Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

Synthesis and Characterization of Zeolite Composite Membranes (I):Synthesis of ZSM-5 Type Zeolites

제올라이트 복합 분리막의 합성 및 특성화(I): ZSM-5계 제올라이트의 합성

  • 현상훈 (연세대학교 세라믹공학과) ;
  • 김준학 (요업기술원 정밀요업과) ;
  • 송재권 (연세대학교 세라믹공학과)
  • Published : 1996.09.01
Download PDF
⟨ Previous Next ⟩

Abstract

The synthetic conditions and characteristics of ZSM-5 type zeolites (ZSM-5/silicalite) for the preparation of the zeolite composite membranes for gas separation were investigated. ZSM-5 zeolites could be synthesized by the hydrothermal treatment of the mixture of colloidal silica sol aluminum nitrate sodium hydroxide and TPABr at a temperature range of 150-17$0^{\circ}C$ in the autoclave. Silicalties were done from the solution of water glass water and TPABr. Their crystalline structures transformed from orthorhombic to monoclinic from and their pore structures of three-dimensional channels were opened as TPABr filling channels was burned off at the calcination temperature of 50$0^{\circ}C$. The specific surface area of the calcined zeolite was about 360 m3/g and its surface property was hydrophobic. Crystal sizes of ZSM-5 and silicalite were 0.5-1.0${\mu}{\textrm}{m}$ and 8-10${\mu}{\textrm}{m}$ respectively having no change due to the calcination. In particular the shape and the size of the ZSM-5 type zeolite were sensitively varied with silica sources and concentrations of reaction solutions/sols.

Keywords

References

  1. Membrane. J v.3 no.1 Present Status and Preparation Technology of Ceramic Membranes S.H. Hyun
  2. Report No. ORNL/TM-113435 Using Inorganic Membranes to Separate Gas:R&D Status Review B.Z. Egan
  3. J. Am. Ceram. Soc v.77 no.12 Synthesis of Nanoparticulate Silica Composite Membranes by the Pressurized Sol-Gel Technique S.H. Hyun;B.S. Kang
  4. J. Am. Ceram. Soc v.79 no.1 Synthesis of Titania Com-posite Membranes by Pressurized Sol-Gel Technique S.H. Hyun;B.S. Kang
  5. U.S. Patent 4,061,724 R.W. Grose;E,M. Flanigen
  6. J. Catalysis v.61 Chemical and Physical Properties of ZSM-5 Substitutional Series D.H. Olson;W.O. Hagg;R.M. Lago
  7. Nature v.271 no.9 Silicalite A New Hydrophobic Crystalline Silica Molecular Sieve E.M. Flanigen;J.M. Bennett;R.W. Grose;J.P. Cohen;R.L. Patton;R.M. Kirchner;J.V. Smith
  8. U.S. Patent 3,702,886 R.J. Argaur;G.R. Landolt
  9. Studies Surface Science Catalysis v.58 Introduction to Zeolit Science and Practice H. Van Bekkum;E.M. Flanigen;J.C. Jansen
  10. Studies Surface Science Catalysis v.33 Synthesis of High-Silica Aluminosilicate Zeolite D.A. Jacobs;J.A. Marteus
  11. Zeolite v.11 Kinetic Study on the nucleation of (Na, TPA)-ZSM-5 Zeolite G. Golemme;A. Nastro;J.B. Nagy;B. Suhotic;F. Crea;R. Aiello
  12. Molecular Sieves:Principles of Synthesis and Identification R. Szostak
  13. Nature v.272 no.30 Structure of Synthetic Zeolite ZSM-5 G.T. Kokotailo;S.L. Lawton;D.H. Olson
  14. J. Phy. Chem v.83 no.2 ZSM-5 Type Materials:Factors Affecting Crystal Symmetry E.L. Wu;S.L. Lawton;D.H. Olson;A.C. Rohrman;G.T. Kokotailo
  15. Nature v.296 no.8 Resolving Crystallographically Distant Tetrahedral Sites in Silicalite and ZSM-5 by Solid State NMR C.A. Fyfe;G.C. Gobbi;J. Khnowski;J.M. Thomas;S. Ramdas
  16. J. Chem. Soc. Chem. Commun Uses of I.R. Spectroscopy in identifying ZSM Zeolite Structure G. Coudurier;C. Naccache;J.C. Verkine
  17. Molecular Sieves: Principles of Synthesis and Identification R. Szostak
  18. Zeolites v.14 MFI Zeolite Crystallization Under Controlled Dosage of TPA Template M. Otabe
  19. Zeolites v.11 Preparation of Characterization of ZSM-5 Zeolite Film T. Sano;Y. Kiyozumi;M. Kawamura;F. Mizukami;H. Takaya;T. Mour;W. Inaoka;Y. Toida;M. Watanabe;K. Toyoda
  20. Zeolite Synthesis, ACS Symp.Ser. 398 Structure and Properties of Aluminosilicate Solutions and Gels G. Harvey;L.S.D. Glasser;M.L. Occelli(ed.);H.Z. Robson(ed.)
  21. see Ref. 20 Crystal Growth Regulation and Morphology of Zeolite Single Crystal of the MFI Type J.C. Jansen;C.W.R. Engelen;H.V. Bekkum
  22. J. Korean. Ceram. Soc v.29 no.6 Development of Ceramic Composite Membranes for Gas Separation: I Coating Characteristics of Nanoparticulate SiO₂Sols S.H. Hyun;M.A. Anderson;S.P. Yoon