• 설비공학논문집
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• 제17권2호
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• pp.110-116
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• 2005

This paper deals with interaction between two bubbles or particles and flow around them, visualized by a moving object flow image analyzer(MOFIA) consisting of a three-dimensional (3D) moving object image analyzer(MOIA) and two-dimensional particle image velocimetry(PIV). The experiments were carried out for rising bubbles or particles of various densities, sizes, and/or shapes in stagnant water in a vertical pipe. In the MOFIA employed, 3D-MOIA was used to measure particles or bubbles motion and PIV was used to measure fluid flow, The experimental results showed that the interaction was characterized by the shape, size and density of two particles or bubbles.

• 한국세라믹학회지
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• 제33권9호
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• pp.1064-1072
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• 1996

The synthetic conditions and characteristics of ZSM-5 type zeolites (ZSM-5/silicalite) for the preparation of the zeolite composite membranes for gas separation were investigated. ZSM-5 zeolites could be synthesized by the hydrothermal treatment of the mixture of colloidal silica sol aluminum nitrate sodium hydroxide and TPABr at a temperature range of 150-17$0^{\circ}C$ in the autoclave. Silicalties were done from the solution of water glass water and TPABr. Their crystalline structures transformed from orthorhombic to monoclinic from and their pore structures of three-dimensional channels were opened as TPABr filling channels was burned off at the calcination temperature of 50$0^{\circ}C$. The specific surface area of the calcined zeolite was about 360 m3/g and its surface property was hydrophobic. Crystal sizes of ZSM-5 and silicalite were 0.5-1.0${\mu}{\textrm}{m}$ and 8-10${\mu}{\textrm}{m}$ respectively having no change due to the calcination. In particular the shape and the size of the ZSM-5 type zeolite were sensitively varied with silica sources and concentrations of reaction solutions/sols.

• Advances in materials Research
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• 제9권1호
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• pp.1-14
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• 2020

The hybrid method of three-dimensional ion implantation and electric arc is presented as a novel plasma-ion technique that allows by means of high voltage pulsed and electric arc discharges, the bombardment of non-metallic and metallic ions then implanting upon the surface of a solid surface, especially out of metallic nature. In this study AISI/SAE 4140 samples, a tool type steel broadly used in the industry due to its acceptable physicochemical properties, were metallographically prepared then surface modified by implanting titanium and simultaneously titanium and nitrogen particles during 5 min and 10 min. The effect of the ion implantation technique over the substrate surface was analysed by characterization and electrochemical techniques. From the results, the formation of Ti micro-droplets upon the surface after the implantation treatment were observed by micrographs obtained by scanning electron microscopy. The presence of doping particles on the implanted substrates were detected by elemental analysis. The linear polarization resistance, potentiodynamic polarization and total porosity analysis demonstrated that the samples whose implantation treatment with Ti ions for 10 min, offer a better protection against the corrosion compared with non-implanted substrates and implanted at the different conditions in this study.

• Bulletin of the Korean Chemical Society
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• 제31권7호
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• pp.1875-1880
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• 2010

A dicycle pyrazoline derivative, 1-phenyl-5-(p-fluorophenyl)-3,4-($\alpha$-p-fluoro-tolylenecyclohexano) pyrazoline, was synthesized and characterized by elemental analysis, IR, UV-vis, fluorescence spectra and X-ray single crystal diffraction. Density function theory (DFT) calculations were performed by using B3LYP method with 6-$311G^{**}$ basis set. The optimized geometry can well simulate the molecular structure. Vibrational frequencies were predicted, assigned and compared with the experimental values, which suggest that B3LYP/6-$311G^{**}$ method can well predict the IR spectra. Both the experimental electronic absorption spectra and the predicted ones by B3LYP/6-$311G^{**}$ method reveal three electron-transition bands, with the theoretical ones having some red shifts compared with the experimental data. Natural bond orbital analyses indicate that the absorption bands are mainly derived from the contribution of n $\rightarrow\pi^*$ and $\pi\rightarrow\pi^*$ transitions. Fluorescence spectra determination shows that the title compound can emit blue-light at about 478 nm. On the basis of vibrational analysis, the thermodynamic properties of title compound at different temperature have been calculated, revealing the correlations between $C^0_{p,m}$, $S^0_m$, $H^0_m$ and temperature.

• Carbon letters
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• 제5권2호
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• pp.68-74
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• 2004

The polymer with contents of $C_{60}$ up to 57 wt.% was produced by mutual condensation of fullerene $C_{60}$ and ethylenediamine. The investigations of this polymer as well as pristine fullerene to comparison were carried out by FT-IR and UV-Vis spectroscopy, ToF-SIMS, TGA, and elemental analysis. At least three kinds of components was revealed as building blocks of polymer. The fullerene cage underwent only distortion but didn't destroy during formation of polymer. The pure fullerene was found as an intermediate of the thermal decomposition of polymer. The conclusion that this polymer could serve as precursor to produce carbon nanomaterial with high concentration curved graphene sheets and can be used for gas adsorption and electrochemical application was made.

• 대한약학회:학술대회논문집
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• 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
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• pp.202.3-202.3
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• 2003

Two Known compounds, syringaresinol monoglucoside(8), chimaphilin(14), together with three new compounds, (9)[mp. $106{\sim} 111^{\circ}C$, C_{29}H_{44}O_{13}$], (10)[mp. $180{\sim}182^{\circ}C$, $C_{15}H_{20}O_{9}$] and (11)[mp. $100{\sim}105^{\circ}C$, $C_{18}H_{28}O_{8}$] were isolated from the BuOH fractionof Pyrola japonics(Pyrolaceae). The structures of the known compounds were determined by chemical and spectorscopic methods. The assignments of the $^{1}H-$ and $^{13}C-NMP$ spectra of these compounds were carried out by two-dimensional $^1H-^1H-COSY$, NOESY and $^1H-^{13}C$ multiple-bond, multiplequantum spectroscopic correlation techniques. The characterization of the three new compounds is now in progress.

• Composites Research
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• 제15권6호
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• pp.30-37
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• 2002

꼰 섬유(twisted yarn)로 이루어진 복합재료의 탄성계수를 예측하기 위한 강성모델을 제시하였다. 이 모델은 단위 셀 구조를 바탕으로 하여 좌표변환과 구성 재료의 연성 상수를 체적 평균함으로써 복합재료의 탄성계수를 예측하는 방법이다. 해석적인 결과와 실험치와의 비교를 위하여 두 종류의 꼬임 각을 가지는 섬유로 구성된 복합재료에 대한 시험을 하였으며 인장, 압축, 전단 강도와 탄성계수를 구하였다. 이 시험편은 유리섬유 및 에폭시 수지를 사용한 RTM 성형법으로 제조하였다. 탄성계수에 대한 비교 곁과 예측치와 실험치는 비교적 잘 일치하였다. 이 모델에 의해 구해진 3차원적인 탄성계수 값은, 꼬인 섬유로 이루어진 직조형 복합재료 구조물의 구조해석을 위한 기본 물성치 입력값으로 사용될 수 있다.

• 대한기계학회논문집A
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• 제25권2호
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• pp.275-282
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• 2001

The reactor pressure vessel is usually cladded with stainless steel to prevent corrosion and radiation embrittlement. Number of subclad cracks may be found during an in-service-inspection due to the presence of cladding. It is specified, in ASME Sec. XI, that a subclad crack is characterized as a surface crack when the thickness of the clad is less than 40% of the crack depth. This condition is provided to keep the crack integrity evaluation conservative. In order to refine the fracture assessment procedures for such subclad cracks under a pressurized thermal shock condition, three dimensional finite element analyses are applied for various subclad cracks existing under cladding. A total of 36 crack geometries are analyzed, and the results are compared with those for surface cracks. The resulting stress intensity factors for subclad cracks are 6 to 44% less than those for surface cracks. It is proven that the flaw characterization condition as specified in ASME Sec. XI can be overly conservative for some subclad cracks.

• Journal of the Optical Society of Korea
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• 제15권2호
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• pp.196-201
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• 2011

Near-field properties of light emanated from a subwavelength double slit of finite length in a thin metal film, which is essential for understanding fundamental physical mechanisms for near-field optical beam manipulations and various potential nanophotonic device applications, is investigated by using a three-dimensional finite-difference time-domain method. Near-field intensity distribution along the propagation direction of light after passing through the slit has been obtained from the phase relation of transverse electric and magnetic fields and the wave impedance. It is found that the near field of emerged light from the both slits is evanescent, that is consistent with conventional surface plasmon localization near the metal surface. Due to the finite of the slit, the amplitude of this evanescent field does not monotonically approach to than of the infinite slit as the slit length increases, i.e. the near-field of the longer slit along the center line can be weaker than that of the shorter one.

• Bulletin of the Korean Chemical Society
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• 제34권4호
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• pp.1120-1126
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• 2013

The syndecan family consists of four transmembrane heparan sulfate proteoglycans present in most cell types and each syndecan shares a common structure containing a heparan sulfate modified extracellular domain, a single transmembrane domain and a C-terminal cytoplasmic domain. To get a better understanding of the mechanism and function of syndecan-4 which is one of the syndecan family, it is crucial to investigate its three-dimensional structure. Unfortunately, it is difficult to prepare the peptide because it is membrane-bound protein that transverses the lipid bilayer of the cell membrane. Here, we optimize the expression, purification, and characterization of transmembrane, cytoplasmic and short extracellular domains of syndecan4 (syndecan-4 eTC). Syndecan-4 eTC was successfully obtained with high purity and yield from the M9 medium. The structural information of syndecan-4 eTC was investigated by MALDI-TOF mass (MS) spectrometry, circular dichroism (CD) spectroscopy, and nuclear magnetic resonance (NMR) spectroscopy. It was confirmed that syndecan-4 eTC had an ${\alpha}$-helical multimeric structure like transmembrane domain of syndecan-4 (syndecan-4 TM) in membrane environments.