concrete creep can remarkably affect the long-term deflections.

Ussing's flux ratio theorem for nonlinear diffusive transport with chemical interactions

  • Bracken, A.J.;McNabb, A.;Suzuki, M.
    • 제어로봇시스템학회:학술대회논문집
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    • 1994.10a
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    • pp.747-752
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    • 1994
  • Ussing's flux ratio theorem (1978) reflects a reciprocal relationship behavior between the unidirectional fluxes in asymmetric steady diffusion-convection in a membrane slab. This surprising result has led to many subsequent studies in a wide range of applications, in particular involving linear models of time dependent problems in biology and physiology. Ussing's theorem and its extensions are inherently linear in character. It is of considerable interest to ask to what extent these results apply, if at all, in situations involving, for example, nonlinear reaction. A physiologically interesting situation has been considered by Weisiger et at. (1989, 1991, 1992) and by McNabb et al. (1990, 1991) who studied the role of albumin in the transport of ligands across aqueous diffusion barriers in a liver membrane slab. The results are that there exist reciprocal relationships between unidirectional fluxes in the steady state, although albumin is chemically interacting in a nonlinear way of the diffusion processes. However, the results do not hold in general at early times. Since this type of study first started, it has been speculated about when and how the Ussing's flux ratio theorem fails in a general diffusion-convection-reaction system. In this paper we discuss the validity of Ussing-type theorems in time-dependent situations, and consider the limiting time behavior of a general nonlinear diffusion system with interaction.

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Noninvasive study of the swelling effect for biopolymers using NMR Microimaging (핵자기공명 현미영상법을 이용한 생체고분자의 팽윤현상에 대한 비파괴연구)

  • Lee, D.H.;Ko, R.K.;Cho, Z.H.;Kim, S.S.
    • Proceedings of the KOSOMBE Conference
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    • v.1995 no.05
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    • pp.223-226
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    • 1995
  • Polymers have been developed and applied in many biomedical areas as well as engineering and industrial fields. The first essential to achieve successful development and applications is that properties of such polymer materials would be investigated. In many cases, such investigations are accomplished by observing polymeric behavior arising from the environmental changes such as pH, temperature, and ionic concentration. It has long been known that NMR is extremely sensitive to many biochemical and physical changes occurring in the polymer samples. In the present study we focus our study on NMR Microimaging, which is one of the important NMR applications, to characterize the swelling effect by observing the time dependent spatial variations of polymer specimens. For the samples three kinds of polyvinyl alcohol (PVA) specimens are prepared with different degrees of cross linking density. $^1H$ NMR microimages are acquired as a function of time to visualize the swelling behavior as well as volumetric changes occurring in the specimens. From the acquired time dependent images, the swelling process is exploited.

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Field Investigation of Composite Behavior in High-speed Railway PSC Box Girder Bridge (고속전철 PSC 박스거더교 합성거동의 현장 계측에 관한 연구)

  • 김영진;김병석;강재윤
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.995-1000
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    • 2000
  • Segmentally erected prestressed concrete box girder bridges have been widely used in Korean high speed railway. Segmental erection has been accomplished along the longitudinal direction and across the depth of cross section. The cross section is similar to a composite cross section, composed of old and new segments. Because these segments have different time-dependent creep and shrinkage properties, a stress redistribution takes place during the construction period. It is the main objective in this research to investigate this behavior. An actual bridge was instrumented with 96 vibrating wire embedded type strain gauges, 6 electronic type steel strain gauges, and 75 thermocouples. Two span continuous high speed railway bridge was selected. Two points of importance, such as the midpoint of the first span and the point of interior support, along the span of the girder were chosen to monitor the time dependent behaviors for an extended period of time. The data collection was starting just after concrete girder were cast and is still going on. According to the measured results, the strain distributions across the depth of the section at midspan and interior support were not continuous and the important redistribution of stresses takes place. Thus, rational design of prestressed concrete composite box girder bridges need.