• Journal of the Korean Wood Science and Technology
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• v.25 no.2
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• pp.21-26
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• 1997

Lignin viscous material was prepared from acetosolve lignin by phenolation and heat treatment. The yield of phenolation was about 160% with p-toluene sulfonic acid(2% of acetosolve lignin) as catalyzer. Phenolated lignin has a good spinnability and thermosetting property by $300^{\circ}C$ treatment with vaccum. Acetosolve lignin carbon fiber has $20{\pm}5$ m diameter and $68.2{\pm}10\;kg/mm^2$ tensile strength. The yield of carbon fiber based on acetosolve lignin was 31%.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.7
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• pp.141-146
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• 2000

A flexible tool is developed for automatic finishing of curved surfaces without any complicated control technique on three-axes machining center. The tool is made of thermosetting polyurethane elastomer on the surface of which aluminum oxide abrasives are mounted. Performance and durability of the tool are examined by finishing ball-end milled surfaces of high-alloyed tool steel. It is demonstrated that the tool removes cusp successfully without changing overall surface shape in relatively short time.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2002.10a
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• pp.185-188
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• 2002

An abrasive vitreous bonded solid mass having a vitrified abrasive structure comprising diamond grains which are held by an in inorganic bonding agent, the vitrified diamond wheel is impregnated with a composition which comprises a thermosetting synthetic resin and a surfactant. The vitrified diamond wheel is manufactured by preparing the composition including the resin and the surfactant, impregnating the abrasive structure with the composition, and curing the composition. The diamond wheel newly developed showed excellent performance in grinding carbide.

• Macromolecular Research
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• v.10 no.4
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• pp.236-239
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• 2002

Centrifugation is a method to create functionally graded materials (FGM) with a thermosetting matrix. In this study the movement of short carbon fibers in an epoxy resin during the centrifugation process was modeled to determine the fiber distribution in the final product. For this purpose a form factor K was introduced to modify a set of equations that was previously shown to be valid for the motion of spheres. It was shown that the results of the simulation were in good agreement with the experimental data, when an empirical K factor of four was chosen.

• Journal of the Korean Geosynthetics Society
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• v.13 no.1
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• pp.33-40
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• 2014

In general, pipes buried underground can be classified into either rigid or flexible pipe. Glass fiber reinforced thermosetting polymer plastic (GFRP) pipe can be considered as one of typical flexible pipes for which the soil-pipe structure interaction must be taked into account in the design. In this paper, we present the result of an investigation pertaining to the short-term and long-term behavior of buried GFRP pipe. The mechanical properties of the GFRP pipe produced in the domestic manufacturer are determined and the results are reported in this paper. In addition, Ring deflection is measured by the field tests and the finite element analysis. Also, the extrapolation using these techniques typically extends the trend from data gathered over a period of approximately 5,232 hours, to a prediction of the property at 50 years, which is the typical maximum extrapolation time. Therefore, it was investigated that the long-term ring deflection of GFRP pipe estimated by methods for Monod-type.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.4 s.175
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• pp.1055-1064
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• 2000

First, various specimen geometries, namely, coupon type, waisted type and dog-bone type, were examined to determine appropriate fatigue specimen of thermoplastic composite material AS4/PEEK and the n, fatigue strength of smooth and notched specimens of AS4/PEEK [-45/0/+45/90]2s was investigated. Fatigue tests were performed under load controlled condition at a stress ratio of 0. 1 at a frequency of 5Hz. Stiffness degradation of specimens with fatigue cycling was monitored using an automated unloading compliance technique. The waisted type specimen is found appropriate for smooth fatigue specimen geometry of AS4/PEEK. As for the effect of stress concentration, it is found that fatigue strength is higher for a 2mm-diameter hole notched specimen than a 5mm-diameter one. Fatigue notch factor decreases with the increase of fatigue life. These results are far different from the trend of fatigue strength of metallic materials. The stiffness variation of smooth specimen was only 4% at maximum until final fracture. On the other hand, the stiffness of hole notched specimen was reduced by 45% at maximum. Notched fatigue strength was compared between thermoplastic composite AS4/PEEK and thermosetting composite Graphite/Epoxy. In long-life fatigue (>104), the AS4/PEEK composite shows superior fatigue strength, but in short-life fatigue, the fatigue strength of the Graphite/Epoxy composite is nearly equal or somewhat higher than that of the AS4/PEEK composite.

• Journal of the Korean Society for Railway
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• v.12 no.6
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• pp.1059-1066
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• 2009

Recently, the amount of thermosetting plastic wastes has increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy resins, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that decompose epoxy resin and recover carbon fibers from carbon fiber reinforced epoxy composites applied to railway vehicles was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

• Polymer(Korea)
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• v.27 no.5
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• pp.436-442
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• 2003

Thermosetting elastomer such as EPDM (Ethylene Propylene Dien Rubber) has been applied to the sponge weatherstrip of a vehicle as a main material. However, the thermosetting elastomers have limited recycling and have brought about the environmental problems. Furthermore, many steps of the manufacturing process such as formulation, mastication and vulcanization make difficult to control uniformity of the endproducts. These problems of current EPDM weatherstrip necessitated development of a new recyclable material, Thermoplastic Vulcanizates (TPV). In this study the influence of the water contents, and the processing conditions. On the foam density and structure in water blowing process was carried out. We found that TPV also can be foamed with water, maintaining the uniformity form this study. Therefore, many inevitable problems of EPDM weatherstrip can be solved, and this new technique is expected to take a roll of making a breakthrough in the rubber industry.

• Composites Research
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• v.30 no.6
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• pp.371-378
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• 2017

In this study, hygroelastic behavior of thermosetting epoxy is predicted by molecular dynamics simulations. Since consistent exposures to humid environments lead to macroscopic degradation of polymer composite, computational simulation study of the hygroscopically aged epoxy cell is essential for long-time durability. Therefore, we modeled amorphous epoxy molecular unit cell structures at a crosslinking ratio of 30, 90% and with the moisture weight fraction of 0, 4 wt% respectively. Diglycidyl ether of bisphenol F (EPON862) and triethylenetetramine (TETA) are chosen as resin and curing agent respectively. Incorporating equilibrium and non-equilibrium ensemble simulation with a classical interatomic potential, various hygroelastic properties including diffusion coefficient of water, coefficient of moisture expansion (CME), stress-strain curve and elastic modulus are predicted. To establish the structural property relationship of pure epoxy, free volume and internal non-bond potential energy of epoxy are examined.

• Journal of the Korean Institute of Gas
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• v.2 no.2
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• pp.55-60
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• 1998

In this study, we investigated the dust explosion characteristics by determining minimum ignition energy and explosion limit for this experiment, we used pine-tree dust which was used widely for the filler of thermosetting resin. The experiment was accomplished according to the variation of discharge gap, dust concentration, particle size and humidity. The result of this experiment are as follows; (1) The relation between the discharge gap and ignition energy was that ignition energy decreased according as the discharge gap became small, but increased when the discharge gap was below 4mm and suddenly became infinite when the discharge gap was below. So, we knew that this infinite value was limit discharge gap. (2) When the dust concentration increase and the particle size became microscopic it was easy to explore and in the same particle size, if the humidity increase the minimum ingnition energy decreased.