• Title/Summary/Keyword: thermodynamic theories

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An Analysis of Problems Related to Cloud Making Experiments in School Science Textbooks and Development of an Experiment Based on the Thermodynamic Theories (열역학적 관점에 근거한 구름발생 실험의 문제점 분석 및 개선방안에 대한 고찰)

  • Park, Dong-Joe;Paik, Seoung-Hey;Kang, Seong-Joo
    • Journal of The Korean Association For Science Education
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    • v.21 no.3
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    • pp.547-557
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    • 2001
  • In this study, we compared the contents of cloud making experiments in middle school science textbooks of 5th and 6th science curriculum from the viewpoint of methods and apparatus. And we analyzed the problems of the experimental methods and apparatus based on the thermodynamic theories. A new experiment was developed to solve the problems, and the effects of new experiment were compared with those of the experiments in the textbooks.

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What Is the Role of Thermodynamics on Protein Stability\ulcorner

  • Gummadi, Sathyanarayana N.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.1
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    • pp.9-18
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    • 2003
  • The most challenging and emerging field of biotechnology is the tailoring of proteins to attain the desired characteristic properties. In order to increase the stability of proteins and to study the function of proteins, the mechanism by which proteins fold and unfold should be known. It has been debated for a long time how exactly the linear form of a protein is converted into a stable 3-dimensional structure. The literature showed that many theories support the fact that protein folding E5 a Thermodynamically controlled process. It is also possible to predict the mechanism of protein deactivation and Stability to an extent from thermodynamic studies. This article reviewed various theories that have been proposed to explain the process of protein folding after its biosynthesis in ribosomes. The theories of the determination of the thermodynamic properties and the interpretation of thermodynamic data of protein stability are 3150 discussed in this article.

Thermodynamic Parameters for Micelle Formation of Dodecylpyridinium Chloride (Dodecylpyridinium Chloride의 micelle 形成의 熱力學變數)

  • Han, Man-Un
    • Journal of the Korean Chemical Society
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    • v.10 no.2
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    • pp.103-108
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    • 1966
  • The effect of temperature on the critical micelle concentration of dodecylpyridinium chloride has been determined by electrical conductance method over the range from $5^{\circ}C\;to\;50^{\circ}C$. The values of the change in heat content, ${\Delta}H_m$, and the other thermodynamic parameters have been estimated using the equation of temperature dependence on the critical micelle concentration for the same temperature range. The significance of these thermodynamic quantities and their relations to the various current theories of micelle forming processes were discussed.

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Domain Structure of Liguid Water According to the Theory of Intermolecular Forces

  • Mu Shik Jhon;Ung In Cho
    • Journal of the Korean Chemical Society
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    • v.16 no.3
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    • pp.135-141
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    • 1972
  • In the past years, a number of theories have been published to elucidate the structure of liquid water. common to most of these theories is that water mainly consist of several different kinds of clusters and also hydrogen bonds in water may be bent to some degree. Recentrly, in a series of paper, Jhon and Eyring successfully explained thermodynamic, dielectric, surface and transport properites of water, assuming that it contains small domains of about 46 molecules. According to the theory, the cluster size does not change with temperature, but the cluster concentration changes. In this paper, the potential function for the hydrogen bond, the dispersion energy and dipole-dipole interaction terms. The calculated results show that the domain of nearly 46 molecules is energetically most probable, and its size is independent of temperature. And also, we evaluated the effect of angel variation of the bent hydrogen bond. In addition, the relaxation energy different for ice and water is also explained by this method.

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Wave propagation in a two-temperature fiber-reinforced magneto-thermoelastic medium with three-phase-lag model

  • Said, Samia M.;Othman, Mohamed I.A.
    • Structural Engineering and Mechanics
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    • v.57 no.2
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    • pp.201-220
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    • 2016
  • A general model of equations of the two-temperature theory of generalized thermoelasticity is applied to study the wave propagation in a fiber-reinforced magneto-thermoelastic medium in the context of the three-phase-lag model and Green-Naghdi theory without energy dissipation. The material is a homogeneous isotropic elastic half-space. The exact expression of the displacement components, force stresses, thermodynamic temperature and conductive temperature is obtained by using normal mode analysis. The variations of the considered variables with the horizontal distance are illustrated graphically. Comparisons are made with the results of the two theories in the absence and presence of a magnetic field as well as a two-temperature parameter. A comparison is also made between the results of the two theories in the absence and presence of reinforcement.

The Effect of Temperature on the Critical Micelle Concentration of Hexadecyl Trimethyl Ammonium Bromide (界面活性劑 Hexadecyl Trimethyl Ammonium Bromide의 C. M. C. 의 溫度效果)

  • Kun Moo Lee
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.1-4
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    • 1969
  • Temperature effect on the critical micelle concentration of hexadecyl trimetyl ammonium bromide over the range of $2^{\circ}-50^{\circ}C$ has been investigated by the method of electrical conductivity. The values obtained have been formulated as a power series in T. Several thermodynamic parameters have been calculated for the temparature range examined and their values have been discussed in the light of current theories on the participation of solvent in micelle formation.

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A Calculation for the Viscosity of Liquid Metals

  • Kim, Won-Soo;Chair, Tong-Seek
    • Bulletin of the Korean Chemical Society
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    • v.11 no.5
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    • pp.446-449
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    • 1990
  • A phenomenological theory of viscosity which has been proposed by authors is applied to liquid metals for which the calculation is a severe test for liquid theories. The thermodynamic properties used in the calculations can be obtained by using the Roulette liquid theory. The calculated values of the viscosities for liquid metals are in good agreements with the observed values.

A quasi 3D solution for thermodynamic response of FG sandwich plates lying on variable elastic foundation with arbitrary boundary conditions

  • Bouiadjra, Rabbab Bachir;Mahmoudi, Abdelkader;Sekkal, Mohamed;Benyoucef, Samir;Selim, Mahmoud M.;Tounsi, Abdelouahed;Hussain, Muzamal
    • Steel and Composite Structures
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    • v.41 no.6
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    • pp.873-886
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    • 2021
  • In this paper, an analytical solution for thermodynamic response of functionally graded (FG) sandwich plates resting on variable elastic foundation is performed by using a quasi 3D shear deformation plate theory. The displacement field used in the present study contains undetermined integral terms and involves only four unknown functions with including stretching effect. The FG sandwich plate is considered to be subject to a time harmonic sinusoidal temperature field across its thickness with any combined boundary conditions. Equations of motion are derived from Hamilton's principle. The numerical results are compared with the existing results of quasi-3D shear deformation theories and an excellent agreement is observed. Several numerical examples for fundamental frequency, deflection, stress and variable elastic foundation parameter's analysis of FG sandwich plates are presented and discussed considering different material gradients, layer thickness ratios, thickness-to-length ratios and boundary conditions. The results of the present study reveal that the nature of the elastic foundation, the boundary conditions and the thermodynamic loading affect the response of the FG plate especially in the case of a thick plate.

Combined influence of variable distribution models and boundary conditions on the thermodynamic behavior of FG sandwich plates lying on various elastic foundations

  • Djamel Eddine Lafi;Abdelhakim Bouhadra;Belgacem Mamen;Abderahmane Menasria;Mohamed Bourada;Abdelmoumen Anis Bousahla;Fouad Bourada;Abdelouahed Tounsi;Abdeldjebbar Tounsi;Murat Yaylaci
    • Structural Engineering and Mechanics
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    • v.89 no.2
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    • pp.103-119
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    • 2024
  • The present research investigates the thermodynamically bending behavior of FG sandwich plates, laying on the Winkler/Pasternak/Kerr foundation with various boundary conditions, subjected to harmonic thermal load varying through thickness. The supposed FG sandwich plate has three layers with a ceramic core. The constituents' volume fractions of the lower and upper faces vary gradually in the direction of the FG sandwich plate thickness. This variation is performed according to various models: a Power law, Trigonometric, Viola-Tornabene, and the Exponential model, while the core is constantly homogeneous. The displacement field considered in the current work contains integral terms and fewer unknowns than other theories in the literature. The corresponding equations of motion are derived based on Hamilton's principle. The impact of the distribution model, scheme, aspect ratio, side-to-thickness ratio, boundary conditions, and elastic foundations on thermodynamic bending are examined in this study. The deflections obtained for the sandwich plate without elastic foundations have the lowest values for all boundary conditions. In addition, the minimum deflection values are obtained for the exponential volume fraction law model. The sandwich plate's non-dimensional deflection increases as the aspect ratio increases for all distribution models.

Physiochemical Properties and Antibacterial Activities of Metal Complexes of Norfloxacin (노르후록사신-금속이온 착물의 물리화학적 성질 및 항균력)

  • Park, Won-Bong;Kim, Kyung-Ah;Lee, Myung-Hwan;Lee, Dong-Sun;Rho, Dong-Yoon
    • YAKHAK HOEJI
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    • v.36 no.6
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    • pp.577-581
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    • 1992
  • Norfloxacin complexes of $Fe^{2+}$, $Cu^{2+}$ and $Al^{3+}$ have been prepared as solids. The stoichiometry of the complexes has been established. IR investigation indicates the metal-ligating sites in norfloxacin. The bioactivities of complexes all lower than that of norfloxacin. The solubilities and partition coefficients have been measured as a function of temperature. The data are used to evaluate the thermodynamic parameters ${\Delta}G$, ${\Delta}H$, ${\Delta}S$ for the solute transfer process and compared with the parent quinolone, norfloxacin. The existence of such complexes is discussed in the light of quinolone mode-of-action theories.

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